Relating Catalysis between Fuel Cell and Metal-Air Batteries
With the ever-increasing demand for higher-performing energy-storage systems, electrocatalysis has become a major topic of interest in an attempt to enhance the electrochemical performance of many electrochemical technologies. Discoveries pertaining to the oxygen reduction reaction catalyst helped e...
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| Published in | Matter Vol. 2; no. 1; pp. 32 - 49 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
Elsevier Inc
08.01.2020
Elsevier |
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| Online Access | Get full text |
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| Abstract | With the ever-increasing demand for higher-performing energy-storage systems, electrocatalysis has become a major topic of interest in an attempt to enhance the electrochemical performance of many electrochemical technologies. Discoveries pertaining to the oxygen reduction reaction catalyst helped enable the commercialization of fuel-cell-based electric vehicles. However, a closely related technology, the metal-air battery, has yet to find commercial application. Much like the Li-ion battery, metal-air batteries can potentially utilize the electrical grid network for charging, bypassing the need for establishing a hydrogen infrastructure. Among the metal-air batteries, Li-air and Zn-air batteries have drawn much interest in the past decade. Unfortunately, state-of-the art metal-air batteries still produce performances that are well below practical levels. In this brief perspective, we hope to bridge some of the ideas from fuel cell to that of metal-air batteries with the aim of inspiring new ideas and directions for future research.
[Display omitted]
Catalyst research for fuel cells has led to much advancement in humanity's understanding of the underlying physics of the process, significantly enhancing the performance of the technologies. In contrast, metal-air batteries such as Li-air and Zn-air batteries remain to be solved. Although the metal anode used in this these systems does play a large role in limiting their commercial success, catalysis also remains quite challenging. In this perspective, a discussion is provided on the similarities and differences between metal-air catalysts and fuel cells for aqueous (alkaline/acidic) and aprotic electrolytes. By attempting to bridge the discussion between the fields and providing our own opinion on the subject, we hope that this perspective will present itself as a starting point in emulating the success of catalysis in fuel cells in the metal-air systems.
Metal-air and fuel cells are both highly attractive energy options for electric vehicles. However, differences among their catalyst design have diverged the two fields with particular separation between aprotic Li-air and aqueous fuel cells. This perspective clarifies the specific differences between the different types of catalyst (aqueous alkaline/acidic and aprotic electrolytes) and attempts to draw analogies for the reader in hopes of sparking new research ideas. |
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| AbstractList | With the ever-increasing demand for higher-performing energy-storage systems, electrocatalysis has become a major topic of interest in an attempt to enhance the electrochemical performance of many electrochemical technologies. Discoveries pertaining to the oxygen reduction reaction catalyst helped enable the commercialization of fuel-cell-based electric vehicles. However, a closely related technology, the metal-air battery, has yet to find commercial application. Much like the Li-ion battery, metal-air batteries can potentially utilize the electrical grid network for charging, bypassing the need for establishing a hydrogen infrastructure. Among the metal-air batteries, Li-air and Zn-air batteries have drawn much interest in the past decade. Unfortunately, state-of-the art metal-air batteries still produce performances that are well below practical levels. In this brief perspective, we hope to bridge some of the ideas from fuel cell to that of metal-air batteries with the aim of inspiring new ideas and directions for future research.
[Display omitted]
Catalyst research for fuel cells has led to much advancement in humanity's understanding of the underlying physics of the process, significantly enhancing the performance of the technologies. In contrast, metal-air batteries such as Li-air and Zn-air batteries remain to be solved. Although the metal anode used in this these systems does play a large role in limiting their commercial success, catalysis also remains quite challenging. In this perspective, a discussion is provided on the similarities and differences between metal-air catalysts and fuel cells for aqueous (alkaline/acidic) and aprotic electrolytes. By attempting to bridge the discussion between the fields and providing our own opinion on the subject, we hope that this perspective will present itself as a starting point in emulating the success of catalysis in fuel cells in the metal-air systems.
Metal-air and fuel cells are both highly attractive energy options for electric vehicles. However, differences among their catalyst design have diverged the two fields with particular separation between aprotic Li-air and aqueous fuel cells. This perspective clarifies the specific differences between the different types of catalyst (aqueous alkaline/acidic and aprotic electrolytes) and attempts to draw analogies for the reader in hopes of sparking new research ideas. |
| Author | Jiang, Gaopeng Li, Yingbo Wang, Rongyue Li, Liang Zhong, Cheng Li, Matthew Chen, Zhongwei Lu, Jun Bi, Xuanxuan |
| Author_xml | – sequence: 1 givenname: Matthew surname: Li fullname: Li, Matthew organization: Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 Cass Avenue, Lemont, IL 60439, USA – sequence: 2 givenname: Xuanxuan surname: Bi fullname: Bi, Xuanxuan organization: Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 Cass Avenue, Lemont, IL 60439, USA – sequence: 3 givenname: Rongyue surname: Wang fullname: Wang, Rongyue organization: Applied Materials Division, Argonne National Laboratory, 9700 Cass Avenue, Lemont, IL 60439, USA – sequence: 4 givenname: Yingbo surname: Li fullname: Li, Yingbo organization: Materials Science Division, Argonne National Laboratory, 9700 Cass Avenue, Lemont, IL 60439, USA – sequence: 5 givenname: Gaopeng surname: Jiang fullname: Jiang, Gaopeng organization: Department of Chemical Engineering, Waterloo Institute of Nanotechnology, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada – sequence: 6 givenname: Liang surname: Li fullname: Li, Liang organization: College of Physics, Optoelectronics and Energy, Center for Energy Conversion Materials & Physics (CECMP), Soochow University, Suzhou 215006, P. R. China – sequence: 7 givenname: Cheng surname: Zhong fullname: Zhong, Cheng email: cheng.zhong@tju.edu.cn organization: Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education) and Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China – sequence: 8 givenname: Zhongwei surname: Chen fullname: Chen, Zhongwei email: zhwchen@uwaterloo.ca organization: Department of Chemical Engineering, Waterloo Institute of Nanotechnology, University of Waterloo, 200 University Avenue West, Waterloo, ON N2L 3G1, Canada – sequence: 9 givenname: Jun orcidid: 0000-0003-0858-8577 surname: Lu fullname: Lu, Jun email: junlu@anl.gov organization: Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 Cass Avenue, Lemont, IL 60439, USA |
| BackLink | https://www.osti.gov/biblio/1581680$$D View this record in Osti.gov |
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| Keywords | oxygen evolution reaction Zn-air battery fuel cell oxygen reduction reaction Li-O2 battery |
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| Title | Relating Catalysis between Fuel Cell and Metal-Air Batteries |
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