The removal of natural organic matter with LiCl–TiO2-doped PVDF membranes by integration of ultrafiltration with photocatalysis

Ultrafiltration has become one of the best alternatives replacing conventional drinking water treatment technologies because of increasing stringent regulations for drinking water quality. However, membrane fouling is an important factor which restricts its widespread application. In this study, the...

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Published inDesalination Vol. 344; pp. 412 - 421
Main Authors Song, Hongchen, Shao, Jiahui, Wang, Jianming, Zhong, Xiaoqing
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.07.2014
Elsevier
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Abstract Ultrafiltration has become one of the best alternatives replacing conventional drinking water treatment technologies because of increasing stringent regulations for drinking water quality. However, membrane fouling is an important factor which restricts its widespread application. In this study, the modified polyvinylidene fluoride (PVDF) membranes were prepared by adding different amounts of LiCl and TiO2 particles. The performances of PVDF–LiCl membranes and PVDF–LiCl–TiO2 membranes were investigated by discussing the rejection of natural organic matter (NOM) and flux decline in both dead-end and cross-flow filtration experiments. The effect of photocatalytic degradation on TiO2-doped PVDF membranes was also evaluated. Results from both this study and the previous one with the membrane prepared by adding organic addition agent PEG and TiO2 photocatalyst indicated that appropriate TiO2-doped modification on PVDF membrane could be an effective way for better NOM rejection and reduction of membrane fouling at the same time. TiO2-doped PVDF membrane also shows good self-cleaning ability. The fouled membrane can be cleaned with irradiation and the foulants' photocatalytic degradation is most effective in the first 30min. •Adding TiO2 to PVDF–LiCl improves membrane hydrophilicity, smoothness and rejection.•TiO2-doped PVDF membrane has a good self-cleaning ability.•Optimum irradiation time should be considered to offer the self-cleaning property.•UV irradiation might be a method of membrane cleaning for photocatalytic membranes.
AbstractList Ultrafiltration has become one of the best alternatives replacing conventional drinking water treatment technologies because of increasing stringent regulations for drinking water quality. However, membrane fouling is an important factor which restricts its widespread application. In this study, the modified polyvinylidene fluoride (PVDF) membranes were prepared by adding different amounts of LiCl and TiO2 particles. The performances of PVDF-LiCl membranes and PVDF-LiCl-TiO2 membranes were investigated by discussing the rejection of natural organic matter (NOM) and flux decline in both dead-end and cross-flow filtration experiments. The effect of photocatalytic degradation on TiO2-doped PVDF membranes was also evaluated. Results from both this study and the previous one with the membrane prepared by adding organic addition agent PEG and TiO2 photocatalyst indicated that appropriate TiO2-doped modification on PVDF membrane could be an effective way for better NOM rejection and reduction of membrane fouling at the same time. TiO2-doped PVDF membrane also shows good self-cleaning ability. The fouled membrane can be cleaned with irradiation and the foulants' photocatalytic degradation is most effective in the first 30min.
Ultrafiltration has become one of the best alternatives replacing conventional drinking water treatment technologies because of increasing stringent regulations for drinking water quality. However, membrane fouling is an important factor which restricts its widespread application. In this study, the modified polyvinylidene fluoride (PVDF) membranes were prepared by adding different amounts of LiCl and TiO2 particles. The performances of PVDF–LiCl membranes and PVDF–LiCl–TiO2 membranes were investigated by discussing the rejection of natural organic matter (NOM) and flux decline in both dead-end and cross-flow filtration experiments. The effect of photocatalytic degradation on TiO2-doped PVDF membranes was also evaluated. Results from both this study and the previous one with the membrane prepared by adding organic addition agent PEG and TiO2 photocatalyst indicated that appropriate TiO2-doped modification on PVDF membrane could be an effective way for better NOM rejection and reduction of membrane fouling at the same time. TiO2-doped PVDF membrane also shows good self-cleaning ability. The fouled membrane can be cleaned with irradiation and the foulants' photocatalytic degradation is most effective in the first 30min. •Adding TiO2 to PVDF–LiCl improves membrane hydrophilicity, smoothness and rejection.•TiO2-doped PVDF membrane has a good self-cleaning ability.•Optimum irradiation time should be considered to offer the self-cleaning property.•UV irradiation might be a method of membrane cleaning for photocatalytic membranes.
Author Shao, Jiahui
Song, Hongchen
Zhong, Xiaoqing
Wang, Jianming
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  surname: Zhong
  fullname: Zhong, Xiaoqing
  organization: Guangdong Key Laboratory of Membrane Materials and Membrane Separation, Guangzhou Institute of Advanced Technology, Chinese Academy of Sciences, Guangzhou 511458, China
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Keywords Rejection
Flux decline
Ultrafiltration
TiO2-doped PVDF membrane
Photocatalysis
Drinking water treatment
Drinking water
Organic matter
doped PVDF membrane
Fouling
Crossflow filtration
Membrane separation
Selfpurification
Water quality
Regulation
TiO
Titanium oxide
Catalyst
Photochemical degradation
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Snippet Ultrafiltration has become one of the best alternatives replacing conventional drinking water treatment technologies because of increasing stringent...
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StartPage 412
SubjectTerms Applied sciences
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Degradation
Drinking water
Drinking water and swimming-pool water. Desalination
Exact sciences and technology
Flux decline
Fouling
General and physical chemistry
Membrane separation (reverse osmosis, dialysis...)
Membranes
Photocatalysis
Pollution
Polyvinylidene fluorides
Reactors
Rejection
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
TiO2-doped PVDF membrane
Titanium dioxide
Ultrafiltration
Water treatment and pollution
Title The removal of natural organic matter with LiCl–TiO2-doped PVDF membranes by integration of ultrafiltration with photocatalysis
URI https://dx.doi.org/10.1016/j.desal.2014.04.012
https://www.proquest.com/docview/1622611491
https://www.proquest.com/docview/1642298473
Volume 344
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