Oxidative dehydrogenation of light alkanes to olefins on metal-free catalysts
Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based produ...
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Published in | Chemical Society reviews Vol. 5; no. 2; pp. 1438 - 1468 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
01.02.2021
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Subjects | |
Online Access | Get full text |
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Abstract | Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO
2
emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched.
Metal-free boron- and carbon-based catalysts for the oxidative dehydrogenation of light alkanes is reviewed from the preparation methods, characterization, catalytic performance and mechanistic issues. |
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AbstractList | Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO₂ emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched. Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO2 emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched. Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO 2 emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched. Metal-free boron- and carbon-based catalysts for the oxidative dehydrogenation of light alkanes is reviewed from the preparation methods, characterization, catalytic performance and mechanistic issues. Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO 2 emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched. Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO2 emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched.Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In particular, boron-based catalysts show a superior selectivity toward olefins, excellent stability and atom-economy to valuable carbon-based products by minimizing CO2 emission, which are highly promising in future industrialization. The carbonaceous catalysts also exhibited impressive behavior in the ODH of light alkanes helped along by surface oxygen-containing functional groups. This review surveyed and compared the preparation methods of the boron- and carbon-based catalysts and their characterization, their performance in the ODH of light alkanes, and the mechanistic issues of the ODH including the identification of the possible active sites and the exploration of the underlying mechanisms. We discussed different boron-based materials and established versatile methodologies for the investigation of active sites and reaction mechanisms. We also elaborated on the similarities and differences in catalytic and kinetic behaviors, and reaction mechanisms between boron- and carbon-based metal-free materials. A perspective of the potential issues of metal-free ODH catalytic systems in terms of their rational design and their synergy with reactor engineering was sketched. |
Author | Wang, Dongqi Sheng, Jian Qiu, Bin Gao, Xin-Qian Lu, An-Hui Yan, Bing Lu, Wen-Duo |
AuthorAffiliation | School of Chemical Engineering State Key Laboratory of Fine Chemicals Dalian University of Technology Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources |
AuthorAffiliation_xml | – name: Liaoning Key Laboratory for Catalytic Conversion of Carbon Resources – name: School of Chemical Engineering – name: Dalian University of Technology – name: State Key Laboratory of Fine Chemicals |
Author_xml | – sequence: 1 givenname: Jian surname: Sheng fullname: Sheng, Jian – sequence: 2 givenname: Bing surname: Yan fullname: Yan, Bing – sequence: 3 givenname: Wen-Duo surname: Lu fullname: Lu, Wen-Duo – sequence: 4 givenname: Bin surname: Qiu fullname: Qiu, Bin – sequence: 5 givenname: Xin-Qian surname: Gao fullname: Gao, Xin-Qian – sequence: 6 givenname: Dongqi surname: Wang fullname: Wang, Dongqi – sequence: 7 givenname: An-Hui surname: Lu fullname: Lu, An-Hui |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/33300532$$D View this record in MEDLINE/PubMed |
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Notes | Bing Yan, born in 1990, obtained his BSc degree from Inner Mongolia University of Science and Technology, and then MSc degree from Dalian Polytechnic University, China. He is currently working on his PhD thesis in the group of Prof. Dr A.-H. Lu and focuses on the oxidative dehydrogenation of light alkanes with metal-free catalysts. Dongqi Wang received his PhD degree from the University of Hong Kong in 2004. He worked at MPI für Kohlenforschung, University of Calgary and ETH Zurich. In 2011, he was selected into the "One Hundred Talents Plan" of Chinese Academy of Sciences and took a faculty position in the Institute of High Energy Physics, Chinese Academy of Sciences. In 2020, he moved to Dalian University of Technology where he is now a professor in chemistry. His research interests include the computational study and big data of heterogeneous catalysis and actinide chemistry. Jian Sheng, born in 1994, obtained his BSc degree from Guizhou University. He is currently working on his PhD thesis in the group of Prof. Dr A.-H. Lu and focuses on the oxidative conversion of alkanes with boron-containing heterogeneous catalysts. Wen-Duo Lu, born in 1991, obtained her BSc degree from Qingdao University of Science and Technology, then received an MSc degree and PhD degree from Dalian University of Technology. She is currently working as a postdoctoral fellow at Dalian University of Technology and focuses on the oxidative dehydrogenation of light alkanes with metal-free catalysts. Bin Qiu, born in 1993, obtained his BSc degree from China University of Mining and Technology. He is currently working on his PhD thesis in the group of Prof. Dr A.-H. Lu and focuses on the oxidative dehydrogenation of light alkanes with zeolite catalysts. An-Hui Lu is currently a professor of Dalian University of Technology, and vice director of the State Key Laboratory of Fine Chemicals. He received the National Science Fund for Distinguished Young Scholars of China (2012), Cheung Kong Scholar by the Ministry of Education of China (2015). He has authored and co-authored more than 200 papers with citation over 17 000 times (H-index, 65). His research interests include synthesis of porous materials for heterogeneous catalysis, adsorption, energy storage and conversion. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 ObjectType-Review-3 content type line 23 |
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Snippet | Metal-free boron- and carbon-based catalysts have shown both great fundamental and practical value in oxidative dehydrogenation (ODH) of light alkanes. In... |
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SubjectTerms | active sites Alkanes Alkenes behavior Boron Carbon carbon dioxide Catalysts Dehydrogenation design Functional groups industrialization kinetics light materials methodology moieties Reaction mechanisms Selectivity society |
Title | Oxidative dehydrogenation of light alkanes to olefins on metal-free catalysts |
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