A highly concentrated electrolyte for high-efficiency potassium metal batteries

We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after...

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Published inChemical communications (Cambridge, England) Vol. 57; no. 8; pp. 134 - 137
Main Authors Xu, Wenxin, Wang, Huwei, Hu, Junyang, Zhang, Haodong, Zhang, Biao, Kang, Feiyu, Zhai, Dengyun
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 01.02.2021
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Abstract We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after 500 cycles) of K||potassium Prussian blue (KPB) batteries. A highly concentrated electrolyte enables dendrite-free cycling of K metal anodes with a high CE (over 98% over 400 cycles).
AbstractList We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after 500 cycles) of K||potassium Prussian blue (KPB) batteries.
We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after 500 cycles) of K||potassium Prussian blue (KPB) batteries. A highly concentrated electrolyte enables dendrite-free cycling of K metal anodes with a high CE (over 98% over 400 cycles).
We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after 500 cycles) of K||potassium Prussian blue (KPB) batteries.We report a highly concentrated electrolyte consisting of 4 M potassium bis(fluorosulfonyl)imide (KFSI) in diethylene glycol dimethyl ether (DEGDME). This new electrolyte enables stable cycling of K metal anodes with a high CE (over 98% over 400 cycles), and excellent capacity retention (99.7% after 500 cycles) of K||potassium Prussian blue (KPB) batteries.
Author Zhang, Biao
Hu, Junyang
Zhang, Haodong
Zhai, Dengyun
Xu, Wenxin
Wang, Huwei
Kang, Feiyu
AuthorAffiliation Tsinghua University
The Hong Kong Polytechnic University Kowloon
Tsinghua Shenzhen International Graduate School
Advanced Materials Institute
Department of Applied Physics
Shenzhen Key Laboratory for Graphene-Based Materials and Engineering Laboratory for Functionalized Carbon Materials
Shenzhen Environmental Science and New Energy Technology Engineering Laboratory
Tsinghua-Berkeley Shenzhen Institute (TBSI)
Shenzhen Geim Graphene Center
Graduate School at Shenzhen
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– name: Tsinghua Shenzhen International Graduate School
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– name: The Hong Kong Polytechnic University Kowloon
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SubjectTerms diethylene glycol
Dimethyl ether
Electrolytes
Pigments
Potassium
Title A highly concentrated electrolyte for high-efficiency potassium metal batteries
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