Molecularly Imprinted Titanium Dioxide: Synthesis Strategies and Applications in Photocatalytic Degradation of Antibiotics from Marine Wastewater: A Review

Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its speci...

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Published inMaterials Vol. 18; no. 9; p. 2161
Main Authors Han, Xue, Jin, Yu, Zhao, Luyang, Zhang, Yuying, Ren, Binqiao, Song, Xiaoxiao, Liu, Rui
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 07.05.2025
MDPI
Subjects
Adsorption
Antibiotics
Aquaculture
Biodegradation
Catalysis
Control systems
Drug resistance
Ecosystems
Efficiency
Electric fields
Energy consumption
Environmental protection
Low concentrations
Marine environment
Methylene blue
Microorganisms
Molecular imprinting
Oxidation
Oxytetracycline
Pharmaceutical industry
Photocatalysis
Photodegradation
Pollutants
Pollution
Pollution control
Recoverability
Review
Salinity
Selectivity
Sulfonamides
Synergistic effect
Tetracyclines
Titanium
Titanium dioxide
Wastewater
Wastewater treatment
China
photocatalysis
antibiotics
molecularly imprinted
TiO2
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Abstract Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO2) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO2 (MI-TiO2) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO2 significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO2 in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
AbstractList Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO2) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO2 (MI-TiO2) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO2 significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO2 in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO ) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO (MI-TiO ) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO 2 ) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO 2 (MI-TiO 2 ) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO 2 significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO 2 in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO[sub.2]) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO[sub.2] (MI-TiO[sub.2]) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO[sub.2] significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO[sub.2] in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO2) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO2 (MI-TiO2) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO2 significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO2 in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and selective pollution control technologies. Molecular imprinting technology (MIT) provides a new idea for antibiotic pollution control with its specific recognition and targeted removal ability. However, traditional titanium dioxide (TiO2) photocatalysts have limited degradation efficiency and lack of selectivity for low concentrations of antibiotics. This paper reviews the preparation strategy and modification means of molecularly imprinted TiO2 (MI-TiO2) and its composites and systematically explores its application mechanism and performance advantages in marine antibiotic wastewater treatment. It was shown that MI-TiO2 significantly enhanced the selective degradation efficiency of antibiotics such as tetracyclines and sulfonamides through the enrichment of target pollutants by specifically imprinted cavities, combined with the efficient generation of photocatalytic reactive oxygen species (ROS). In addition, emerging technologies such as magnetic/electric field-assisted catalysis and photothermal synergistic effect further optimized the recoverability and stability of the catalysts. This paper provides theoretical support for the practical application of MI-TiO2 in complex marine pollution systems and looks forward to its future development in the field of environmental remediation.
Audience Academic
Author Liu, Rui
Jin, Yu
Song, Xiaoxiao
Zhao, Luyang
Zhang, Yuying
Han, Xue
Ren, Binqiao
AuthorAffiliation 1 Institute of Advanced Technology, Heilongjiang Academy of Sciences, Harbin 150009, China; hxyep883@163.com (X.H.); jinyu36@126.com (Y.J.); zly516678@163.com (L.Z.); 18847008955@163.com (Y.Z.)
2 Heilongjiang Institute of Environmental and Sciences, Harbin 150056, China
3 Center of Pharmaceutical Engineering and Technology, Harbin University of Commerce, Harbin 150076, China
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Snippet Antibiotic residues in the marine environment pose a serious threat to ecosystems and human health, and there is an urgent need to develop efficient and...
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SubjectTerms Adsorption
Antibiotics
Aquaculture
Biodegradation
Catalysis
Control systems
Drug resistance
Ecosystems
Efficiency
Electric fields
Energy consumption
Environmental protection
Low concentrations
Marine environment
Methylene blue
Microorganisms
Molecular imprinting
Oxidation
Oxytetracycline
Pharmaceutical industry
Photocatalysis
Photodegradation
Pollutants
Pollution
Pollution control
Recoverability
Review
Salinity
Selectivity
Sulfonamides
Synergistic effect
Tetracyclines
Titanium
Titanium dioxide
Wastewater
Wastewater treatment
Title Molecularly Imprinted Titanium Dioxide: Synthesis Strategies and Applications in Photocatalytic Degradation of Antibiotics from Marine Wastewater: A Review
URI https://www.ncbi.nlm.nih.gov/pubmed/40363665
https://www.proquest.com/docview/3203208723
https://www.proquest.com/docview/3203923485
https://pubmed.ncbi.nlm.nih.gov/PMC12073087
Volume 18
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