Catalytic activity of cobalt and cerium catalysts supported on calcium hydroxyapatite in ethanol steam reforming

In this paper, Co,Ce/Ca (PO (OH) catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H , N adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests....

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Published inPolish journal of chemical technology Vol. 18; no. 3; pp. 59 - 67
Main Authors Dobosz, Justyna, Hull, Sylwia, Zawadzki, Mirosław
Format Journal Article
LanguageEnglish
Published De Gruyter Open 01.09.2016
Sciendo
Subjects
cerium
cobalt
ethanol steam reforming
hydrogen production
hydroxyapatite
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Abstract In this paper, Co,Ce/Ca (PO (OH) catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H , N adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests. High ethanol conversion (close to 100%) was obtained for the catalysts prepared by both methods but these ones prepared under hydrothermal conditions (HAp-H) ensured higher hydrogen yield (3.49 mol H /mol C OH) as well as higher amount of hydrogen formed (up to 70%) under reaction conditions. The superior performance of 5Co,10Ce/HAp-H catalyst is thought to be due to a combination of factors, including increased reducibility and oxygen mobility, higher density of basic sites on its surface, and improved textural properties. The results also show a significant effect of cobalt loading on catalysts efficiency in hydrogen production: the higher H yield exhibit catalysts with lower cobalt content, regardless of the used synthesis method.
AbstractList In this paper, Co,Ce/Ca (PO (OH) catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H , N adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests. High ethanol conversion (close to 100%) was obtained for the catalysts prepared by both methods but these ones prepared under hydrothermal conditions (HAp-H) ensured higher hydrogen yield (3.49 mol H /mol C OH) as well as higher amount of hydrogen formed (up to 70%) under reaction conditions. The superior performance of 5Co,10Ce/HAp-H catalyst is thought to be due to a combination of factors, including increased reducibility and oxygen mobility, higher density of basic sites on its surface, and improved textural properties. The results also show a significant effect of cobalt loading on catalysts efficiency in hydrogen production: the higher H yield exhibit catalysts with lower cobalt content, regardless of the used synthesis method.
In this paper, Co,Ce/Ca10(PO4)6(OH)2 catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H2, N2 adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests. High ethanol conversion (close to 100%) was obtained for the catalysts prepared by both methods but these ones prepared under hydrothermal conditions (HAp-H) ensured higher hydrogen yield (3.49 mol H2/mol C2H5OH) as well as higher amount of hydrogen formed (up to 70%) under reaction conditions. The superior performance of 5Co,10Ce/HAp-H catalyst is thought to be due to a combination of factors, including increased reducibility and oxygen mobility, higher density of basic sites on its surface, and improved textural properties. The results also show a significant effect of cobalt loading on catalysts efficiency in hydrogen production: the higher H2 yield exhibit catalysts with lower cobalt content, regardless of the used synthesis method.
Abstract In this paper, Co,Ce/Ca 10 (PO 4 ) 6 (OH) 2 catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H 2 , N 2 adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests. High ethanol conversion (close to 100%) was obtained for the catalysts prepared by both methods but these ones prepared under hydrothermal conditions (HAp-H) ensured higher hydrogen yield (3.49 mol H 2 /mol C 2 H 5 OH) as well as higher amount of hydrogen formed (up to 70%) under reaction conditions. The superior performance of 5Co,10Ce/HAp-H catalyst is thought to be due to a combination of factors, including increased reducibility and oxygen mobility, higher density of basic sites on its surface, and improved textural properties. The results also show a significant effect of cobalt loading on catalysts efficiency in hydrogen production: the higher H 2 yield exhibit catalysts with lower cobalt content, regardless of the used synthesis method.
Author Dobosz, Justyna
Hull, Sylwia
Zawadzki, Mirosław
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CitedBy_id crossref_primary_10_1007_s10971_020_05245_8
crossref_primary_10_1016_j_ceramint_2020_04_103
crossref_primary_10_1016_j_fuel_2018_02_139
crossref_primary_10_1016_j_jechem_2017_12_004
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Snippet In this paper, Co,Ce/Ca (PO (OH) catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal...
Abstract In this paper, Co,Ce/Ca 10 (PO 4 ) 6 (OH) 2 catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by...
In this paper, Co,Ce/Ca10(PO4)6(OH)2 catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted...
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walterdegruyter
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StartPage 59
SubjectTerms cerium
cobalt
ethanol steam reforming
hydrogen production
hydroxyapatite
Title Catalytic activity of cobalt and cerium catalysts supported on calcium hydroxyapatite in ethanol steam reforming
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https://doaj.org/article/96a2965ae0d1409ba48c072f649d7e15
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