Molecular and heterogenized dinuclear Ir-Cp water oxidation catalysts bearing EDTA or EDTMP as bridging and anchoring ligands
[Display omitted] The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)2(μ-κ3-O,N,O-H4-EDTMP)] (Ir-H4-EDTMP, H4-EDTMP4− = ethylenediamine...
Saved in:
| Published in | Science bulletin Vol. 65; no. 19; pp. 1614 - 1625 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Netherlands
Elsevier B.V
15.10.2020
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | [Display omitted]
The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)2(μ-κ3-O,N,O-H4-EDTMP)] (Ir-H4-EDTMP, H4-EDTMP4− = ethylenediamine tetra(methylene phosphonate)) and [(Cp*Ir)2(μ-κ3-O,N,O-EDTA)] (Ir-EDTA, EDTA4− = ethylenediaminetetraacetate), were synthesized and completely characterized in solution, by multinuclear and multidimensional NMR spectroscopy, and in the solid state, by single crystal X-Ray diffraction. They were supported onto rutile TiO2 nanocrystals obtaining Ir-H4-EDTMP@TiO2 and Ir-EDTA@TiO2 hybrid materials. Both molecular complexes and hybrid materials were found to be efficient catalysts for WO driven by NaIO4, providing almost quantitative yields, and TON values only limited by the amount of NaIO4 used. As for the molecular catalysts, Ir-H4-EDTMP (TOF up to 184 min−1) exhibited much higher activity than Ir-EDTA (TOF up to 19 min−1), likely owing to the higher propensity of the former to generate a coordination vacancy through the dissociation of a Ir–OP bond (2.123 Å, significantly longer than Ir–OC, 2.0913 Å), which is a necessary step to activate these saturated complexes. Ir-H4-EDTMP@TiO2 (up to 33 min−1) and Ir-EDTA@TiO2 (up to 41 min−1) hybrid materials showed similar activity that was only marginally reduced in the second and third catalytic runs carried out after having separated the supernatant, which did not show any sign of activity, instead. The observed TOF values for hybrid materials are higher than those reported for analogous systems deriving from heterogenized mononuclear complexes. This suggests that supporting dinuclear molecular precursors could be a successful strategy to obtain efficient heterogenized water oxidation catalysts. |
|---|---|
| AbstractList | The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)
(μ-κ
-O,N,O-H
-EDTMP)] (Ir-H
-EDTMP, H
-EDTMP
= ethylenediamine tetra(methylene phosphonate)) and [(Cp*Ir)
(μ-κ
-O,N,O-EDTA)] (Ir-EDTA, EDTA
= ethylenediaminetetraacetate), were synthesized and completely characterized in solution, by multinuclear and multidimensional NMR spectroscopy, and in the solid state, by single crystal X-Ray diffraction. They were supported onto rutile TiO
nanocrystals obtaining Ir-H
-EDTMP@TiO
and Ir-EDTA@TiO
hybrid materials. Both molecular complexes and hybrid materials were found to be efficient catalysts for WO driven by NaIO
, providing almost quantitative yields, and TON values only limited by the amount of NaIO
used. As for the molecular catalysts, Ir-H
-EDTMP (TOF up to 184 min
) exhibited much higher activity than Ir-EDTA (TOF up to 19 min
), likely owing to the higher propensity of the former to generate a coordination vacancy through the dissociation of a Ir-OP bond (2.123 Å, significantly longer than Ir-OC, 2.0913 Å), which is a necessary step to activate these saturated complexes. Ir-H
-EDTMP@TiO
(up to 33 min
) and Ir-EDTA@TiO
(up to 41 min
) hybrid materials showed similar activity that was only marginally reduced in the second and third catalytic runs carried out after having separated the supernatant, which did not show any sign of activity, instead. The observed TOF values for hybrid materials are higher than those reported for analogous systems deriving from heterogenized mononuclear complexes. This suggests that supporting dinuclear molecular precursors could be a successful strategy to obtain efficient heterogenized water oxidation catalysts. The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)2(μ-κ3-O,N,O-H4-EDTMP)] (Ir-H4-EDTMP, H4-EDTMP4− = ethylenediamine tetra(methylene phosphonate)) and [(Cp*Ir)2(μ-κ3-O,N,O-EDTA)] (Ir-EDTA, EDTA4− = ethylenediaminetetraacetate), were synthesized and completely characterized in solution, by multinuclear and multidimensional NMR spectroscopy, and in the solid state, by single crystal X-Ray diffraction. They were supported onto rutile TiO2 nanocrystals obtaining Ir-H4-EDTMP@TiO2 and Ir-EDTA@TiO2 hybrid materials. Both molecular complexes and hybrid materials were found to be efficient catalysts for WO driven by NaIO4, providing almost quantitative yields, and TON values only limited by the amount of NaIO4 used. As for the molecular catalysts, Ir-H4-EDTMP (TOF up to 184 min−1) exhibited much higher activity than Ir-EDTA (TOF up to 19 min−1), likely owing to the higher propensity of the former to generate a coordination vacancy through the dissociation of a Ir–OP bond (2.123 Å, significantly longer than Ir–OC, 2.0913 Å), which is a necessary step to activate these saturated complexes. Ir-H4-EDTMP@TiO2 (up to 33 min−1) and Ir-EDTA@TiO2 (up to 41 min−1) hybrid materials showed similar activity that was only marginally reduced in the second and third catalytic runs carried out after having separated the supernatant, which did not show any sign of activity, instead. The observed TOF values for hybrid materials are higher than those reported for analogous systems deriving from heterogenized mononuclear complexes. This suggests that supporting dinuclear molecular precursors could be a successful strategy to obtain efficient heterogenized water oxidation catalysts. [Display omitted] The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing renewable fuels. Herein, two novel dinuclear complexes, [(Cp*Ir)2(μ-κ3-O,N,O-H4-EDTMP)] (Ir-H4-EDTMP, H4-EDTMP4− = ethylenediamine tetra(methylene phosphonate)) and [(Cp*Ir)2(μ-κ3-O,N,O-EDTA)] (Ir-EDTA, EDTA4− = ethylenediaminetetraacetate), were synthesized and completely characterized in solution, by multinuclear and multidimensional NMR spectroscopy, and in the solid state, by single crystal X-Ray diffraction. They were supported onto rutile TiO2 nanocrystals obtaining Ir-H4-EDTMP@TiO2 and Ir-EDTA@TiO2 hybrid materials. Both molecular complexes and hybrid materials were found to be efficient catalysts for WO driven by NaIO4, providing almost quantitative yields, and TON values only limited by the amount of NaIO4 used. As for the molecular catalysts, Ir-H4-EDTMP (TOF up to 184 min−1) exhibited much higher activity than Ir-EDTA (TOF up to 19 min−1), likely owing to the higher propensity of the former to generate a coordination vacancy through the dissociation of a Ir–OP bond (2.123 Å, significantly longer than Ir–OC, 2.0913 Å), which is a necessary step to activate these saturated complexes. Ir-H4-EDTMP@TiO2 (up to 33 min−1) and Ir-EDTA@TiO2 (up to 41 min−1) hybrid materials showed similar activity that was only marginally reduced in the second and third catalytic runs carried out after having separated the supernatant, which did not show any sign of activity, instead. The observed TOF values for hybrid materials are higher than those reported for analogous systems deriving from heterogenized mononuclear complexes. This suggests that supporting dinuclear molecular precursors could be a successful strategy to obtain efficient heterogenized water oxidation catalysts. |
| Author | Costantino, Ferdinando Valentini, Massimiliano Tensi, Leonardo Macchioni, Alceo Kissimina, Nade Zaccaria, Francesco D'Amato, Roberto Domestici, Chiara Zuccaccia, Cristiano |
| Author_xml | – sequence: 1 givenname: Chiara surname: Domestici fullname: Domestici, Chiara organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 2 givenname: Leonardo surname: Tensi fullname: Tensi, Leonardo organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 3 givenname: Francesco surname: Zaccaria fullname: Zaccaria, Francesco email: francesco.zaccaria@unipg.it organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 4 givenname: Nade surname: Kissimina fullname: Kissimina, Nade organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 5 givenname: Massimiliano surname: Valentini fullname: Valentini, Massimiliano organization: Department of Chemistry, Sultan Qaboos University, Muscat 123, Oman – sequence: 6 givenname: Roberto surname: D'Amato fullname: D'Amato, Roberto organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 7 givenname: Ferdinando surname: Costantino fullname: Costantino, Ferdinando email: ferdinando.costantino@unipg.it organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 8 givenname: Cristiano surname: Zuccaccia fullname: Zuccaccia, Cristiano email: cristiano.zuccaccia@unipg.it organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy – sequence: 9 givenname: Alceo surname: Macchioni fullname: Macchioni, Alceo email: alceo.macchioni@unipg.it organization: Department of Chemistry, Biology and Biotechnology, University of Perugia and CIRCC, Perugia 06123, Italy |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/36659037$$D View this record in MEDLINE/PubMed https://hal.science/hal-02935124$$DView record in HAL |
| BookMark | eNp9kEFv1DAQhS3UipbSP8AB-cohYew4TixxWS2FVtqqPZSz5djOrlepvbKzLUXiv2OzsMeeZjTve0-a9w6d-OAtQh8I1AQI_7ytk3ZDTYFCDbwG0r5B5xREWwnak5Pj3jVn6DKlLQAQJiiD7i06azhvBTTdOfp9Gyar95OKWHmDN3a2Maytd7-swcb5vZ5s1m5itdzhZ5VVHH46o2YXPNZqVtNLmhMeMuT8Gl99fVjgEMu8vccqC9GZdVFKuvJ6E_5yk1vnQ3qPTkc1JXv5b16gH9-uHpbX1eru-81ysao0a9hcmYECGTVoxnRnRQvKjETbfhi5FoMARk3f5-cE56MZtSUDEEU6w0emesNJc4E-HXI3apK76B5VfJFBOXm9WMlyAyqallD2VFh6YHUMKUU7Hg0EZKlebmWpXpbqJXCZq8-mjwfTbj88WnO0_C86A18OgM1vPjkbS4b12hoXrZ6lCe61_D-qNpdb |
| CitedBy_id | crossref_primary_10_1016_j_xcrp_2021_100495 crossref_primary_10_1002_ejic_202300211 crossref_primary_10_1002_ejic_202300300 crossref_primary_10_1039_D0CY02306J crossref_primary_10_1016_j_ica_2020_120161 crossref_primary_10_1021_acsami_0c07925 crossref_primary_10_1002_cjoc_202100285 crossref_primary_10_1016_j_ijhydene_2021_02_087 crossref_primary_10_1039_D1CY01087E crossref_primary_10_1002_ejic_202001003 crossref_primary_10_1016_j_jcis_2023_03_080 crossref_primary_10_1002_aenm_202300896 crossref_primary_10_1021_acscatal_0c03350 crossref_primary_10_1021_acs_organomet_1c00464 |
| Cites_doi | 10.1039/C8CS00660A 10.1002/chem.201304412 10.1039/b910241h 10.1021/ar900209b 10.1002/anie.201609167 10.1002/ejic.201800451 10.1021/acsami.6b04510 10.1021/ic0611793 10.1039/C6DT00809G 10.3390/inorganics7100123 10.1002/ejic.201801328 10.1039/C9DT04306C 10.1073/pnas.1319628110 10.1038/ncomms7469 10.1039/C9DT04841C 10.1039/C3CS60405E 10.1021/ja3033026 10.1039/C5DT00863H 10.1002/anie.201203560 10.1021/acscatal.7b01883 10.1039/c1gc15899f 10.1039/c3dt51517f 10.1021/acscatal.6b01101 10.1021/jacs.7b07361 10.1002/zaac.201000044 10.1016/S0020-1693(00)87353-3 10.1016/0020-1693(95)05011-6 10.1021/ic050904r 10.1002/anie.201504427 10.1126/science.1162018 10.1002/anie.201005260 10.1038/nchem.1301 10.1021/ic501018a 10.1021/acscentsci.8b00335 10.1134/S0036023614060114 10.1021/acscatal.7b02387 10.1002/9780470132609.ch53 10.1007/BF01025674 10.1002/cctc.201901092 10.1002/cssc.201701818 10.1039/c1ee01037a 10.1016/j.jssc.2007.03.011 10.1007/s12274-019-2383-y 10.1039/C8DT00485D 10.1021/ja203095k 10.1021/jacs.5b06541 10.1039/c0cc05108j 10.1021/cs501590k 10.1002/cctc.201800916 10.1002/cssc.201200067 10.1021/ic990364w 10.1038/nature16529 10.1021/acscatal.5b00319 10.1002/cssc.200700087 10.1002/asia.201801253 10.1039/C8TA01304G 10.1021/cm001253u 10.1073/pnas.1001132107 10.3390/inorganics7030029 10.1002/aenm.201900399 10.1002/cssc.201701370 10.1002/cctc.201500051 10.1073/pnas.1722137115 10.1021/acsenergylett.6b00606 10.1021/acsenergylett.8b00847 10.1021/ic50082a016 10.1021/ja4086808 10.1039/C7DT04555G 10.1021/ja203564w 10.1002/ejic.201800798 10.1021/acs.chemrev.6b00398 10.1016/S0277-5387(01)01005-1 10.1021/jacs.7b06096 10.1073/pnas.0603395103 10.1021/cm8012683 10.1021/ic00132a021 10.1016/j.cattod.2015.08.014 10.1021/ja310074j 10.1021/acs.jpcc.6b02635 10.1021/om300071v 10.1038/s41570-019-0096-0 10.1021/ja4048762 10.1038/ncomms6865 10.1016/j.poly.2017.11.007 10.1039/C7CS00306D 10.1021/jz2016507 10.1021/ja104775j 10.1021/acsami.8b04138 10.1021/ja407115p 10.1039/C2DT32424E 10.1021/jacs.5b10215 10.1002/chem.201303796 10.1002/chem.201602008 10.1021/ja01602a010 10.1002/ejic.201300530 10.1016/j.ica.2006.03.027 10.1039/C5TA00369E 10.1002/chem.201705619 10.1002/chem.201801572 10.1039/C7CS00314E 10.1002/ejic.201100954 10.1021/acscatal.0c00531 10.1016/S0020-1693(00)89632-2 10.1039/c0dt00454e 10.1021/cr400572f 10.1021/ja901270f 10.1002/anie.201601943 10.1039/c0cc03801f |
| ContentType | Journal Article |
| Copyright | 2020 Science China Press Copyright © 2020 Science China Press. Published by Elsevier B.V. All rights reserved. Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: 2020 Science China Press – notice: Copyright © 2020 Science China Press. Published by Elsevier B.V. All rights reserved. – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | NPM AAYXX CITATION 1XC VOOES |
| DOI | 10.1016/j.scib.2020.06.015 |
| DatabaseName | PubMed CrossRef Hyper Article en Ligne (HAL) Hyper Article en Ligne (HAL) (Open Access) |
| DatabaseTitle | PubMed CrossRef |
| DatabaseTitleList | PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Sciences (General) |
| EISSN | 2095-9281 |
| EndPage | 1625 |
| ExternalDocumentID | oai_HAL_hal_02935124v1 10_1016_j_scib_2020_06_015 36659037 S2095927320303947 |
| Genre | Journal Article |
| GroupedDBID | --M 0R~ 4.4 5VR AACTN AAEDT AAEDW AAIAV AAJKR AAKOC AALRI AAOAW AARTL AAXUO AAYIU ABBBX ABJNI ABMAC ABQEM ABQYD ABTHY ABUDA ABYKQ ACDAQ ACGFS ACIWK ACKNC ACPRK ACRLP ADBBV ADINQ AEBSH AEGNC AEHWI AEJHL AENEX AFKWA AFRAH AFTJW AFUIB AFXIZ AFZHZ AFZKB AGUBO AGWZB AGYKE AHBYD AHJVU AIEXJ AIIXL AIKHN AITUG AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG ATOGT AUKKA AVWKF AXJTR AZFZN BGNMA BJAXD BKOJK CCEZO CCVFK CHBEP EBS EFJIC EFLBG FA0 FDB FIRID FRRFC FYGXN IXD KOM KOV M41 M4Y NU0 O9- ROL RSV SOJ SPC SPCBC SSE SSK SST SSU SSZ T5K ~G- NPM -SA -S~ 5XA 5XB AAIAL AANXM AAQFI AAXDM AAXKI AAYQN AAYTO AAYXX ABJOX ABTEG ABTMW ACBXY ADKPE ADRFC ADVLN AEOHA AEPYU AFBBN AFJKZ AFLOW AGJBK AGQMX AHAVH AHSBF AJBLW AKRWK AMKLP CAJEA CITATION CJPJV CSCUP EJD H13 HX~ Q-- TCJ TGP U1G U5K UG4 1XC AAYZH VOOES |
| ID | FETCH-LOGICAL-c434t-db201fc0c44c7e950adf1ce8bf6c9b9042d88492966fdfce1b01a17d6f4a8d613 |
| IEDL.DBID | AIKHN |
| ISSN | 2095-9273 |
| IngestDate | Tue Oct 15 15:02:04 EDT 2024 Thu Sep 26 18:41:18 EDT 2024 Wed Mar 20 10:58:35 EDT 2024 Fri Feb 23 02:49:29 EST 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 19 |
| Keywords | Renewable fuels Heterogenized catalysts Organometallic chemistry Dinuclear complexes Water oxidation Homogeneous catalysis |
| Language | English |
| License | Copyright © 2020 Science China Press. Published by Elsevier B.V. All rights reserved. Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c434t-db201fc0c44c7e950adf1ce8bf6c9b9042d88492966fdfce1b01a17d6f4a8d613 |
| OpenAccessLink | https://hal.science/hal-02935124 |
| PMID | 36659037 |
| PageCount | 12 |
| ParticipantIDs | hal_primary_oai_HAL_hal_02935124v1 crossref_primary_10_1016_j_scib_2020_06_015 pubmed_primary_36659037 elsevier_sciencedirect_doi_10_1016_j_scib_2020_06_015 |
| PublicationCentury | 2000 |
| PublicationDate | 2020-10-15 |
| PublicationDateYYYYMMDD | 2020-10-15 |
| PublicationDate_xml | – month: 10 year: 2020 text: 2020-10-15 day: 15 |
| PublicationDecade | 2020 |
| PublicationPlace | Netherlands |
| PublicationPlace_xml | – name: Netherlands |
| PublicationTitle | Science bulletin |
| PublicationTitleAlternate | Sci Bull (Beijing) |
| PublicationYear | 2020 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Codolà, Gómez, Kleespies (b0065) 2015; 6 Sheehan, Thomsen, Hintermair (b0115) 2015; 6 Aizawa, Natsume, Hatano (b0500) 1996; 248 Grotjahn, Brown, Martin (b0300) 2011; 133 Li, Güttinger, Moré (b0070) 2017; 46 Van Dijk, Menendez Rodriguez, Wu (b0325) 2020; 10 Mahanti, González Miera, Martínez-Castro (b0290) 2017; 10 Vshivtseva, Fridman, Zhadanov (b0465) 1978; 4 Creus, Matheu, Peñafiel (b0055) 2016; 55 Savini, Bucci, Nocchetti (b0095) 2015; 5 Li, Sheehan, He (b0340) 2015; 54 Llobet (b0050) 2014 Materna, Rudshteyn, Brennan (b0105) 2016; 6 Hintermair, Sheehan, Parent (b0320) 2013; 135 Matheu, Garrido-Barros, Gil-Sepulcre (b0170) 2019; 3 Savini, Belanzoni, Bellachioma (b0305) 2011; 13 Hintermair, Hashmi, Elimelech (b0315) 2012; 134 Navarro, Li, Bernhard (b0225) 2018; 47 Fairley, Unruh, Donovan (b0495) 2013; 42 Corbucci, Petronilho, Müller-Bunz (b0265) 2015; 5 Venturini, Barbieri, Reek (b0285) 2014; 20 Zhao, Yang, Wang (b0430) 2018; 115 Duan, Bozoglian, Mandal (b0045) 2012; 4 Mavrokefalos, Patzke (b0165) 2019; 7 Rodriguez, Gatto, Zuccaccia (b0270) 2017; 10 Blakemore, Schley, Balcells (b0255) 2010; 132 Menendez Rodriguez, Bucci, Hutchinson (b0275) 2017; 2 Alstrum-Acevedo, Brennaman, Meyer (b0015) 2005; 44 Niu, Wang, Li (b0415) 2019; 10 Chen, Concepcion, Hu (b0090) 2010; 107 Zhao, Yan, Yang (b0435) 2018; 4 Materna, Jiang, Crabtree (b0410) 2019; 11 Yamasaki, Shibahara (b0525) 1993; 205 Labed, Jiang, Labed (b0480) 2015; 7 Guerre, Mutin, Vioux (b0395) 2001; 13 Liu, Moré, Grundmann (b0140) 2016; 138 Venkateswara Rao, Palta, Puri (b0460) 1988; 13 McCrory, Jung, Peters (b0135) 2013; 135 McNamara, Snoeberger, Li (b0405) 2009; 2 Wang, Andy Hor, Yan (b0535) 2006; 359 Lewis, Nocera (b0020) 2006; 103 Gerlach, Bhagan, Cruce (b0060) 2014; 53 Popov, Shemyakina, Dyatlova (b0570) 1981; 7 Wang, Xie, deKrafft (b0365) 2011; 133 Zuccaccia, Bellachioma, Bolaño (b0310) 2012; 9 Matheu, Ertem, Benet-Buchholz (b0180) 2015; 137 Ledendecker, Geiger, Hengge (b0195) 2019; 12 edta Wan, Wang, Dong (b0120) 2018; 3 Fridman, Vshivtseva, Barkhanova (b0470) 1976; 2 Cherevko, Geiger, Kasian (b0150) 2016; 262 Wang, Wang, Lin (b0130) 2012; 134 Klepser, Bartlett (b0380) 2014; 136 Savini, Bucci, Bellachioma (b0010) 2014; 4 Lee, Suntivich, May (b0155) 2012; 3 Chen, Hoffmann, Prots (b0490) 2010; 636 Liu, Zhang, Sun (b0205) 2019; 14 Luo, Xu (b0510) 2006; 45 Moore, Blakemore, Milot (b0335) 2011; 4 Kärkäs, Verho, Johnston (b0190) 2014; 114 Odrobina, Scholz, Risch (b0385) 2017; 7 Bucci, Dunn, Bellachioma (b0260) 2017; 7 Liu, Li, Wu (b0355) 2016; 8 Zhao, Zhang, Wang (b0360) 2018; 47 Cayemittes, Poth, Fernandez (b0455) 1999; 38 Zuccaccia, Bellachioma, Bortolini (b0330) 2014; 20 Pastori, Wahab, Bucci (b0100) 2016; 22 Ressnig, Shalom, Patscheider (b0125) 2015; 3 Lalrempuia, McDaniel, Müller-Bunz (b0245) 2010; 49 Bae, Jang, Lee (b0420) 2019; 15 Xie, Shaffer, Lewandowska-Andralojc (b0575) 2016; 55 Macchioni (b0175) 2019; 1 Liu, Xu, Gao (b0550) 2007; 180 Balzani, Credi, Venturi (b0025) 2008; 1 Krishnamurthy, Morris (b0560) 1968; 8 Savini, Bellachioma, Ciancaleoni (b0235) 2010; 46 Hull, Balcells, Blakemore (b0295) 2009; 131 Li, Zhu, Wang (b0445) 2020; 49 Leont’eva, Dyatlova (b0565) 1990; 16 Corbucci, Albrecht (b0185) 2017 Casadevall, Bucci, Costas (b0210) 2019; 74 Hunter, Gray, Müller (b0215) 2016; 116 Volpe, Natali, Graiff (b0220) 2020; 49 Shao, Yang, Huang (b0375) 2018; 24 Babailov, Zapolotsky (b0555) 2018; 139 Appleton, Hall, Lambert (b0545) 1978; 29 Annunziata, Esposito, Gatto (b0080) 2018; 28 Thomsen, Huang, Crabtree (b0005) 2015; 44 Sackville, Marken, Hintermair (b0240) 2018; 10 Savini, Bellachioma, Bolaño (b0425) 2012; 5 O: the first example of a cyclic nitrido-bridged tetrameric technetium complex . J Chem Soc Chem Commun, 2153–2154. Brennan, Koenigsmann, Materna (b0400) 2016; 120 6H Song, Moré, Schilling (b0085) 2017; 139 Materna, Crabtree, Brudvig (b0110) 2017; 46 Sarmah, Hazarika, Islam (b0505) 2002; 21 Gust, Moore, Moore (b0030) 2009; 42 Hetterscheid, Reek (b0250) 2011; 47 White, Yates, Maitlis (b0450) 1992; 29 Berardi, Drouet, Francàs (b0040) 2014; 43 Navarro, Smith, Li (b0280) 2018; 24 Brodard-Severac, Guerrero, Maquet (b0390) 2008; 20 Corbucci, Zaccaria, Heath (b0230) 2019; 11 Alibabaei, Brennaman, Norris (b0440) 2013; 110 Kornev, Buldakova, Didik (b0540) 2014; 59 Gatto, Macchioni, Bondi (b0370) 2019; 7 Cheng, Lin, Tseng (b0485) 2013; 42 Fagiolari, Zaccaria, Costantino (b0160) 2020; 49 Freeman, Schultz, Reilley (b0515) 1982; 21 McDaniel, Bernhard (b0035) 2010; 39 Kanan, Nocera (b0145) 2008; 321 Joya, Subbaiyan, D’Souza (b0345) 2012; 51 Okamura, Kondo, Kuga (b0075) 2016; 530 Liu, Jiang, Li (b0350) 2018; 6 Kärkäs, Åkermark (b0200) 2016; 45 Baldas J , Colmanet SF , Ivanov Z , et al. 1994. Preparation and structure of [{TcN(thiourea)} O, Lough, Morris (b0475) 2012; 31 Shaffer, Xie, Szalda (b0580) 2017; 139 Pecsok, Sawyer (b0520) 1956; 78 Cherevko (10.1016/j.scib.2020.06.015_b0150) 2016; 262 Kornev (10.1016/j.scib.2020.06.015_b0540) 2014; 59 Chen (10.1016/j.scib.2020.06.015_b0090) 2010; 107 Fagiolari (10.1016/j.scib.2020.06.015_b0160) 2020; 49 Ledendecker (10.1016/j.scib.2020.06.015_b0195) 2019; 12 Navarro (10.1016/j.scib.2020.06.015_b0225) 2018; 47 Cheng (10.1016/j.scib.2020.06.015_b0485) 2013; 42 Hunter (10.1016/j.scib.2020.06.015_b0215) 2016; 116 Van Dijk (10.1016/j.scib.2020.06.015_b0325) 2020; 10 Materna (10.1016/j.scib.2020.06.015_b0110) 2017; 46 Rodriguez (10.1016/j.scib.2020.06.015_b0270) 2017; 10 Bucci (10.1016/j.scib.2020.06.015_b0260) 2017; 7 Zhao (10.1016/j.scib.2020.06.015_b0435) 2018; 4 Chen (10.1016/j.scib.2020.06.015_b0490) 2010; 636 Pecsok (10.1016/j.scib.2020.06.015_b0520) 1956; 78 Savini (10.1016/j.scib.2020.06.015_b0010) 2014; 4 Lewis (10.1016/j.scib.2020.06.015_b0020) 2006; 103 Gust (10.1016/j.scib.2020.06.015_b0030) 2009; 42 Mavrokefalos (10.1016/j.scib.2020.06.015_b0165) 2019; 7 Krishnamurthy (10.1016/j.scib.2020.06.015_b0560) 1968; 8 Sarmah (10.1016/j.scib.2020.06.015_b0505) 2002; 21 Odrobina (10.1016/j.scib.2020.06.015_b0385) 2017; 7 Codolà (10.1016/j.scib.2020.06.015_b0065) 2015; 6 Brodard-Severac (10.1016/j.scib.2020.06.015_b0390) 2008; 20 Wan (10.1016/j.scib.2020.06.015_b0120) 2018; 3 Babailov (10.1016/j.scib.2020.06.015_b0555) 2018; 139 Corbucci (10.1016/j.scib.2020.06.015_b0185) 2017 Guerre (10.1016/j.scib.2020.06.015_b0395) 2001; 13 White (10.1016/j.scib.2020.06.015_b0450) 1992; 29 Shaffer (10.1016/j.scib.2020.06.015_b0580) 2017; 139 Zhao (10.1016/j.scib.2020.06.015_b0430) 2018; 115 Kärkäs (10.1016/j.scib.2020.06.015_b0200) 2016; 45 Corbucci (10.1016/j.scib.2020.06.015_b0265) 2015; 5 Zuccaccia (10.1016/j.scib.2020.06.015_b0310) 2012; 9 McNamara (10.1016/j.scib.2020.06.015_b0405) 2009; 2 Savini (10.1016/j.scib.2020.06.015_b0095) 2015; 5 Yamasaki (10.1016/j.scib.2020.06.015_b0525) 1993; 205 Savini (10.1016/j.scib.2020.06.015_b0235) 2010; 46 Niu (10.1016/j.scib.2020.06.015_b0415) 2019; 10 10.1016/j.scib.2020.06.015_b0530 Liu (10.1016/j.scib.2020.06.015_b0140) 2016; 138 Sheehan (10.1016/j.scib.2020.06.015_b0115) 2015; 6 Lee (10.1016/j.scib.2020.06.015_b0155) 2012; 3 Alibabaei (10.1016/j.scib.2020.06.015_b0440) 2013; 110 Freeman (10.1016/j.scib.2020.06.015_b0515) 1982; 21 Okamura (10.1016/j.scib.2020.06.015_b0075) 2016; 530 Venkateswara Rao (10.1016/j.scib.2020.06.015_b0460) 1988; 13 Savini (10.1016/j.scib.2020.06.015_b0305) 2011; 13 Song (10.1016/j.scib.2020.06.015_b0085) 2017; 139 Venturini (10.1016/j.scib.2020.06.015_b0285) 2014; 20 Labed (10.1016/j.scib.2020.06.015_b0480) 2015; 7 Fairley (10.1016/j.scib.2020.06.015_b0495) 2013; 42 McCrory (10.1016/j.scib.2020.06.015_b0135) 2013; 135 Gerlach (10.1016/j.scib.2020.06.015_b0060) 2014; 53 Liu (10.1016/j.scib.2020.06.015_b0205) 2019; 14 Ressnig (10.1016/j.scib.2020.06.015_b0125) 2015; 3 Materna (10.1016/j.scib.2020.06.015_b0105) 2016; 6 Luo (10.1016/j.scib.2020.06.015_b0510) 2006; 45 Matheu (10.1016/j.scib.2020.06.015_b0170) 2019; 3 Joya (10.1016/j.scib.2020.06.015_b0345) 2012; 51 Gatto (10.1016/j.scib.2020.06.015_b0370) 2019; 7 Navarro (10.1016/j.scib.2020.06.015_b0280) 2018; 24 Moore (10.1016/j.scib.2020.06.015_b0335) 2011; 4 Li (10.1016/j.scib.2020.06.015_b0340) 2015; 54 Li (10.1016/j.scib.2020.06.015_b0445) 2020; 49 Hull (10.1016/j.scib.2020.06.015_b0295) 2009; 131 Materna (10.1016/j.scib.2020.06.015_b0410) 2019; 11 Liu (10.1016/j.scib.2020.06.015_b0550) 2007; 180 Grotjahn (10.1016/j.scib.2020.06.015_b0300) 2011; 133 Bae (10.1016/j.scib.2020.06.015_b0420) 2019; 15 Annunziata (10.1016/j.scib.2020.06.015_b0080) 2018; 28 Wang (10.1016/j.scib.2020.06.015_b0130) 2012; 134 Menendez Rodriguez (10.1016/j.scib.2020.06.015_b0275) 2017; 2 Kärkäs (10.1016/j.scib.2020.06.015_b0190) 2014; 114 Li (10.1016/j.scib.2020.06.015_b0070) 2017; 46 Volpe (10.1016/j.scib.2020.06.015_b0220) 2020; 49 Berardi (10.1016/j.scib.2020.06.015_b0040) 2014; 43 Zhao (10.1016/j.scib.2020.06.015_b0360) 2018; 47 Blakemore (10.1016/j.scib.2020.06.015_b0255) 2010; 132 Liu (10.1016/j.scib.2020.06.015_b0355) 2016; 8 Fridman (10.1016/j.scib.2020.06.015_b0470) 1976; 2 Balzani (10.1016/j.scib.2020.06.015_b0025) 2008; 1 Aizawa (10.1016/j.scib.2020.06.015_b0500) 1996; 248 Thomsen (10.1016/j.scib.2020.06.015_b0005) 2015; 44 Kanan (10.1016/j.scib.2020.06.015_b0145) 2008; 321 Corbucci (10.1016/j.scib.2020.06.015_b0230) 2019; 11 Wang (10.1016/j.scib.2020.06.015_b0365) 2011; 133 Sackville (10.1016/j.scib.2020.06.015_b0240) 2018; 10 Matheu (10.1016/j.scib.2020.06.015_b0180) 2015; 137 Lalrempuia (10.1016/j.scib.2020.06.015_b0245) 2010; 49 Shao (10.1016/j.scib.2020.06.015_b0375) 2018; 24 Macchioni (10.1016/j.scib.2020.06.015_b0175) 2019; 1 Hintermair (10.1016/j.scib.2020.06.015_b0315) 2012; 134 Liu (10.1016/j.scib.2020.06.015_b0350) 2018; 6 O (10.1016/j.scib.2020.06.015_b0475) 2012; 31 Duan (10.1016/j.scib.2020.06.015_b0045) 2012; 4 Brennan (10.1016/j.scib.2020.06.015_b0400) 2016; 120 Alstrum-Acevedo (10.1016/j.scib.2020.06.015_b0015) 2005; 44 Mahanti (10.1016/j.scib.2020.06.015_b0290) 2017; 10 Klepser (10.1016/j.scib.2020.06.015_b0380) 2014; 136 Wang (10.1016/j.scib.2020.06.015_b0535) 2006; 359 Cayemittes (10.1016/j.scib.2020.06.015_b0455) 1999; 38 Popov (10.1016/j.scib.2020.06.015_b0570) 1981; 7 Xie (10.1016/j.scib.2020.06.015_b0575) 2016; 55 Vshivtseva (10.1016/j.scib.2020.06.015_b0465) 1978; 4 Llobet (10.1016/j.scib.2020.06.015_b0050) 2014 Zuccaccia (10.1016/j.scib.2020.06.015_b0330) 2014; 20 Savini (10.1016/j.scib.2020.06.015_b0425) 2012; 5 Hetterscheid (10.1016/j.scib.2020.06.015_b0250) 2011; 47 Creus (10.1016/j.scib.2020.06.015_b0055) 2016; 55 Casadevall (10.1016/j.scib.2020.06.015_b0210) 2019; 74 Hintermair (10.1016/j.scib.2020.06.015_b0320) 2013; 135 Appleton (10.1016/j.scib.2020.06.015_b0545) 1978; 29 McDaniel (10.1016/j.scib.2020.06.015_b0035) 2010; 39 Leont’eva (10.1016/j.scib.2020.06.015_b0565) 1990; 16 Pastori (10.1016/j.scib.2020.06.015_b0100) 2016; 22 |
| References_xml | – volume: 42 start-page: 1890 year: 2009 end-page: 1898 ident: b0030 article-title: Solar fuels via artificial photosynthesis publication-title: Acc Chem Res contributor: fullname: Moore – volume: 45 start-page: 11030 year: 2006 end-page: 11034 ident: b0510 article-title: Layered lanthanide molybdate pillared by chiral [λ-Mo publication-title: Inorg Chem contributor: fullname: Xu – volume: 4 start-page: 2389 year: 2011 end-page: 2392 ident: b0335 article-title: A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst publication-title: Energy Environ Sci contributor: fullname: Milot – volume: 45 start-page: 14421 year: 2016 end-page: 14461 ident: b0200 article-title: Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges publication-title: Dalton Trans contributor: fullname: Åkermark – volume: 47 start-page: 2712 year: 2011 ident: b0250 article-title: Me publication-title: Chem Commun contributor: fullname: Reek – volume: 42 start-page: 2765 year: 2013 end-page: 2772 ident: b0485 article-title: Syntheses, structures, and properties of multidimensional lithium coordination polymers based on aliphatic carboxylic acids publication-title: Dalt Trans contributor: fullname: Tseng – volume: 180 start-page: 1664 year: 2007 end-page: 1671 ident: b0550 article-title: Two-dimensional layer architecture assembled by Keggin polyoxotungstate, Cu(II)–EDTA complex and sodium linker: synthesis, crystal structures, and magnetic properties publication-title: J Solid State Chem contributor: fullname: Gao – volume: 139 start-page: 323 year: 2018 end-page: 326 ident: b0555 article-title: Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for publication-title: Polyhedron contributor: fullname: Zapolotsky – volume: 2 start-page: 1173 year: 2009 end-page: 1175 ident: b0405 article-title: Hydroxamate anchors for water-stable attachment to TiO publication-title: Energy Environ Sci contributor: fullname: Li – volume: 1 start-page: 7 year: 2019 end-page: 17 ident: b0175 article-title: The middle-earth between homogeneous and heterogeneous catalysis in water oxidation with iridium publication-title: Eur J Inorg Chem contributor: fullname: Macchioni – volume: 12 start-page: 2275 year: 2019 end-page: 2280 ident: b0195 article-title: Towards maximized utilization of iridium for the acidic oxygen evolution reaction publication-title: Nano Res contributor: fullname: Hengge – volume: 24 start-page: 15143 year: 2018 end-page: 15155 ident: b0375 article-title: The design of water oxidation electrocatalysts from nanoscale metal–organic frameworks publication-title: Chem Eur J contributor: fullname: Huang – volume: 59 start-page: 626 year: 2014 end-page: 631 ident: b0540 article-title: Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl publication-title: Russ J Inorg Chem contributor: fullname: Didik – volume: 107 start-page: 7225 year: 2010 end-page: 7229 ident: b0090 article-title: Concerted O atom-proton transfer in the O-O bond forming step in water oxidation publication-title: Proc Natl Acad Sci USA contributor: fullname: Hu – volume: 46 start-page: 6099 year: 2017 end-page: 6110 ident: b0110 article-title: Anchoring groups for photocatalytic water oxidation on metal oxide surfaces publication-title: Chem Soc Rev contributor: fullname: Brudvig – volume: 53 start-page: 12689 year: 2014 end-page: 12698 ident: b0060 article-title: Studies of the pathways open to copper water oxidation catalysts containing proximal hydroxy groups during basic electrocatalysis publication-title: Inorg Chem contributor: fullname: Cruce – volume: 530 start-page: 465 year: 2016 end-page: 468 ident: b0075 article-title: A pentanuclear iron catalyst designed for water oxidation publication-title: Nature contributor: fullname: Kuga – volume: 7 start-page: 1090 year: 2015 end-page: 1096 ident: b0480 article-title: Iridium-catalyzed sustainable access to functionalized julolidines through hydrogen autotransfer publication-title: ChemCatChem contributor: fullname: Labed – volume: 132 start-page: 16017 year: 2010 end-page: 16029 ident: b0255 article-title: Half-sandwich iridium complexes for homogeneous water-oxidation catalysis publication-title: J Am Chem Soc contributor: fullname: Balcells – volume: 10 start-page: 1900399 year: 2019 ident: b0415 article-title: Hybrid photoelectrochemical water splitting systems: from interface design to system assembly publication-title: Adv Energy Mater contributor: fullname: Li – volume: 1 start-page: 26 year: 2008 end-page: 58 ident: b0025 article-title: Photochemical conversion of solar energy publication-title: ChemSusChem contributor: fullname: Venturi – volume: 24 start-page: 6386 year: 2018 end-page: 6398 ident: b0280 article-title: Optimization of synthetically versatile pyridylidene amide ligands for efficient iridium-catalyzed water oxidation publication-title: Chem Eur J contributor: fullname: Li – volume: 8 start-page: 18577 year: 2016 end-page: 18583 ident: b0355 article-title: Improved photoelectrocatalytic performance for water oxidation by earth-abundant cobalt molecular porphyrin complex-integrated BiVO publication-title: ACS Appl Mater Interfaces contributor: fullname: Wu – volume: 7 start-page: 6235 year: 2017 end-page: 6244 ident: b0385 article-title: Chasing the Achilles’ heel in hybrid systems of diruthenium water oxidation catalysts anchored on indium tin oxide: the stability of the anchor publication-title: ACS Catal contributor: fullname: Risch – volume: 103 start-page: 15729 year: 2006 end-page: 15735 ident: b0020 article-title: Powering the planet: chemical challenges in solar energy utilization publication-title: Proc Natl Acad Sci USA contributor: fullname: Nocera – volume: 3 start-page: 5072 year: 2015 end-page: 5082 ident: b0125 article-title: Photochemical and electrocatalytic water oxidation activity of cobalt carbodiimide publication-title: J Mater Chem A contributor: fullname: Patscheider – volume: 7 start-page: 1522 year: 1981 end-page: 1526 ident: b0570 article-title: Formation of a mixed binuclear compound of rhodium(III) with ethylenediaminetetraacetate and chloride ions and with ethylenediamine publication-title: Koord Khimiya contributor: fullname: Dyatlova – volume: 10 start-page: 4616 year: 2017 end-page: 4623 ident: b0290 article-title: Homogeneous water oxidation by half-sandwich iridium(III) N-heterocyclic carbene complexes with pendant hydroxy and amino groups publication-title: ChemSusChem contributor: fullname: Martínez-Castro – volume: 5 start-page: 264 year: 2015 end-page: 271 ident: b0095 article-title: Activity and recyclability of an iridium–EDTA water oxidation catalyst immobilized onto rutile TiO publication-title: ACS Catal contributor: fullname: Nocchetti – volume: 55 start-page: 15382 year: 2016 end-page: 15386 ident: b0055 article-title: A million turnover molecular anode for catalytic water oxidation publication-title: Angew Chem Int Ed contributor: fullname: Peñafiel – volume: 6 start-page: 5371 year: 2016 end-page: 5377 ident: b0105 article-title: Heterogenized iridium water-oxidation catalyst from a silatrane precursor publication-title: ACS Catal contributor: fullname: Brennan – volume: 49 start-page: 2468 year: 2020 end-page: 2476 ident: b0160 article-title: Ir- and Ru-doped layered double hydroxides as affordable heterogeneous catalysts for electrochemical water oxidation publication-title: Dalton Trans contributor: fullname: Costantino – volume: 54 start-page: 11428 year: 2015 end-page: 11432 ident: b0340 article-title: Hematite-based solar water splitting in acidic solutions: functionalization by mono- and multilayers of iridium oxygen-evolution catalysts publication-title: Angew Chem Int Ed contributor: fullname: He – volume: 43 start-page: 7501 year: 2014 end-page: 7519 ident: b0040 article-title: Molecular artificial photosynthesis publication-title: Chem Soc Rev contributor: fullname: Francàs – volume: 13 start-page: 4367 year: 2001 end-page: 4373 ident: b0395 article-title: Anchoring of phosphonate and phosphinate coupling molecules on titania particles publication-title: Chem Mater contributor: fullname: Vioux – volume: 3 start-page: 331 year: 2019 end-page: 341 ident: b0170 article-title: The development of molecular water oxidation catalysts publication-title: Nat Rev Chem contributor: fullname: Gil-Sepulcre – volume: 42 start-page: 13706 year: 2013 end-page: 13714 ident: b0495 article-title: Synthesis and characterization of homo- and heteronuclear molecular Al publication-title: Dalt Trans contributor: fullname: Donovan – volume: 137 start-page: 10786 year: 2015 end-page: 10795 ident: b0180 article-title: Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex publication-title: J Am Chem Soc contributor: fullname: Benet-Buchholz – volume: 74 start-page: 151 year: 2019 end-page: 196 ident: b0210 article-title: Water oxidation catalysis with well-defined molecular iron complexes publication-title: Adv Organomet Chem contributor: fullname: Costas – volume: 29 start-page: 228 year: 1992 end-page: 234 ident: b0450 article-title: (η publication-title: Inorg Synth contributor: fullname: Maitlis – volume: 138 start-page: 1527 year: 2016 end-page: 1535 ident: b0140 article-title: Promoting photochemical water oxidation with metallic band structures publication-title: J Am Chem Soc contributor: fullname: Grundmann – volume: 49 start-page: 9765 year: 2010 end-page: 9768 ident: b0245 article-title: Water oxidation catalyzed by strong carbene-type donor-ligand complexes of iridium publication-title: Angew Chem Int Ed contributor: fullname: Müller-Bunz – volume: 44 start-page: 6802 year: 2005 end-page: 6827 ident: b0015 article-title: Chemical approaches to artificial photosynthesis. 2 publication-title: Inorg Chem contributor: fullname: Meyer – volume: 39 start-page: 10021 year: 2010 end-page: 10030 ident: b0035 article-title: Solar fuels: thermodynamics, candidates, tactics, and figures of merit publication-title: Dalton Trans contributor: fullname: Bernhard – volume: 114 start-page: 11863 year: 2014 end-page: 12001 ident: b0190 article-title: Artificial photosynthesis: molecular systems for catalytic water oxidation publication-title: Chem Rev contributor: fullname: Johnston – volume: 28 start-page: 3304 year: 2018 end-page: 3311 ident: b0080 article-title: Iron(III) complexes with cross-bridged cyclams: synthesis and use in alcohol and water oxidation catalysis publication-title: Eur J Inorg Chem contributor: fullname: Gatto – volume: 20 start-page: 3446 year: 2014 end-page: 3456 ident: b0330 article-title: Transformation of a Cp*-iridium(III) precatalyst for water oxidation when exposed to oxidative stress publication-title: Chem Eur J contributor: fullname: Bortolini – volume: 38 start-page: 4309 year: 1999 end-page: 4316 ident: b0455 article-title: Mechanistic investigation on the water substitution in the η publication-title: Inorg Chem contributor: fullname: Fernandez – volume: 4 start-page: 418 year: 2012 end-page: 423 ident: b0045 article-title: A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II publication-title: Nat Chem contributor: fullname: Mandal – volume: 248 start-page: 215 year: 1996 end-page: 224 ident: b0500 article-title: Complexation equilibria and structures of dimethyltin (IV) complexes with N-methyliminodiacetate, pyridine-2,6-dicarboxylate, ethylenediamine-N, N′-diacetate and ethylenediamine-N, N, N′, N′-tetraacetate publication-title: Inorg Chim Acta contributor: fullname: Hatano – volume: 136 start-page: 1694 year: 2014 end-page: 1697 ident: b0380 article-title: Anchoring a molecular iron catalyst to solar-responsive WO publication-title: J Am Chem Soc contributor: fullname: Bartlett – volume: 110 start-page: 20008 year: 2013 end-page: 20013 ident: b0440 article-title: Solar water splitting in a molecular photoelectrochemical cell publication-title: Proc Natl Acad Sci USA contributor: fullname: Norris – volume: 20 start-page: 5358 year: 2014 end-page: 5368 ident: b0285 article-title: Catalytic water splitting with an iridium carbene complex: a theoretical study publication-title: Chem Eur J contributor: fullname: Reek – volume: 15 start-page: 2040 year: 2019 end-page: 2057 ident: b0420 article-title: Tailored assembly of molecular water oxidation catalysts on photoelectrodes for artificial photosynthesis publication-title: Eur J Inorg Chem contributor: fullname: Lee – volume: 22 start-page: 13459 year: 2016 end-page: 13463 ident: b0100 article-title: Heterogenized water oxidation catalysts prepared by immobilizing Kläui-type organometallic precursors publication-title: Chem Eur J contributor: fullname: Bucci – volume: 13 start-page: 3360 year: 2011 end-page: 3374 ident: b0305 article-title: Activity and degradation pathways of pentamethyl-cyclopentadienyl-iridium catalysts for water oxidation publication-title: Green Chem contributor: fullname: Bellachioma – volume: 133 start-page: 13445 year: 2011 end-page: 13454 ident: b0365 article-title: Doping metal–organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis publication-title: J Am Chem Soc contributor: fullname: deKrafft – volume: 47 start-page: 659 year: 2018 end-page: 662 ident: b0225 article-title: A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects publication-title: Dalton Trans contributor: fullname: Bernhard – volume: 2 start-page: 1198 year: 1976 end-page: 1202 ident: b0470 article-title: Mixed binuclear compounds of copper ethylenediaminetetraacetate and ethylenediaminetetramethylphosphonate with ethylenediamine and ions of glycine and oxalate publication-title: Koord Khimiya contributor: fullname: Barkhanova – volume: 205 start-page: 45 year: 1993 end-page: 51 ident: b0525 article-title: Syntheses of sulfur-bridged tungsten(V) complexes with syn-W publication-title: Inorg Chim Acta contributor: fullname: Shibahara – volume: 11 start-page: 5602 year: 2019 end-page: 5609 ident: b0410 article-title: Silatrane anchors for metal oxide surfaces: optimization for potential photocatalytic and electrocatalytic applications publication-title: ACS Appl Mater Interfaces contributor: fullname: Crabtree – volume: 7 start-page: 29 year: 2019 ident: b0165 article-title: Water oxidation catalysts: the quest for new oxide-based materials publication-title: Inorganics contributor: fullname: Patzke – volume: 359 start-page: 3754 year: 2006 end-page: 3762 ident: b0535 article-title: Synthesis and X-ray structures of rhenium(I) carbonyl aminoalkoxide and aminocarboxylate complexes publication-title: Inorg Chim Acta contributor: fullname: Yan – volume: 46 start-page: 9218 year: 2010 end-page: 9219 ident: b0235 article-title: Iridium(III) molecular catalysts for water oxidation: the simpler the faster publication-title: Chem Commun contributor: fullname: Ciancaleoni – volume: 46 start-page: 6124 year: 2017 end-page: 6147 ident: b0070 article-title: Frontiers of water oxidation: the quest for true catalysts publication-title: Chem Soc Rev contributor: fullname: Moré – volume: 135 start-page: 16977 year: 2013 end-page: 16987 ident: b0135 article-title: Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction publication-title: J Am Chem Soc contributor: fullname: Peters – volume: 49 start-page: 2696 year: 2020 end-page: 2705 ident: b0220 article-title: Novel iridium complexes with N-heterocyclic dicarbene ligands in light-driven water oxidation catalysis: photon management, ligand effect and catalyst evolution publication-title: Dalton Trans contributor: fullname: Graiff – volume: 4 start-page: 1166 year: 2018 end-page: 1172 ident: b0435 article-title: End-on bound iridium dinuclear heterogeneous catalysts on WO publication-title: ACS Cent Sci contributor: fullname: Yang – volume: 3 start-page: 1613 year: 2018 end-page: 1619 ident: b0120 article-title: Activating Kläui-type organometallic precursors at metal oxide surfaces for enhanced solar water oxidation publication-title: ACS Energy Lett contributor: fullname: Dong – volume: 7 start-page: 7788 year: 2017 end-page: 7796 ident: b0260 article-title: A single organoiridium complex generating highly active catalysts for both water oxidation and NAD publication-title: ACS Catal contributor: fullname: Bellachioma – volume: 115 start-page: 2902 year: 2018 end-page: 2907 ident: b0430 article-title: Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation publication-title: Proc Natl Acad Sci USA contributor: fullname: Wang – volume: 29 start-page: 89 year: 1978 end-page: 99 ident: b0545 article-title: Amino acid complexes of platinum(IV). I. Trimethylplatinum(IV) complexes with glycinate, iminodiacetate, N-methyliminodiacetate, nitrilotriacetate, and ethylenediamine-tetraacetate publication-title: Inorg Chim Acta contributor: fullname: Lambert – volume: 321 start-page: 1072 year: 2008 end-page: 1075 ident: b0145 article-title: formation of an water containing phosphate and Co publication-title: Science contributor: fullname: Nocera – volume: 47 start-page: 4646 year: 2018 end-page: 4652 ident: b0360 article-title: Engineering iridium-based metal organic frameworks towards electrocatalytic water oxidation publication-title: Dalton Trans contributor: fullname: Wang – volume: 21 start-page: 567 year: 1982 end-page: 576 ident: b0515 article-title: Carbon-13, oxygen-17 and molybdenum-95 nuclear magnetic resonance studies of oxomolybdenum(VI) complexes publication-title: Inorg Chem contributor: fullname: Reilley – volume: 6 start-page: 6469 year: 2015 ident: b0115 article-title: A molecular catalyst for water oxidation that binds to metal oxide surfaces publication-title: Nat Commun contributor: fullname: Hintermair – volume: 4 start-page: 690 year: 2014 end-page: 697 ident: b0010 article-title: Mechanistic aspects of water oxidation catalyzed by organometallic iridium complexes publication-title: Eur J Inorg Chem contributor: fullname: Bellachioma – volume: 8 start-page: 2620 year: 1968 end-page: 2624 ident: b0560 article-title: Synthesis and properties of certain uranyl aminopolycarboxylates publication-title: Inorg Chem contributor: fullname: Morris – volume: 10 start-page: 4398 year: 2020 end-page: 4410 ident: b0325 article-title: The influence of the ligand in the iridium mediated electrocatalyic water oxidation publication-title: ACS Catal contributor: fullname: Wu – volume: 55 start-page: 8067 year: 2016 end-page: 8071 ident: b0575 article-title: Water oxidation by ruthenium complexes incorporating multifunctional bipyridyl diphosphonate ligands publication-title: Angew Chem Int Ed contributor: fullname: Lewandowska-Andralojc – volume: 21 start-page: 389 year: 2002 end-page: 394 ident: b0505 article-title: Reaction of diperoxovanadate with vanadyl sulphate in presence of EDTA as an access to dinuclear peroxovanadates(V) publication-title: Polyhedron contributor: fullname: Islam – volume: 10 start-page: 4503 year: 2017 end-page: 4509 ident: b0270 article-title: Benchmarking water oxidation catalysts based on iridium complexes: clues and doubts on the nature of active species publication-title: ChemSusChem contributor: fullname: Zuccaccia – volume: 4 start-page: 1728 year: 1978 end-page: 1731 ident: b0465 article-title: Mixed binuclear compounds of nickel and copper ethylenediaminetetramethylphosphonates with ethylenediamine and glycine publication-title: Koord Khimiya contributor: fullname: Zhadanov – volume: 135 start-page: 10837 year: 2013 end-page: 10851 ident: b0320 article-title: Precursor transformation during molecular oxidation catalysis with organometallic iridium complexes publication-title: J Am Chem Soc contributor: fullname: Parent – volume: 139 start-page: 14198 year: 2017 end-page: 14208 ident: b0085 article-title: Co publication-title: J Am Chem Soc contributor: fullname: Schilling – volume: 6 start-page: 5865 year: 2015 ident: b0065 article-title: Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation publication-title: Nat Commun contributor: fullname: Kleespies – volume: 116 start-page: 14120 year: 2016 end-page: 14136 ident: b0215 article-title: Earth-abundant heterogeneous water oxidation catalysts publication-title: Chem Rev contributor: fullname: Müller – volume: 9 start-page: 1462 year: 2012 end-page: 1468 ident: b0310 article-title: An NMR study of the oxidative degradation of Cp*Ir catalysts for water oxidation: evidence for a preliminary attack on the quaternary carbon atom of the –C–CH publication-title: Eur J Inorg Chem contributor: fullname: Bolaño – volume: 44 start-page: 12452 year: 2015 end-page: 12472 ident: b0005 article-title: Iridium-based complexes for water oxidation publication-title: Dalton Trans contributor: fullname: Crabtree – volume: 3 start-page: 399 year: 2012 end-page: 404 ident: b0155 article-title: Synthesis and activities of rutile IrO publication-title: J Phys Chem Lett contributor: fullname: May – volume: 7 start-page: 123 year: 2019 ident: b0370 article-title: Post synthetic defect engineering of UiO-66 metal–organic framework with An iridium(III)-HEDTA complex and application in water oxidation catalysis publication-title: Inorganics contributor: fullname: Bondi – volume: 51 start-page: 9601 year: 2012 end-page: 9605 ident: b0345 article-title: Surface-immobilized single-site iridium complexes for electrocatalytic water splitting publication-title: Angew Chem Int Ed contributor: fullname: D’Souza – volume: 139 start-page: 15347 year: 2017 end-page: 15355 ident: b0580 article-title: Lability and basicity of bipyridine-carboxylate-phosphonate ligand accelerate single-site water oxidation by ruthenium-based molecular catalysts publication-title: J Am Chem Soc contributor: fullname: Szalda – volume: 20 start-page: 5191 year: 2008 end-page: 5196 ident: b0390 article-title: High-field publication-title: Chem Mater contributor: fullname: Maquet – volume: 131 start-page: 8730 year: 2009 end-page: 8731 ident: b0295 article-title: Highly active and robust Cp* iridium complexes for catalytic water oxidation publication-title: J Am Chem Soc contributor: fullname: Blakemore – volume: 134 start-page: 19895 year: 2012 end-page: 19908 ident: b0130 article-title: Metal−organic frameworks: a comprehensive structural, catalytic, spectroscopic, and kinetic study publication-title: J Am Chem Soc contributor: fullname: Lin – year: 2017 ident: b0185 article-title: Iridium complexes in water oxidation catalysis publication-title: Iridium(III) Optoelectronic Photonics Applications contributor: fullname: Albrecht – volume: 6 start-page: 10761 year: 2018 end-page: 10768 ident: b0350 article-title: Molecular cobalt salophen catalyst-integrated BiVO publication-title: J Mater Chem A contributor: fullname: Li – volume: 16 start-page: 823 year: 1990 end-page: 828 ident: b0565 article-title: Basic features of the formation of transition metal dinuclear ethylenediaminetetraacetates, M publication-title: Koord Khimiya contributor: fullname: Dyatlova – volume: 134 start-page: 9785 year: 2012 end-page: 9795 ident: b0315 article-title: Particle formation during oxidation catalysis with Cp* iridium complexes publication-title: J Am Chem Soc contributor: fullname: Elimelech – volume: 262 start-page: 170 year: 2016 end-page: 180 ident: b0150 article-title: Oxygen and hydrogen evolution reactions on Ru, RuO publication-title: Catal Today contributor: fullname: Kasian – volume: 636 start-page: 1710 year: 2010 end-page: 1715 ident: b0490 article-title: Preparation, crystal structures and thermal decomposition of Ba publication-title: Z Anorg Allg Chem contributor: fullname: Prots – volume: 11 start-page: 5353 year: 2019 end-page: 5361 ident: b0230 article-title: Iridium water oxidation catalysts based on pyridine-carbene alkyl-substituted ligands publication-title: ChemCatChem contributor: fullname: Heath – volume: 78 start-page: 5496 year: 1956 end-page: 5500 ident: b0520 article-title: Molybdenum(V) and molybdenum(VI) complexes with ethylenediaminetetraacetic acid publication-title: J Am Chem Soc contributor: fullname: Sawyer – volume: 2 start-page: 105 year: 2017 end-page: 110 ident: b0275 article-title: Extremely active, tunable, and pH-responsive iridium water oxidation catalysts publication-title: ACS Energy Lett contributor: fullname: Hutchinson – volume: 5 start-page: 1415 year: 2012 end-page: 1419 ident: b0425 article-title: Iridium-EDTA as an efficient and readily available catalyst for water oxidation publication-title: ChemSusChem contributor: fullname: Bolaño – volume: 133 start-page: 19024 year: 2011 end-page: 19027 ident: b0300 article-title: Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate publication-title: J Am Chem Soc contributor: fullname: Martin – volume: 49 start-page: 765 year: 2020 end-page: 838 ident: b0445 article-title: Dinuclear metal complexes: multifunctional properties and applications publication-title: Chem Soc Rev contributor: fullname: Wang – volume: 120 start-page: 12495 year: 2016 end-page: 12502 ident: b0400 article-title: Surface-induced deprotection of THP-protected hydroxamic acids on titanium dioxide publication-title: J Phys Chem C contributor: fullname: Materna – volume: 31 start-page: 2152 year: 2012 end-page: 2165 ident: b0475 article-title: Bifunctional mechanism with unconventional intermediates for the hydrogenation of ketones catalyzed by an iridium(III) complex containing an N-heterocyclic carbene with a primary amine donor publication-title: Organometallics contributor: fullname: Morris – volume: 10 start-page: 4280 year: 2018 end-page: 4291 ident: b0240 article-title: Electrochemical and kinetic insights into molecular water oxidation catalysts derived from Cp*Ir(pyridine-alkoxide) complexes publication-title: ChemCatChem contributor: fullname: Hintermair – volume: 14 start-page: 31 year: 2019 end-page: 43 ident: b0205 article-title: Iron-based molecular water oxidation catalysts: abundant, cheap, and promising publication-title: Chem Asian J contributor: fullname: Sun – volume: 5 start-page: 2714 year: 2015 end-page: 2718 ident: b0265 article-title: Substantial improvement of pyridine-carbene iridium water oxidation catalysts by a simple methyl-to-octyl substitution publication-title: ACS Catal contributor: fullname: Müller-Bunz – volume: 13 start-page: 281 year: 1988 end-page: 283 ident: b0460 article-title: Polynuclear trivalent metal complexes with phosphonic acids publication-title: Transit Met Chem contributor: fullname: Puri – year: 2014 ident: b0050 article-title: Molecular water oxidation catalysis: a key topic for new sustainable energy conversion schemes contributor: fullname: Llobet – volume: 49 start-page: 765 year: 2020 ident: 10.1016/j.scib.2020.06.015_b0445 article-title: Dinuclear metal complexes: multifunctional properties and applications publication-title: Chem Soc Rev doi: 10.1039/C8CS00660A contributor: fullname: Li – volume: 20 start-page: 3446 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0330 article-title: Transformation of a Cp*-iridium(III) precatalyst for water oxidation when exposed to oxidative stress publication-title: Chem Eur J doi: 10.1002/chem.201304412 contributor: fullname: Zuccaccia – volume: 2 start-page: 1173 year: 2009 ident: 10.1016/j.scib.2020.06.015_b0405 article-title: Hydroxamate anchors for water-stable attachment to TiO2 nanoparticles publication-title: Energy Environ Sci doi: 10.1039/b910241h contributor: fullname: McNamara – volume: 42 start-page: 1890 year: 2009 ident: 10.1016/j.scib.2020.06.015_b0030 article-title: Solar fuels via artificial photosynthesis publication-title: Acc Chem Res doi: 10.1021/ar900209b contributor: fullname: Gust – volume: 55 start-page: 15382 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0055 article-title: A million turnover molecular anode for catalytic water oxidation publication-title: Angew Chem Int Ed doi: 10.1002/anie.201609167 contributor: fullname: Creus – volume: 28 start-page: 3304 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0080 article-title: Iron(III) complexes with cross-bridged cyclams: synthesis and use in alcohol and water oxidation catalysis publication-title: Eur J Inorg Chem doi: 10.1002/ejic.201800451 contributor: fullname: Annunziata – volume: 8 start-page: 18577 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0355 article-title: Improved photoelectrocatalytic performance for water oxidation by earth-abundant cobalt molecular porphyrin complex-integrated BiVO4 photoanode publication-title: ACS Appl Mater Interfaces doi: 10.1021/acsami.6b04510 contributor: fullname: Liu – volume: 45 start-page: 11030 year: 2006 ident: 10.1016/j.scib.2020.06.015_b0510 article-title: Layered lanthanide molybdate pillared by chiral [λ-Mo2O4EDTA]2− publication-title: Inorg Chem doi: 10.1021/ic0611793 contributor: fullname: Luo – volume: 45 start-page: 14421 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0200 article-title: Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges publication-title: Dalton Trans doi: 10.1039/C6DT00809G contributor: fullname: Kärkäs – volume: 7 start-page: 123 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0370 article-title: Post synthetic defect engineering of UiO-66 metal–organic framework with An iridium(III)-HEDTA complex and application in water oxidation catalysis publication-title: Inorganics doi: 10.3390/inorganics7100123 contributor: fullname: Gatto – volume: 15 start-page: 2040 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0420 article-title: Tailored assembly of molecular water oxidation catalysts on photoelectrodes for artificial photosynthesis publication-title: Eur J Inorg Chem doi: 10.1002/ejic.201801328 contributor: fullname: Bae – volume: 49 start-page: 2468 year: 2020 ident: 10.1016/j.scib.2020.06.015_b0160 article-title: Ir- and Ru-doped layered double hydroxides as affordable heterogeneous catalysts for electrochemical water oxidation publication-title: Dalton Trans doi: 10.1039/C9DT04306C contributor: fullname: Fagiolari – volume: 110 start-page: 20008 year: 2013 ident: 10.1016/j.scib.2020.06.015_b0440 article-title: Solar water splitting in a molecular photoelectrochemical cell publication-title: Proc Natl Acad Sci USA doi: 10.1073/pnas.1319628110 contributor: fullname: Alibabaei – volume: 16 start-page: 823 year: 1990 ident: 10.1016/j.scib.2020.06.015_b0565 article-title: Basic features of the formation of transition metal dinuclear ethylenediaminetetraacetates, M2EDTA publication-title: Koord Khimiya contributor: fullname: Leont’eva – volume: 6 start-page: 6469 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0115 article-title: A molecular catalyst for water oxidation that binds to metal oxide surfaces publication-title: Nat Commun doi: 10.1038/ncomms7469 contributor: fullname: Sheehan – volume: 49 start-page: 2696 year: 2020 ident: 10.1016/j.scib.2020.06.015_b0220 article-title: Novel iridium complexes with N-heterocyclic dicarbene ligands in light-driven water oxidation catalysis: photon management, ligand effect and catalyst evolution publication-title: Dalton Trans doi: 10.1039/C9DT04841C contributor: fullname: Volpe – volume: 43 start-page: 7501 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0040 article-title: Molecular artificial photosynthesis publication-title: Chem Soc Rev doi: 10.1039/C3CS60405E contributor: fullname: Berardi – volume: 134 start-page: 9785 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0315 article-title: Particle formation during oxidation catalysis with Cp* iridium complexes publication-title: J Am Chem Soc doi: 10.1021/ja3033026 contributor: fullname: Hintermair – volume: 44 start-page: 12452 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0005 article-title: Iridium-based complexes for water oxidation publication-title: Dalton Trans doi: 10.1039/C5DT00863H contributor: fullname: Thomsen – volume: 51 start-page: 9601 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0345 article-title: Surface-immobilized single-site iridium complexes for electrocatalytic water splitting publication-title: Angew Chem Int Ed doi: 10.1002/anie.201203560 contributor: fullname: Joya – volume: 7 start-page: 6235 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0385 article-title: Chasing the Achilles’ heel in hybrid systems of diruthenium water oxidation catalysts anchored on indium tin oxide: the stability of the anchor publication-title: ACS Catal doi: 10.1021/acscatal.7b01883 contributor: fullname: Odrobina – volume: 13 start-page: 3360 year: 2011 ident: 10.1016/j.scib.2020.06.015_b0305 article-title: Activity and degradation pathways of pentamethyl-cyclopentadienyl-iridium catalysts for water oxidation publication-title: Green Chem doi: 10.1039/c1gc15899f contributor: fullname: Savini – volume: 42 start-page: 13706 year: 2013 ident: 10.1016/j.scib.2020.06.015_b0495 article-title: Synthesis and characterization of homo- and heteronuclear molecular Al3+ and Th4+ species chelated by the ethylenediaminetetraacetate (edta) ligand publication-title: Dalt Trans doi: 10.1039/c3dt51517f contributor: fullname: Fairley – volume: 6 start-page: 5371 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0105 article-title: Heterogenized iridium water-oxidation catalyst from a silatrane precursor publication-title: ACS Catal doi: 10.1021/acscatal.6b01101 contributor: fullname: Materna – volume: 139 start-page: 14198 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0085 article-title: Co4O4 and CoxNi4–xO4 cubane water oxidation catalysts as surface cut-outs of cobalt oxides publication-title: J Am Chem Soc doi: 10.1021/jacs.7b07361 contributor: fullname: Song – volume: 636 start-page: 1710 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0490 article-title: Preparation, crystal structures and thermal decomposition of Ba2(EDTA) and Ba2(EDTA)·2.5H2O publication-title: Z Anorg Allg Chem doi: 10.1002/zaac.201000044 contributor: fullname: Chen – volume: 205 start-page: 45 year: 1993 ident: 10.1016/j.scib.2020.06.015_b0525 article-title: Syntheses of sulfur-bridged tungsten(V) complexes with syn-W2O2S2 cores. X-ray structures of K2[W2O2S2(cys)2]·5H2O and NaNH4[W2O2S2(edta)]·2H2O publication-title: Inorg Chim Acta doi: 10.1016/S0020-1693(00)87353-3 contributor: fullname: Yamasaki – volume: 248 start-page: 215 year: 1996 ident: 10.1016/j.scib.2020.06.015_b0500 article-title: Complexation equilibria and structures of dimethyltin (IV) complexes with N-methyliminodiacetate, pyridine-2,6-dicarboxylate, ethylenediamine-N, N′-diacetate and ethylenediamine-N, N, N′, N′-tetraacetate publication-title: Inorg Chim Acta doi: 10.1016/0020-1693(95)05011-6 contributor: fullname: Aizawa – volume: 44 start-page: 6802 year: 2005 ident: 10.1016/j.scib.2020.06.015_b0015 article-title: Chemical approaches to artificial photosynthesis. 2 publication-title: Inorg Chem doi: 10.1021/ic050904r contributor: fullname: Alstrum-Acevedo – volume: 54 start-page: 11428 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0340 article-title: Hematite-based solar water splitting in acidic solutions: functionalization by mono- and multilayers of iridium oxygen-evolution catalysts publication-title: Angew Chem Int Ed doi: 10.1002/anie.201504427 contributor: fullname: Li – volume: 321 start-page: 1072 year: 2008 ident: 10.1016/j.scib.2020.06.015_b0145 article-title: In situ formation of an water containing phosphate and Co2+ publication-title: Science doi: 10.1126/science.1162018 contributor: fullname: Kanan – volume: 49 start-page: 9765 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0245 article-title: Water oxidation catalyzed by strong carbene-type donor-ligand complexes of iridium publication-title: Angew Chem Int Ed doi: 10.1002/anie.201005260 contributor: fullname: Lalrempuia – volume: 4 start-page: 418 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0045 article-title: A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II publication-title: Nat Chem doi: 10.1038/nchem.1301 contributor: fullname: Duan – volume: 53 start-page: 12689 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0060 article-title: Studies of the pathways open to copper water oxidation catalysts containing proximal hydroxy groups during basic electrocatalysis publication-title: Inorg Chem doi: 10.1021/ic501018a contributor: fullname: Gerlach – volume: 4 start-page: 1166 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0435 article-title: End-on bound iridium dinuclear heterogeneous catalysts on WO3 for solar water oxidation publication-title: ACS Cent Sci doi: 10.1021/acscentsci.8b00335 contributor: fullname: Zhao – volume: 59 start-page: 626 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0540 article-title: Heteroligand polynuclear nickel(II) complexonates in aqueous solutions of 2,2′-dipyridyl publication-title: Russ J Inorg Chem doi: 10.1134/S0036023614060114 contributor: fullname: Kornev – volume: 7 start-page: 7788 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0260 article-title: A single organoiridium complex generating highly active catalysts for both water oxidation and NAD+/NADH transformations publication-title: ACS Catal doi: 10.1021/acscatal.7b02387 contributor: fullname: Bucci – volume: 29 start-page: 228 year: 1992 ident: 10.1016/j.scib.2020.06.015_b0450 article-title: (η5-Pentamethylcyclopentadienyl)rhodium and -iridium compounds publication-title: Inorg Synth doi: 10.1002/9780470132609.ch53 contributor: fullname: White – volume: 13 start-page: 281 year: 1988 ident: 10.1016/j.scib.2020.06.015_b0460 article-title: Polynuclear trivalent metal complexes with phosphonic acids publication-title: Transit Met Chem doi: 10.1007/BF01025674 contributor: fullname: Venkateswara Rao – volume: 11 start-page: 5353 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0230 article-title: Iridium water oxidation catalysts based on pyridine-carbene alkyl-substituted ligands publication-title: ChemCatChem doi: 10.1002/cctc.201901092 contributor: fullname: Corbucci – volume: 10 start-page: 4503 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0270 article-title: Benchmarking water oxidation catalysts based on iridium complexes: clues and doubts on the nature of active species publication-title: ChemSusChem doi: 10.1002/cssc.201701818 contributor: fullname: Rodriguez – volume: 4 start-page: 2389 year: 2011 ident: 10.1016/j.scib.2020.06.015_b0335 article-title: A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst publication-title: Energy Environ Sci doi: 10.1039/c1ee01037a contributor: fullname: Moore – volume: 180 start-page: 1664 year: 2007 ident: 10.1016/j.scib.2020.06.015_b0550 article-title: Two-dimensional layer architecture assembled by Keggin polyoxotungstate, Cu(II)–EDTA complex and sodium linker: synthesis, crystal structures, and magnetic properties publication-title: J Solid State Chem doi: 10.1016/j.jssc.2007.03.011 contributor: fullname: Liu – volume: 12 start-page: 2275 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0195 article-title: Towards maximized utilization of iridium for the acidic oxygen evolution reaction publication-title: Nano Res doi: 10.1007/s12274-019-2383-y contributor: fullname: Ledendecker – year: 2014 ident: 10.1016/j.scib.2020.06.015_b0050 contributor: fullname: Llobet – volume: 47 start-page: 4646 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0360 article-title: Engineering iridium-based metal organic frameworks towards electrocatalytic water oxidation publication-title: Dalton Trans doi: 10.1039/C8DT00485D contributor: fullname: Zhao – volume: 133 start-page: 19024 year: 2011 ident: 10.1016/j.scib.2020.06.015_b0300 article-title: Evolution of iridium-based molecular catalysts during water oxidation with ceric ammonium nitrate publication-title: J Am Chem Soc doi: 10.1021/ja203095k contributor: fullname: Grotjahn – volume: 137 start-page: 10786 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0180 article-title: Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex publication-title: J Am Chem Soc doi: 10.1021/jacs.5b06541 contributor: fullname: Matheu – volume: 47 start-page: 2712 year: 2011 ident: 10.1016/j.scib.2020.06.015_b0250 article-title: Me2–NHC based robust Ir catalyst for efficient water oxidation publication-title: Chem Commun doi: 10.1039/c0cc05108j contributor: fullname: Hetterscheid – volume: 5 start-page: 264 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0095 article-title: Activity and recyclability of an iridium–EDTA water oxidation catalyst immobilized onto rutile TiO2 publication-title: ACS Catal doi: 10.1021/cs501590k contributor: fullname: Savini – volume: 10 start-page: 4280 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0240 article-title: Electrochemical and kinetic insights into molecular water oxidation catalysts derived from Cp*Ir(pyridine-alkoxide) complexes publication-title: ChemCatChem doi: 10.1002/cctc.201800916 contributor: fullname: Sackville – volume: 5 start-page: 1415 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0425 article-title: Iridium-EDTA as an efficient and readily available catalyst for water oxidation publication-title: ChemSusChem doi: 10.1002/cssc.201200067 contributor: fullname: Savini – volume: 38 start-page: 4309 year: 1999 ident: 10.1016/j.scib.2020.06.015_b0455 article-title: Mechanistic investigation on the water substitution in the η5-organometallic complexes Cp*Ir(H2O)32+ and Cp*Rh(H2O)32+ publication-title: Inorg Chem doi: 10.1021/ic990364w contributor: fullname: Cayemittes – volume: 530 start-page: 465 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0075 article-title: A pentanuclear iron catalyst designed for water oxidation publication-title: Nature doi: 10.1038/nature16529 contributor: fullname: Okamura – year: 2017 ident: 10.1016/j.scib.2020.06.015_b0185 article-title: Iridium complexes in water oxidation catalysis contributor: fullname: Corbucci – volume: 5 start-page: 2714 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0265 article-title: Substantial improvement of pyridine-carbene iridium water oxidation catalysts by a simple methyl-to-octyl substitution publication-title: ACS Catal doi: 10.1021/acscatal.5b00319 contributor: fullname: Corbucci – volume: 1 start-page: 26 year: 2008 ident: 10.1016/j.scib.2020.06.015_b0025 article-title: Photochemical conversion of solar energy publication-title: ChemSusChem doi: 10.1002/cssc.200700087 contributor: fullname: Balzani – volume: 14 start-page: 31 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0205 article-title: Iron-based molecular water oxidation catalysts: abundant, cheap, and promising publication-title: Chem Asian J doi: 10.1002/asia.201801253 contributor: fullname: Liu – volume: 6 start-page: 10761 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0350 article-title: Molecular cobalt salophen catalyst-integrated BiVO4 as stable and robust photoanodes for photoelectrochemical water splitting publication-title: J Mater Chem A doi: 10.1039/C8TA01304G contributor: fullname: Liu – volume: 13 start-page: 4367 year: 2001 ident: 10.1016/j.scib.2020.06.015_b0395 article-title: Anchoring of phosphonate and phosphinate coupling molecules on titania particles publication-title: Chem Mater doi: 10.1021/cm001253u contributor: fullname: Guerre – volume: 107 start-page: 7225 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0090 article-title: Concerted O atom-proton transfer in the O-O bond forming step in water oxidation publication-title: Proc Natl Acad Sci USA doi: 10.1073/pnas.1001132107 contributor: fullname: Chen – volume: 7 start-page: 29 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0165 article-title: Water oxidation catalysts: the quest for new oxide-based materials publication-title: Inorganics doi: 10.3390/inorganics7030029 contributor: fullname: Mavrokefalos – volume: 10 start-page: 1900399 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0415 article-title: Hybrid photoelectrochemical water splitting systems: from interface design to system assembly publication-title: Adv Energy Mater doi: 10.1002/aenm.201900399 contributor: fullname: Niu – volume: 10 start-page: 4616 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0290 article-title: Homogeneous water oxidation by half-sandwich iridium(III) N-heterocyclic carbene complexes with pendant hydroxy and amino groups publication-title: ChemSusChem doi: 10.1002/cssc.201701370 contributor: fullname: Mahanti – volume: 7 start-page: 1090 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0480 article-title: Iridium-catalyzed sustainable access to functionalized julolidines through hydrogen autotransfer publication-title: ChemCatChem doi: 10.1002/cctc.201500051 contributor: fullname: Labed – volume: 115 start-page: 2902 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0430 article-title: Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation publication-title: Proc Natl Acad Sci USA doi: 10.1073/pnas.1722137115 contributor: fullname: Zhao – volume: 2 start-page: 1198 year: 1976 ident: 10.1016/j.scib.2020.06.015_b0470 article-title: Mixed binuclear compounds of copper ethylenediaminetetraacetate and ethylenediaminetetramethylphosphonate with ethylenediamine and ions of glycine and oxalate publication-title: Koord Khimiya contributor: fullname: Fridman – volume: 2 start-page: 105 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0275 article-title: Extremely active, tunable, and pH-responsive iridium water oxidation catalysts publication-title: ACS Energy Lett doi: 10.1021/acsenergylett.6b00606 contributor: fullname: Menendez Rodriguez – volume: 3 start-page: 1613 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0120 article-title: Activating Kläui-type organometallic precursors at metal oxide surfaces for enhanced solar water oxidation publication-title: ACS Energy Lett doi: 10.1021/acsenergylett.8b00847 contributor: fullname: Wan – volume: 8 start-page: 2620 year: 1968 ident: 10.1016/j.scib.2020.06.015_b0560 article-title: Synthesis and properties of certain uranyl aminopolycarboxylates publication-title: Inorg Chem doi: 10.1021/ic50082a016 contributor: fullname: Krishnamurthy – volume: 136 start-page: 1694 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0380 article-title: Anchoring a molecular iron catalyst to solar-responsive WO3 improves the rate and selectivity of photoelectrochemical water oxidation publication-title: J Am Chem Soc doi: 10.1021/ja4086808 contributor: fullname: Klepser – volume: 47 start-page: 659 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0225 article-title: A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects publication-title: Dalton Trans doi: 10.1039/C7DT04555G contributor: fullname: Navarro – volume: 133 start-page: 13445 year: 2011 ident: 10.1016/j.scib.2020.06.015_b0365 article-title: Doping metal–organic frameworks for water oxidation, carbon dioxide reduction, and organic photocatalysis publication-title: J Am Chem Soc doi: 10.1021/ja203564w contributor: fullname: Wang – volume: 1 start-page: 7 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0175 article-title: The middle-earth between homogeneous and heterogeneous catalysis in water oxidation with iridium publication-title: Eur J Inorg Chem doi: 10.1002/ejic.201800798 contributor: fullname: Macchioni – volume: 116 start-page: 14120 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0215 article-title: Earth-abundant heterogeneous water oxidation catalysts publication-title: Chem Rev doi: 10.1021/acs.chemrev.6b00398 contributor: fullname: Hunter – volume: 21 start-page: 389 year: 2002 ident: 10.1016/j.scib.2020.06.015_b0505 article-title: Reaction of diperoxovanadate with vanadyl sulphate in presence of EDTA as an access to dinuclear peroxovanadates(V) publication-title: Polyhedron doi: 10.1016/S0277-5387(01)01005-1 contributor: fullname: Sarmah – volume: 139 start-page: 15347 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0580 article-title: Lability and basicity of bipyridine-carboxylate-phosphonate ligand accelerate single-site water oxidation by ruthenium-based molecular catalysts publication-title: J Am Chem Soc doi: 10.1021/jacs.7b06096 contributor: fullname: Shaffer – volume: 103 start-page: 15729 year: 2006 ident: 10.1016/j.scib.2020.06.015_b0020 article-title: Powering the planet: chemical challenges in solar energy utilization publication-title: Proc Natl Acad Sci USA doi: 10.1073/pnas.0603395103 contributor: fullname: Lewis – ident: 10.1016/j.scib.2020.06.015_b0530 – volume: 20 start-page: 5191 year: 2008 ident: 10.1016/j.scib.2020.06.015_b0390 article-title: High-field 17O MAS NMR investigation of phosphonic acid monolayers on titania publication-title: Chem Mater doi: 10.1021/cm8012683 contributor: fullname: Brodard-Severac – volume: 21 start-page: 567 year: 1982 ident: 10.1016/j.scib.2020.06.015_b0515 article-title: Carbon-13, oxygen-17 and molybdenum-95 nuclear magnetic resonance studies of oxomolybdenum(VI) complexes publication-title: Inorg Chem doi: 10.1021/ic00132a021 contributor: fullname: Freeman – volume: 262 start-page: 170 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0150 article-title: Oxygen and hydrogen evolution reactions on Ru, RuO2, Ir, and IrO2 thin film electrodes in acidic and alkaline electrolytes: a comparative study on activity and stability publication-title: Catal Today doi: 10.1016/j.cattod.2015.08.014 contributor: fullname: Cherevko – volume: 134 start-page: 19895 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0130 article-title: Metal−organic frameworks: a comprehensive structural, catalytic, spectroscopic, and kinetic study publication-title: J Am Chem Soc doi: 10.1021/ja310074j contributor: fullname: Wang – volume: 120 start-page: 12495 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0400 article-title: Surface-induced deprotection of THP-protected hydroxamic acids on titanium dioxide publication-title: J Phys Chem C doi: 10.1021/acs.jpcc.6b02635 contributor: fullname: Brennan – volume: 31 start-page: 2152 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0475 article-title: Bifunctional mechanism with unconventional intermediates for the hydrogenation of ketones catalyzed by an iridium(III) complex containing an N-heterocyclic carbene with a primary amine donor publication-title: Organometallics doi: 10.1021/om300071v contributor: fullname: O – volume: 3 start-page: 331 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0170 article-title: The development of molecular water oxidation catalysts publication-title: Nat Rev Chem doi: 10.1038/s41570-019-0096-0 contributor: fullname: Matheu – volume: 135 start-page: 10837 year: 2013 ident: 10.1016/j.scib.2020.06.015_b0320 article-title: Precursor transformation during molecular oxidation catalysis with organometallic iridium complexes publication-title: J Am Chem Soc doi: 10.1021/ja4048762 contributor: fullname: Hintermair – volume: 6 start-page: 5865 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0065 article-title: Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation publication-title: Nat Commun doi: 10.1038/ncomms6865 contributor: fullname: Codolà – volume: 139 start-page: 323 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0555 article-title: Complex of ytterbium ethylenediaminetetraacetate as combined NMR paramagnetic probe for in situ control of temperature and pH in aqueous media publication-title: Polyhedron doi: 10.1016/j.poly.2017.11.007 contributor: fullname: Babailov – volume: 46 start-page: 6124 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0070 article-title: Frontiers of water oxidation: the quest for true catalysts publication-title: Chem Soc Rev doi: 10.1039/C7CS00306D contributor: fullname: Li – volume: 3 start-page: 399 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0155 article-title: Synthesis and activities of rutile IrO2 and RuO2 nanoparticles for oxygen evolution in acid and alkaline solutions publication-title: J Phys Chem Lett doi: 10.1021/jz2016507 contributor: fullname: Lee – volume: 132 start-page: 16017 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0255 article-title: Half-sandwich iridium complexes for homogeneous water-oxidation catalysis publication-title: J Am Chem Soc doi: 10.1021/ja104775j contributor: fullname: Blakemore – volume: 11 start-page: 5602 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0410 article-title: Silatrane anchors for metal oxide surfaces: optimization for potential photocatalytic and electrocatalytic applications publication-title: ACS Appl Mater Interfaces doi: 10.1021/acsami.8b04138 contributor: fullname: Materna – volume: 135 start-page: 16977 year: 2013 ident: 10.1016/j.scib.2020.06.015_b0135 article-title: Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction publication-title: J Am Chem Soc doi: 10.1021/ja407115p contributor: fullname: McCrory – volume: 42 start-page: 2765 year: 2013 ident: 10.1016/j.scib.2020.06.015_b0485 article-title: Syntheses, structures, and properties of multidimensional lithium coordination polymers based on aliphatic carboxylic acids publication-title: Dalt Trans doi: 10.1039/C2DT32424E contributor: fullname: Cheng – volume: 7 start-page: 1522 year: 1981 ident: 10.1016/j.scib.2020.06.015_b0570 article-title: Formation of a mixed binuclear compound of rhodium(III) with ethylenediaminetetraacetate and chloride ions and with ethylenediamine publication-title: Koord Khimiya contributor: fullname: Popov – volume: 74 start-page: 151 year: 2019 ident: 10.1016/j.scib.2020.06.015_b0210 article-title: Water oxidation catalysis with well-defined molecular iron complexes publication-title: Adv Organomet Chem contributor: fullname: Casadevall – volume: 138 start-page: 1527 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0140 article-title: Promoting photochemical water oxidation with metallic band structures publication-title: J Am Chem Soc doi: 10.1021/jacs.5b10215 contributor: fullname: Liu – volume: 20 start-page: 5358 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0285 article-title: Catalytic water splitting with an iridium carbene complex: a theoretical study publication-title: Chem Eur J doi: 10.1002/chem.201303796 contributor: fullname: Venturini – volume: 22 start-page: 13459 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0100 article-title: Heterogenized water oxidation catalysts prepared by immobilizing Kläui-type organometallic precursors publication-title: Chem Eur J doi: 10.1002/chem.201602008 contributor: fullname: Pastori – volume: 78 start-page: 5496 year: 1956 ident: 10.1016/j.scib.2020.06.015_b0520 article-title: Molybdenum(V) and molybdenum(VI) complexes with ethylenediaminetetraacetic acid publication-title: J Am Chem Soc doi: 10.1021/ja01602a010 contributor: fullname: Pecsok – volume: 4 start-page: 690 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0010 article-title: Mechanistic aspects of water oxidation catalyzed by organometallic iridium complexes publication-title: Eur J Inorg Chem doi: 10.1002/ejic.201300530 contributor: fullname: Savini – volume: 359 start-page: 3754 year: 2006 ident: 10.1016/j.scib.2020.06.015_b0535 article-title: Synthesis and X-ray structures of rhenium(I) carbonyl aminoalkoxide and aminocarboxylate complexes publication-title: Inorg Chim Acta doi: 10.1016/j.ica.2006.03.027 contributor: fullname: Wang – volume: 4 start-page: 1728 year: 1978 ident: 10.1016/j.scib.2020.06.015_b0465 article-title: Mixed binuclear compounds of nickel and copper ethylenediaminetetramethylphosphonates with ethylenediamine and glycine publication-title: Koord Khimiya contributor: fullname: Vshivtseva – volume: 3 start-page: 5072 year: 2015 ident: 10.1016/j.scib.2020.06.015_b0125 article-title: Photochemical and electrocatalytic water oxidation activity of cobalt carbodiimide publication-title: J Mater Chem A doi: 10.1039/C5TA00369E contributor: fullname: Ressnig – volume: 24 start-page: 6386 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0280 article-title: Optimization of synthetically versatile pyridylidene amide ligands for efficient iridium-catalyzed water oxidation publication-title: Chem Eur J doi: 10.1002/chem.201705619 contributor: fullname: Navarro – volume: 24 start-page: 15143 year: 2018 ident: 10.1016/j.scib.2020.06.015_b0375 article-title: The design of water oxidation electrocatalysts from nanoscale metal–organic frameworks publication-title: Chem Eur J doi: 10.1002/chem.201801572 contributor: fullname: Shao – volume: 46 start-page: 6099 year: 2017 ident: 10.1016/j.scib.2020.06.015_b0110 article-title: Anchoring groups for photocatalytic water oxidation on metal oxide surfaces publication-title: Chem Soc Rev doi: 10.1039/C7CS00314E contributor: fullname: Materna – volume: 9 start-page: 1462 year: 2012 ident: 10.1016/j.scib.2020.06.015_b0310 article-title: An NMR study of the oxidative degradation of Cp*Ir catalysts for water oxidation: evidence for a preliminary attack on the quaternary carbon atom of the –C–CH3 moiety publication-title: Eur J Inorg Chem doi: 10.1002/ejic.201100954 contributor: fullname: Zuccaccia – volume: 10 start-page: 4398 year: 2020 ident: 10.1016/j.scib.2020.06.015_b0325 article-title: The influence of the ligand in the iridium mediated electrocatalyic water oxidation publication-title: ACS Catal doi: 10.1021/acscatal.0c00531 contributor: fullname: Van Dijk – volume: 29 start-page: 89 year: 1978 ident: 10.1016/j.scib.2020.06.015_b0545 article-title: Amino acid complexes of platinum(IV). I. Trimethylplatinum(IV) complexes with glycinate, iminodiacetate, N-methyliminodiacetate, nitrilotriacetate, and ethylenediamine-tetraacetate publication-title: Inorg Chim Acta doi: 10.1016/S0020-1693(00)89632-2 contributor: fullname: Appleton – volume: 39 start-page: 10021 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0035 article-title: Solar fuels: thermodynamics, candidates, tactics, and figures of merit publication-title: Dalton Trans doi: 10.1039/c0dt00454e contributor: fullname: McDaniel – volume: 114 start-page: 11863 year: 2014 ident: 10.1016/j.scib.2020.06.015_b0190 article-title: Artificial photosynthesis: molecular systems for catalytic water oxidation publication-title: Chem Rev doi: 10.1021/cr400572f contributor: fullname: Kärkäs – volume: 131 start-page: 8730 year: 2009 ident: 10.1016/j.scib.2020.06.015_b0295 article-title: Highly active and robust Cp* iridium complexes for catalytic water oxidation publication-title: J Am Chem Soc doi: 10.1021/ja901270f contributor: fullname: Hull – volume: 55 start-page: 8067 year: 2016 ident: 10.1016/j.scib.2020.06.015_b0575 article-title: Water oxidation by ruthenium complexes incorporating multifunctional bipyridyl diphosphonate ligands publication-title: Angew Chem Int Ed doi: 10.1002/anie.201601943 contributor: fullname: Xie – volume: 46 start-page: 9218 year: 2010 ident: 10.1016/j.scib.2020.06.015_b0235 article-title: Iridium(III) molecular catalysts for water oxidation: the simpler the faster publication-title: Chem Commun doi: 10.1039/c0cc03801f contributor: fullname: Savini |
| SSID | ssj0001492407 ssib054405809 |
| Score | 2.4147274 |
| Snippet | [Display omitted]
The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at... The development of efficient water oxidation catalysts (WOCs) is of key importance in order to drive sustainable reductive processes aimed at producing... |
| SourceID | hal crossref pubmed elsevier |
| SourceType | Open Access Repository Aggregation Database Index Database Publisher |
| StartPage | 1614 |
| SubjectTerms | Chemical Sciences Dinuclear complexes Heterogenized catalysts Homogeneous catalysis Organometallic chemistry Renewable fuels Water oxidation |
| Title | Molecular and heterogenized dinuclear Ir-Cp water oxidation catalysts bearing EDTA or EDTMP as bridging and anchoring ligands |
| URI | https://dx.doi.org/10.1016/j.scib.2020.06.015 https://www.ncbi.nlm.nih.gov/pubmed/36659037 https://hal.science/hal-02935124 |
| Volume | 65 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR3ZattAcIidl76UpOnhpjVL6UNDEV5Jq2MfjZvgNLExTQJ5E3toa5ViG9s9of_eGWmVEAh5yJOQZg-xMzsXcwC8d7GlUj5JILSMAuG4CVSqRZBbpZ1GkWAtOfQn03R8JT5fJ9c7MGpzYSis0vP-hqfX3Np_GfjTHKyqanARkQsLpW-EdBpLkXVgF8VRlHdhd3h6Np7eulqEJLuF2sxx6kyIc3z6TBPphatrtBQjXlfypAa594uozpxiJe9on7UUOtmDp159ZMPmD_dhp1w8g31_QTfsg68ifXQA_yZt41umFpbNKexlidRS_S0tQ4FFdYwRdroORiv2CzXONVv-rpoOS6x26vzZbDdM4yCUbuz40-WQLdf0nMyYQgBlehGEVkfSmdeRfOx79ZWSh5_D1cnx5Wgc-F4LgRGx2AZWoybgDDdCmKyUCVfWhabMtUuN1BKvts1zPEe0jpx1pgw1D1WY2dQJlVvUCV5Ad7FclK-AycyqMtE6IrtbqBDhXJrYoq1p0jwzPfjYHm-xakpqFG2s2beCkFEQMgoKuAuTHiQtBoo7hFEgz39w3jtE180GVEV7PDwv6BtHFQf1HPEz7MHLBps34-I0TSSPs9eP3PYQntAbSbcweQPd7fpH-RbVlq3uI1mOvpzP-p48-9CZzib_AUZI7Ig |
| link.rule.ids | 230,315,783,787,888,24128,27936,27937,45691 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Zi9swEB72eGhfSrdneorSh5ZiItvyoceQ7uJ0k1BoFvZN6LAal5KEJD2h_70ztrxlofShTwaNDqMZab4ZRjMAL33qKJVPFgkjk0h4biOdGxGVThtvUCU4Rw792TyvLsS7y-zyAMb9WxgKqwx3f3ent7d1aBmG3Rxummb4ISEXFmrfBOU0laI4hGNEAxJP5_Focl7N_7hahCS7hcrMcapMiGPC85ku0gtnN2gpJrzN5EkFcv-uog6XFCt5DX22WujsNtwK8JGNuj88gYN6dQdOwgHdsVchi_Tru_Br1he-ZXrl2JLCXtYoLc3P2jFUWJTHGGmTbTTesG-IOLds_b3pKiyx1qnzY7ffMYOdULux07eLEVtv6Tt7zzQS6KUXUWh2FJ1lG8nHPjcf6fHwPbg4O12MqyjUWoisSMU-cgaRgLfcCmGLWmZcOx_bujQ-t9JIPNquLHEf0Tryzts6NjzWceFyL3TpEBPch6PVelU_BCYLp-vMmITsbqFjpHNpU4e2ps3Lwg7gTb-9atOl1FB9rNknRcxQxAxFAXdxNoCs54C6JhgK7_x_jnuB7LpagLJoV6OpojaOEAdxjvgaD-BBx82rfmmeZ5KnxaP_XPY53KgWs6maTubnj-EmUUjTxdkTONpvv9RPEcLszbMgor8BlmTs2Q |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Molecular+and+heterogenized+dinuclear+Ir-Cp+water+oxidation+catalysts+bearing+EDTA+or+EDTMP+as+bridging+and+anchoring+ligands&rft.jtitle=Science+bulletin+%28Beijing%29&rft.au=Domestici%2C+C.&rft.au=Tensi%2C+L.&rft.au=Zaccaria%2C+F.&rft.au=Kissimina%2C+N.&rft.date=2020-10-15&rft.pub=Elsevier&rft.issn=2095-9273&rft.volume=65&rft.issue=19&rft.spage=1614&rft.epage=1625&rft_id=info:doi/10.1016%2Fj.scib.2020.06.015&rft.externalDBID=HAS_PDF_LINK&rft.externalDocID=oai_HAL_hal_02935124v1 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2095-9273&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2095-9273&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2095-9273&client=summon |