Isoselenazole Synthesis by Rh-Catalyzed Direct Annulation of Benzimidates with Sodium Selenite

• Published in: Chemistry an international journal Vol. 5; no. 4; pp. 2068 - 2074
• Main Authors: Xu-Xu, Qing-Feng, Nishii, Yuji, Miura, Masahiro
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.09.2023
• Subjects: Acids; annulation; Catalysis; Chemical reactions; Chemical synthesis; Chemistry; Chromatography; C–H bond cleavage; direct coupling; NMR; Nuclear magnetic resonance; Organic chemistry; organoselenium compound; Organoselenium compounds; Reagents; Selenites; Selenium; Sodium; Solvents

Organoselenium compounds have attracted significant research interest because of their potent therapeutic activities and indispensable applications in the organic chemistry field. The selenation reactions conventionally rely on the use of sensitive Se reagents; thus, new synthetic methods with impro...