Enhanced removal of Cr(VI) from aqueous solution by stabilized nanoscale zero valent iron and copper bimetal intercalated montmorillonite

[Display omitted] Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0) nanocomposite. MMT-nFe0/Cu0 was characterized using SEM, TEM, XRD, FTIR, N2 adsorption–desorption isotherms and XPS. The results demonst...

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Published inJournal of colloid and interface science Vol. 606; no. Pt 2; pp. 941 - 952
Main Authors Wang, Yin, Gong, Yishu, Lin, Naipeng, Yu, Lan, Du, Baobao, Zhang, Xiaodong
Format Journal Article
LanguageEnglish
Published Elsevier Inc 15.01.2022
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Abstract [Display omitted] Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0) nanocomposite. MMT-nFe0/Cu0 was characterized using SEM, TEM, XRD, FTIR, N2 adsorption–desorption isotherms and XPS. The results demonstrated that highly dispersed nanoscale Fe0/Cu0 (nFe0/Cu0) were successfully introduced into the montmorillonite (MMT) layers. In the reaction process, the combination of Cu0 and Fe0 acted as a galvanic cell, and electrocorrosion not only speeded up the reaction rate, but also increased reduction activity of nFe0. MMT-nFe0/Cu0 as an excellent carrier had good functions in dispersing nFe0 and Cu0 particles, pH buffering and could keep nFe0 and Cu0 particles from being released. Besides, no iron ions and very low concentrations of copper ions released in the reaction system, which greatly avoided the influence of secondary environmental pollution.
AbstractList Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe⁰/Cu⁰) nanocomposite. MMT-nFe⁰/Cu⁰ was characterized using SEM, TEM, XRD, FTIR, N₂ adsorption–desorption isotherms and XPS. The results demonstrated that highly dispersed nanoscale Fe⁰/Cu⁰ (nFe⁰/Cu⁰) were successfully introduced into the montmorillonite (MMT) layers. In the reaction process, the combination of Cu⁰ and Fe⁰ acted as a galvanic cell, and electrocorrosion not only speeded up the reaction rate, but also increased reduction activity of nFe⁰. MMT-nFe⁰/Cu⁰ as an excellent carrier had good functions in dispersing nFe⁰ and Cu⁰ particles, pH buffering and could keep nFe⁰ and Cu⁰ particles from being released. Besides, no iron ions and very low concentrations of copper ions released in the reaction system, which greatly avoided the influence of secondary environmental pollution.
Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0) nanocomposite. MMT-nFe0/Cu0 was characterized using SEM, TEM, XRD, FTIR, N2 adsorption-desorption isotherms and XPS. The results demonstrated that highly dispersed nanoscale Fe0/Cu0 (nFe0/Cu0) were successfully introduced into the montmorillonite (MMT) layers. In the reaction process, the combination of Cu0 and Fe0 acted as a galvanic cell, and electrocorrosion not only speeded up the reaction rate, but also increased reduction activity of nFe0. MMT-nFe0/Cu0 as an excellent carrier had good functions in dispersing nFe0 and Cu0 particles, pH buffering and could keep nFe0 and Cu0 particles from being released. Besides, no iron ions and very low concentrations of copper ions released in the reaction system, which greatly avoided the influence of secondary environmental pollution.Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0) nanocomposite. MMT-nFe0/Cu0 was characterized using SEM, TEM, XRD, FTIR, N2 adsorption-desorption isotherms and XPS. The results demonstrated that highly dispersed nanoscale Fe0/Cu0 (nFe0/Cu0) were successfully introduced into the montmorillonite (MMT) layers. In the reaction process, the combination of Cu0 and Fe0 acted as a galvanic cell, and electrocorrosion not only speeded up the reaction rate, but also increased reduction activity of nFe0. MMT-nFe0/Cu0 as an excellent carrier had good functions in dispersing nFe0 and Cu0 particles, pH buffering and could keep nFe0 and Cu0 particles from being released. Besides, no iron ions and very low concentrations of copper ions released in the reaction system, which greatly avoided the influence of secondary environmental pollution.
[Display omitted] Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0) nanocomposite. MMT-nFe0/Cu0 was characterized using SEM, TEM, XRD, FTIR, N2 adsorption–desorption isotherms and XPS. The results demonstrated that highly dispersed nanoscale Fe0/Cu0 (nFe0/Cu0) were successfully introduced into the montmorillonite (MMT) layers. In the reaction process, the combination of Cu0 and Fe0 acted as a galvanic cell, and electrocorrosion not only speeded up the reaction rate, but also increased reduction activity of nFe0. MMT-nFe0/Cu0 as an excellent carrier had good functions in dispersing nFe0 and Cu0 particles, pH buffering and could keep nFe0 and Cu0 particles from being released. Besides, no iron ions and very low concentrations of copper ions released in the reaction system, which greatly avoided the influence of secondary environmental pollution.
Author Gong, Yishu
Zhang, Xiaodong
Du, Baobao
Yu, Lan
Lin, Naipeng
Wang, Yin
Author_xml – sequence: 1
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  surname: Wang
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  givenname: Yishu
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  givenname: Naipeng
  surname: Lin
  fullname: Lin, Naipeng
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  givenname: Lan
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  givenname: Baobao
  surname: Du
  fullname: Du, Baobao
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  givenname: Xiaodong
  surname: Zhang
  fullname: Zhang, Xiaodong
  email: zhangxiaodong@usst.edu.cn
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Montmorillonite
Copper
Nanoscale zero valent iron
Galvanic cell
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PublicationDate 2022-01-15
PublicationDateYYYYMMDD 2022-01-15
PublicationDate_xml – month: 01
  year: 2022
  text: 2022-01-15
  day: 15
PublicationDecade 2020
PublicationTitle Journal of colloid and interface science
PublicationYear 2022
Publisher Elsevier Inc
Publisher_xml – name: Elsevier Inc
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Snippet [Display omitted] Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite...
Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe0/Cu0)...
Batch experiments were conducted to study the Cr(VI) removal by nanoscale zero valent iron and copper intercalated montmorillonite (MMT-nFe⁰/Cu⁰)...
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SubjectTerms aqueous solutions
Copper
Cr(VI)
Galvanic cell
iron
Montmorillonite
nanocomposites
Nanoscale zero valent iron
pollution
Title Enhanced removal of Cr(VI) from aqueous solution by stabilized nanoscale zero valent iron and copper bimetal intercalated montmorillonite
URI https://dx.doi.org/10.1016/j.jcis.2021.08.075
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