Evaluation of different catalyst systems for bulk polymerization through “click” chemistry

“Click” chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a step-growth polymerization technique. In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed...

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Published inPolymer (Guilford) Vol. 52; no. 20; pp. 4435 - 4441
Main Authors Sheng, Xia, Rock, Darman M., Mauldin, Timothy C., Kessler, Michael R.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 12.09.2011
Elsevier
Subjects
Addition polymerization
Alkynes
Applied sciences
Architecture
Bulk polymerization
Catalysts
Differential scanning calorimetry
Exact sciences and technology
Kinetics
Organic polymers
Physicochemistry of polymers
Polycondensation
Polymerization
polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
Rheology
thermogravimetry
“Click” chemistry
Rheology
“Click” chemistry
Kinetics
Viscoelasticity
Propargylic compound
Ether polymer
Complex catalyst polymerization
Complex catalyst
Thermal stability
Alcohol polymer
Hydroxyether
Click chemistry
Copper
Activation energy
Organic azide
Cyclopolymerization
Copper complex
Experimental study
Functional polymer
Chemical reaction kinetics
Cyclopolymer
Triazole derivative polymer
Tertiary amine
Bromo complex
Catalyst activity
Comparative study
Charcoal
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Abstract “Click” chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a step-growth polymerization technique. In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu(PPh3)3Br and a heterogeneous Cu/C catalyst. The effects of different catalyst systems on the kinetics of the “click” polymerization were evaluated by differential scanning calorimetry (DSC) and oscillatory rheology. Additionally, the thermomechanical properties of resulting polymers were evaluated by temperature-ramp oscillatory rheology and thermal stabilities by thermogravimetry. [Display omitted]
AbstractList "Click" chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a step-growth polymerization technique. In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu(PPh3)3Br and a heterogeneous Cu/C catalyst. The effects of different catalyst systems on the kinetics of the "click" polymerization were evaluated by differential scanning calorimetry (DSC) and oscillatory rheology. Additionally, the thermomechanical properties of resulting polymers were evaluated by temperature-ramp oscillatory rheology and thermal stabilities by thermogravimetry.
“Click” chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a step-growth polymerization technique. In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu(PPh₃)₃Br and a heterogeneous Cu/C catalyst. The effects of different catalyst systems on the kinetics of the “click” polymerization were evaluated by differential scanning calorimetry (DSC) and oscillatory rheology. Additionally, the thermomechanical properties of resulting polymers were evaluated by temperature-ramp oscillatory rheology and thermal stabilities by thermogravimetry.
“Click” chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a step-growth polymerization technique. In this study, the bulk polymerization of a diyne and a bisazide were achieved through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu(PPh3)3Br and a heterogeneous Cu/C catalyst. The effects of different catalyst systems on the kinetics of the “click” polymerization were evaluated by differential scanning calorimetry (DSC) and oscillatory rheology. Additionally, the thermomechanical properties of resulting polymers were evaluated by temperature-ramp oscillatory rheology and thermal stabilities by thermogravimetry. [Display omitted]
Author Rock, Darman M.
Sheng, Xia
Mauldin, Timothy C.
Kessler, Michael R.
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Issue 20
Keywords Rheology
“Click” chemistry
Kinetics
Viscoelasticity
Propargylic compound
Ether polymer
Complex catalyst polymerization
Complex catalyst
Thermal stability
Alcohol polymer
Hydroxyether
Click chemistry
Copper
Activation energy
Organic azide
Cyclopolymerization
Copper complex
Experimental study
Functional polymer
Chemical reaction kinetics
Cyclopolymer
Triazole derivative polymer
Tertiary amine
Bromo complex
Catalyst activity
Comparative study
Charcoal
Language English
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Snippet “Click” chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a...
"Click" chemistry is a frequently used technique in polymer chemistry for coupling polymer end groups to construct novel copolymer architectures and as a...
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SubjectTerms Addition polymerization
Alkynes
Applied sciences
Architecture
Bulk polymerization
Catalysts
Differential scanning calorimetry
Exact sciences and technology
Kinetics
Organic polymers
Physicochemistry of polymers
Polycondensation
Polymerization
polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
Rheology
thermogravimetry
“Click” chemistry
Title Evaluation of different catalyst systems for bulk polymerization through “click” chemistry
URI https://dx.doi.org/10.1016/j.polymer.2011.07.018
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