Fabricate organic thermoelectric modules use modified PCBM and PEDOT:PSS materials
In this paper, we fabricated an organic thermo- electric (TE) device with modified [6,6]-phenyl-C61- butyric acid methyl ester (PCBM) and poly(3,4-ethylene- dioxythiophene) polystyrene sulfonate (PEDOT:PSS); the device showed good stability in air condition. For n-leg, PCBM were doped with acridine...
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Published in | Frontiers of Optoelectronics (Online) Vol. 10; no. 2; pp. 117 - 123 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Beijing
Higher Education Press
01.06.2017
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
ISSN | 2095-2759 2095-2767 |
DOI | 10.1007/s12200-017-0712-x |
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Abstract | In this paper, we fabricated an organic thermo- electric (TE) device with modified [6,6]-phenyl-C61- butyric acid methyl ester (PCBM) and poly(3,4-ethylene- dioxythiophene) polystyrene sulfonate (PEDOT:PSS); the device showed good stability in air condition. For n-leg, PCBM were doped with acridine orange base (3,6-bis (dimethylamino)acridine) (AOB) and 1,3-dimethyl-2,3- dihydro- 1H-benzoimidazole (N-DMBI). Co-doped PCBM utilizes synergistic effects of AOB and N-DMBI, resulting in excellent electrical conductivity and Seebeck coefficient values reaching 2 S/cm and -500 μV/K, respectively, at room temperature with dopant molar ratio of 0.11. P-type leg used modified PEDOT:PSS. Based on modified PCBM and PEDOT:PSS materials, we fabricated a TE module device with 48 p-type and n-type thermocouple and tested their output voltage, short current, and power. Output voltage measured -0.82 V, and generated power reached almost 945 μW with 75 K temperature gradient at 453 K hot-side temperature. These promising results showed potential of modified PEDOT and PCBM as TE materials for application in device optimization. |
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AbstractList | In this paper, we fabricated an organic thermoelectric (TE) device with modified [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS); the device showed good stability in air condition. For n-leg, PCBM were doped with acridine orange base (3,6-bis (dimethylamino)acridine) (AOB) and 1,3-dimethyl-2,3-dihydro-1H-benzoimidazole (N-DMBI). Co-doped PCBM utilizes synergistic effects of AOB and N-DMBI, resulting in excellent electrical conductivity and Seebeck coefficient values reaching 2 S/cm and -500 mV/K, respectively, at room temperature with dopant molar ratio of 0.11. P-type leg used modified PEDOT:PSS. Based on modified PCBM and PEDOT:PSS materials, we fabricated a TE module device with 48 p-type and n-type thermocouple and tested their output voltage, short current, and power. Output voltage measured ~0.82 V, and generated power reached almost 945 mW with 75 K temperature gradient at 453 K hot-side temperature. These promising results showed potential of modified PEDOT and PCBM as TE materials for application in device optimization. In this paper, we fabricated an organic thermo- electric (TE) device with modified [6,6]-phenyl-C61- butyric acid methyl ester (PCBM) and poly(3,4-ethylene- dioxythiophene) polystyrene sulfonate (PEDOT:PSS); the device showed good stability in air condition. For n-leg, PCBM were doped with acridine orange base (3,6-bis (dimethylamino)acridine) (AOB) and 1,3-dimethyl-2,3- dihydro- 1H-benzoimidazole (N-DMBI). Co-doped PCBM utilizes synergistic effects of AOB and N-DMBI, resulting in excellent electrical conductivity and Seebeck coefficient values reaching 2 S/cm and -500 μV/K, respectively, at room temperature with dopant molar ratio of 0.11. P-type leg used modified PEDOT:PSS. Based on modified PCBM and PEDOT:PSS materials, we fabricated a TE module device with 48 p-type and n-type thermocouple and tested their output voltage, short current, and power. Output voltage measured -0.82 V, and generated power reached almost 945 μW with 75 K temperature gradient at 453 K hot-side temperature. These promising results showed potential of modified PEDOT and PCBM as TE materials for application in device optimization. |
Author | FengGAO Yuchun LIU Yan XIONG Ping WU Bin HU Ling XU |
AuthorAffiliation | Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China |
Author_xml | – sequence: 1 givenname: Feng surname: GAO fullname: GAO, Feng organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China – sequence: 2 givenname: Yuchun surname: LIU fullname: LIU, Yuchun organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China – sequence: 3 givenname: Yan surname: XIONG fullname: XIONG, Yan organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China – sequence: 4 givenname: Ping surname: WU fullname: WU, Ping organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China – sequence: 5 givenname: Bin surname: HU fullname: HU, Bin organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China – sequence: 6 givenname: Ling surname: XU fullname: XU, Ling email: xuling@mail.hust.edu.cn organization: Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China |
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Keywords | organic thermoelectric generator thermocouple [6.6]-phenyl-C61butyric acid methyl ester (PCBM) poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) |
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Notes | 10-1029/TN In this paper, we fabricated an organic thermo- electric (TE) device with modified [6,6]-phenyl-C61- butyric acid methyl ester (PCBM) and poly(3,4-ethylene- dioxythiophene) polystyrene sulfonate (PEDOT:PSS); the device showed good stability in air condition. For n-leg, PCBM were doped with acridine orange base (3,6-bis (dimethylamino)acridine) (AOB) and 1,3-dimethyl-2,3- dihydro- 1H-benzoimidazole (N-DMBI). Co-doped PCBM utilizes synergistic effects of AOB and N-DMBI, resulting in excellent electrical conductivity and Seebeck coefficient values reaching 2 S/cm and -500 μV/K, respectively, at room temperature with dopant molar ratio of 0.11. P-type leg used modified PEDOT:PSS. Based on modified PCBM and PEDOT:PSS materials, we fabricated a TE module device with 48 p-type and n-type thermocouple and tested their output voltage, short current, and power. Output voltage measured -0.82 V, and generated power reached almost 945 μW with 75 K temperature gradient at 453 K hot-side temperature. These promising results showed potential of modified PEDOT and PCBM as TE materials for application in device optimization. organic thermoelectric generator, thermocou-pie, poly(3,4-ethylenedioxythiophene) polystyrene sulfo-nate (PEDOT-PSS), [6.6]-phenyl-C61butyric acid methylester (PCBM) Document accepted on :2017-05-04 organic thermoelectric generator thermocouple [6.6]-phenyl-C61butyric acid methyl ester (PCBM) Document received on :2017-03-22 poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
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Snippet | In this paper, we fabricated an organic thermo- electric (TE) device with modified [6,6]-phenyl-C61- butyric acid methyl ester (PCBM) and poly(3,4-ethylene-... In this paper, we fabricated an organic thermoelectric (TE) device with modified [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and... |
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SubjectTerms | [6.6]-phenyl-C61butyric acid methyl ester (PCBM) Biomedical Engineering and Bioengineering Butyric acid Electric potential Electrical Engineering Electrical resistivity Engineering Modules organic thermoelectric generator Physics poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) Polystyrene resins Research Article Temperature gradients thermocouple Thermoelectricity |
Title | Fabricate organic thermoelectric modules use modified PCBM and PEDOT:PSS materials |
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