Application of High-Porosity Ceramic Block-Cellular Palladium Catalysts in the Oxidation of Hydrogen Isotopes

The main physical-chemical characteristics of ceramic high-porosity block-cellular catalysts coated with a palladium active layer in the process of oxidation of hydrogen under different experimental conditions are presented. It is concluded on the basis of the data obtained on the energy of activati...

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Published inGlass and ceramics Vol. 71; no. 11-12; pp. 396 - 399
Main Authors Gasparyan, M. D., Grunskii, V. N., Bespalov, A. V., Popova, N. A., Bagramyan, T. A., Grigoryan, N. S., Abrashov, A. A., Rozenkevich, M. B., Pak, Yu. S., Bukin, A. N., Sumchenko, A. S.
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Published Boston Springer US 01.03.2015
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Abstract The main physical-chemical characteristics of ceramic high-porosity block-cellular catalysts coated with a palladium active layer in the process of oxidation of hydrogen under different experimental conditions are presented. It is concluded on the basis of the data obtained on the energy of activation and catalytic activity that in comparison with imported granular catalysts they hold promise for use in the catalytic oxidation of hydrogen isotopes.
AbstractList The main physical-chemical characteristics of ceramic high-porosity block-cellular catalysts coated with a palladium active layer in the process of oxidation of hydrogen under different experimental conditions are presented. It is concluded on the basis of the data obtained on the energy of activation and catalytic activity that in comparison with imported granular catalysts they hold promise for use in the catalytic oxidation of hydrogen isotopes.
Audience Academic
Author Pak, Yu. S.
Bespalov, A. V.
Bagramyan, T. A.
Abrashov, A. A.
Grigoryan, N. S.
Grunskii, V. N.
Rozenkevich, M. B.
Popova, N. A.
Sumchenko, A. S.
Bukin, A. N.
Gasparyan, M. D.
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Issue 11-12
Keywords activation energy
activity of catalyst
high-porosity ceramic block-cellular catalysts
gas-dynamic resistance
hydrogen oxidation reaction rate constant
palladium active layer
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References M. D. Gasparyan, V. N. Grunskii, A. V. Bespalov, et al., “Highporosity ceramic block-cellular catalysts, coated with a palladium active layer, for oxidation of hydrogen isotopes,” Steklo Keram., No. 9, 24 – 27 (2014).
M. D. Gasparyan, V. N. Grunskii, A. V. Bespalov, et al., “Prospects for using high-porosity ceramic block-cellular filters-sorbents of gaseous radioactive cesium in solving the problems of securing the ecological safety of operations in the nuclear industry,” Ékologiya Promysh. Proizvod., No. 1, 26 – 33 (2014).
M. D. Gasparyan, I. A. Kozlov, V. N. Grunskii, et al., Method of Obtaining Ceramic Block-Cellular Filters-Sorbents for Catching Gaseous Radioactive and Harmful Substances, RF Patent No. 2474558 [in Russian]; published February 10, 2013.
M. D. Gasparyan, V. N. Grunskii, A. V. Bespalov, et al., “Highporosity ceramic block-cellular catalysts with a palladium active layer for oxidation of hydrogen isotopes,” Ogneup. Tekh. Keram., No. 7 – 8, 49 – 54 (2014).
BukinANGorbatenkoEAMarunichSARozenkevichMBCharacteristics of deep catalytic oxidation of hydrogen using the catalyst Pt/γ-Al2O3 in application to the process of purifying air by removing tritiumUsp. Khim. Khimich. Tekhnol.2010247(112)4449
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SubjectTerms At Enterprises and Institutes
Ceramics
Characterization and Evaluation of Materials
Chemical properties
Chemistry and Materials Science
Composites
Glass
Hydrogen
Materials Science
Natural Materials
Oxidation-reduction reaction
Palladium
Palladium catalysts
Porosity
Title Application of High-Porosity Ceramic Block-Cellular Palladium Catalysts in the Oxidation of Hydrogen Isotopes
URI https://link.springer.com/article/10.1007/s10717-015-9696-4
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