Electroactive polymeric material with condensed structure on the basis of magnesium(II) polyporphine

• Published in: Electrochimica acta Vol. 56; no. 10; pp. 3436 - 3442
• Main Authors: Vorotyntsev, Mikhail A., Konev, Dmitry V., Devillers, Charles H., Bezverkhyy, Igor, Heintz, Olivier
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.04.2011; Elsevier
• Subjects: Analytical chemistry; Anodizing; Chemical Sciences; Conducting polymer; Coordination chemistry; C–C coupling; Documents; Electroactive materials; Electroactive polymers; Electrodes; Electronics; Electropolymerization; Magnesium porphine; Material chemistry; Molecular structure; Organic chemistry; Porphines; Unsubstituted porphyrin; X-ray photoelectron spectroscopy; C–C coupling; Electroactive materials; Conducting polymer; Unsubstituted porphyrin; Electropolymerization; Magnesium porphine; C-C coupling; conducting polymer; electropolymerization; magnesium porphine; unsubstituted porphyrin; electroactive materials

Previous publication of the authors presented evidences that electrochemical oxidation of Mg(II) porphine (fully unsubstituted porphyrin, MgP) in acetonitrile (AN) at a very low potential leads to deposition of films at electrode surface corresponding to typical electroactive polymers, with their re...