Fourier Transform Infrared (FTIR) Spectroscopy for Measurements of Vehicle Exhaust Emissions: A Review
Pollution from vehicles is a serious concern for the environment and human health. Vehicle emission regulations worldwide have limits for pollutants such as hydrocarbons, CO, and NOx. The measurements are typically conducted at engine dynamometers (heavy-duty engines) sampling from the tailpipe or a...
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Published in | Applied sciences Vol. 11; no. 16; p. 7416 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Basel
MDPI AG
12.08.2021
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Online Access | Get full text |
ISSN | 2076-3417 2076-3417 |
DOI | 10.3390/app11167416 |
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Abstract | Pollution from vehicles is a serious concern for the environment and human health. Vehicle emission regulations worldwide have limits for pollutants such as hydrocarbons, CO, and NOx. The measurements are typically conducted at engine dynamometers (heavy-duty engines) sampling from the tailpipe or at chassis dynamometers (light-duty vehicles) sampling from the dilution tunnel. The latest regulations focused on the actual emissions of the vehicles on the road. Greenhouse gases (GHG) (such as CO2, CH4, N2O), and NH3 have also been the subject of some regulations. One instrument that can measure many gaseous compounds simultaneously is the Fourier transform infrared (FTIR) spectrometer. In this review the studies that assessed FTIRs since the 1980s are summarized. Studies with calibration gases or vehicle exhaust gas in comparison with well-established techniques were included. The main conclusion is that FTIRs, even when used at the tailpipe and not at the dilution tunnel, provide comparable results with other well-established techniques for CO2, CO, NOx, while for hydrocarbons, higher deviations were noticed. The introduction of FTIRs in the regulation needs a careful description of the technical requirements, especially interference tests. Although the limited results of prototype portable FTIRs for on-road measurement are promising, their performance at the wide range of environmental conditions (temperature, pressure, vibrations) needs further studies. |
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AbstractList | Featured ApplicationThe review showed that sampling with FTIR from the tailpipe of vehicles for the determination of various gaseous pollutants is a possible alternative to currently regulated techniques.AbstractPollution from vehicles is a serious concern for the environment and human health. Vehicle emission regulations worldwide have limits for pollutants such as hydrocarbons, CO, and NOx. The measurements are typically conducted at engine dynamometers (heavy-duty engines) sampling from the tailpipe or at chassis dynamometers (light-duty vehicles) sampling from the dilution tunnel. The latest regulations focused on the actual emissions of the vehicles on the road. Greenhouse gases (GHG) (such as CO2, CH4, N2O), and NH3 have also been the subject of some regulations. One instrument that can measure many gaseous compounds simultaneously is the Fourier transform infrared (FTIR) spectrometer. In this review the studies that assessed FTIRs since the 1980s are summarized. Studies with calibration gases or vehicle exhaust gas in comparison with well-established techniques were included. The main conclusion is that FTIRs, even when used at the tailpipe and not at the dilution tunnel, provide comparable results with other well-established techniques for CO2, CO, NOx, while for hydrocarbons, higher deviations were noticed. The introduction of FTIRs in the regulation needs a careful description of the technical requirements, especially interference tests. Although the limited results of prototype portable FTIRs for on-road measurement are promising, their performance at the wide range of environmental conditions (temperature, pressure, vibrations) needs further studies. Pollution from vehicles is a serious concern for the environment and human health. Vehicle emission regulations worldwide have limits for pollutants such as hydrocarbons, CO, and NOx. The measurements are typically conducted at engine dynamometers (heavy-duty engines) sampling from the tailpipe or at chassis dynamometers (light-duty vehicles) sampling from the dilution tunnel. The latest regulations focused on the actual emissions of the vehicles on the road. Greenhouse gases (GHG) (such as CO2, CH4, N2O), and NH3 have also been the subject of some regulations. One instrument that can measure many gaseous compounds simultaneously is the Fourier transform infrared (FTIR) spectrometer. In this review the studies that assessed FTIRs since the 1980s are summarized. Studies with calibration gases or vehicle exhaust gas in comparison with well-established techniques were included. The main conclusion is that FTIRs, even when used at the tailpipe and not at the dilution tunnel, provide comparable results with other well-established techniques for CO2, CO, NOx, while for hydrocarbons, higher deviations were noticed. The introduction of FTIRs in the regulation needs a careful description of the technical requirements, especially interference tests. Although the limited results of prototype portable FTIRs for on-road measurement are promising, their performance at the wide range of environmental conditions (temperature, pressure, vibrations) needs further studies. |
Author | Giechaskiel, Barouch Clairotte, Michaël |
Author_xml | – sequence: 1 givenname: Barouch surname: Giechaskiel fullname: Giechaskiel, Barouch – sequence: 2 givenname: Michaël surname: Clairotte fullname: Clairotte, Michaël |
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Snippet | Pollution from vehicles is a serious concern for the environment and human health. Vehicle emission regulations worldwide have limits for pollutants such as... Featured ApplicationThe review showed that sampling with FTIR from the tailpipe of vehicles for the determination of various gaseous pollutants is a possible... |
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StartPage | 7416 |
SubjectTerms | Air pollution CLA Conformity Emissions Engines formaldehyde FTIR Gases Gasoline Laboratories Light Measurement techniques NDIR NDUV NH3 Nitrogen Pollutants Regulation Temperature Vehicles |
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Title | Fourier Transform Infrared (FTIR) Spectroscopy for Measurements of Vehicle Exhaust Emissions: A Review |
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