Tensile properties of two responsive hydrogels
Temperature-responsive hydrogels were prepared from N-vinyl caprolactam/ethylene glycol dimethacrylate (PVCL) or from hydroxypropylcellulose/divinyl sulfone (HPC). Both gels undergo reversible volume shrinkage between room temperature and 50 °C, and for both, the tensile stress–strain behavior in th...
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Published in | Polymer (Guilford) Vol. 45; no. 26; pp. 8837 - 8843 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Oxford
Elsevier Ltd
01.12.2004
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | Temperature-responsive hydrogels were prepared from
N-vinyl caprolactam/ethylene glycol dimethacrylate (PVCL) or from hydroxypropylcellulose/divinyl sulfone (HPC). Both gels undergo reversible volume shrinkage between room temperature and 50
°C, and for both, the tensile stress–strain behavior in the collapsed state above the temperature-induced transition is qualitatively different from that at room temperature. At the higher temperature, PVCL gels become stiffer, more ductile, and more viscoelastic. HPC gels, on the other hand, have lower initial tangent moduli in the high-temperature state. Possible molecular mechanisms are suggested, and implications for the design of temperature-responsive actuators (‘artificial muscles’) from these materials are discussed. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 0032-3861 1873-2291 |
DOI: | 10.1016/j.polymer.2004.09.088 |