Surface modification of commercial cellulose acetate membranes using surface-initiated polymerization of 2-hydroxyethyl methacrylate to improve membrane surface biofouling resistance

► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties. To improve biofouling resistance, cellulose acetate...

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Published inJournal of membrane science Vol. 385; pp. 30 - 39
Main Authors Worthley, Clare H., Constantopoulos, Kristina T., Ginic-Markovic, Milena, Pillar, Rachel J., Matisons, Janis G., Clarke, Stephen
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.12.2011
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Abstract ► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties. To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling.
AbstractList To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling.
► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties. To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling.
Author Worthley, Clare H.
Ginic-Markovic, Milena
Pillar, Rachel J.
Constantopoulos, Kristina T.
Matisons, Janis G.
Clarke, Stephen
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Keywords Desalination
Activators regenerated by electron transfer (ARGET)
Atom transfer radical polymerization (ATRP)
Reverse osmosis
2-Hydroxyethyl methacrylate (HEMA)
Cellulose acetate
Membrane modification
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Snippet ► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine...
To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer...
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SubjectTerms 2-Hydroxyethyl methacrylate (HEMA)
Activators regenerated by electron transfer (ARGET)
aquariums
artificial membranes
Atom transfer radical polymerization (ATRP)
atomic force microscopy
biofouling
Cellulose acetate
coatings
contact angle
Desalination
electron transfer
hydrophilicity
Membrane modification
polymerization
polymers
Reverse osmosis
roughness
seawater
sodium chloride
tanks
thermogravimetry
Title Surface modification of commercial cellulose acetate membranes using surface-initiated polymerization of 2-hydroxyethyl methacrylate to improve membrane surface biofouling resistance
URI https://dx.doi.org/10.1016/j.memsci.2011.09.017
https://search.proquest.com/docview/1464506793
Volume 385
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