Surface modification of commercial cellulose acetate membranes using surface-initiated polymerization of 2-hydroxyethyl methacrylate to improve membrane surface biofouling resistance
► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties. To improve biofouling resistance, cellulose acetate...
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Published in | Journal of membrane science Vol. 385; pp. 30 - 39 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.12.2011
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Abstract | ► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties.
To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling. |
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AbstractList | To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling. ► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine membranes. ► Membranes with low graft density showed no major loss of filtration properties. To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer radical polymerization (ATRP) initiator, 2-bromoisobutyryl bromide, followed by polymeric grafting of 2-hydroxyethyl methacrylate (pHEMA) using activators regenerated by electron transfer (ARGET) ATRP. Thermogravimetric analysis (TGA), atomic force microscopy (AFM) and water contact angle (WCA) measurements of pristine and modified membranes were performed to measure and compare the amount of polymer deposited, the surface morphology and the hydrophilicity of the surfaces, respectively. Roughness and hydrophilicity increased with graft density. The biofouling resistance of pHEMA-modified membranes immersed in seawater aquarium tanks was compared to pristine membranes and the effect of pHEMA coating on water flux and NaCl rejection was measured. Based on stirred-cell and aquaria experiments, pHEMA-modified membranes with low graft density showed just a 6% decrease in salt rejection and water flux relative to pristine CA membranes, and a 24% improvement in resistance to seawater microbial biofouling. |
Author | Worthley, Clare H. Ginic-Markovic, Milena Pillar, Rachel J. Constantopoulos, Kristina T. Matisons, Janis G. Clarke, Stephen |
Author_xml | – sequence: 1 givenname: Clare H. surname: Worthley fullname: Worthley, Clare H. email: john0426@flinders.edu.au – sequence: 2 givenname: Kristina T. surname: Constantopoulos fullname: Constantopoulos, Kristina T. – sequence: 3 givenname: Milena surname: Ginic-Markovic fullname: Ginic-Markovic, Milena – sequence: 4 givenname: Rachel J. surname: Pillar fullname: Pillar, Rachel J. – sequence: 5 givenname: Janis G. surname: Matisons fullname: Matisons, Janis G. – sequence: 6 givenname: Stephen surname: Clarke fullname: Clarke, Stephen |
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Keywords | Desalination Activators regenerated by electron transfer (ARGET) Atom transfer radical polymerization (ATRP) Reverse osmosis 2-Hydroxyethyl methacrylate (HEMA) Cellulose acetate Membrane modification |
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Snippet | ► Cellulose acetate reverse osmosis membranes surface-modified with polyHEMA. ► Modified membranes showed a greater resistance to biofouling than pristine... To improve biofouling resistance, cellulose acetate (CA) reverse osmosis membranes were modified by reacting surface hydroxyl groups with an atom transfer... |
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SubjectTerms | 2-Hydroxyethyl methacrylate (HEMA) Activators regenerated by electron transfer (ARGET) aquariums artificial membranes Atom transfer radical polymerization (ATRP) atomic force microscopy biofouling Cellulose acetate coatings contact angle Desalination electron transfer hydrophilicity Membrane modification polymerization polymers Reverse osmosis roughness seawater sodium chloride tanks thermogravimetry |
Title | Surface modification of commercial cellulose acetate membranes using surface-initiated polymerization of 2-hydroxyethyl methacrylate to improve membrane surface biofouling resistance |
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