Characterizing archaeological bronze corrosion products intersecting electrochemical impedance measurements with voltammetry of immobilized particles

• Published in: Electrochimica acta Vol. 246; pp. 269 - 279
• Main Authors: Redondo-Marugán, Jorge, Piquero-Cilla, Joan, Doménech-Carbó, María Teresa, Ramírez-Barat, Blanca, Sekhaneh, Wassef Al, Capelo, Sofia, Doménech-Carbó, Antonio
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 20.08.2017; Elsevier BV
• Subjects: Archaeological bronze; Copper; Corrosion; Corrosion products; Electrochemical Impedance Measurements; Electrodes; Galvanic corrosion; Graphite; Historic sites; Historical metallurgy; Voltammetry of immobilized particles; Electrochemical Impedance Measurements; Archaeological bronze; Voltammetry of immobilized particles
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2017.05.190

[Display omitted] •Electrochemical impedance measurements are applied to microparticulate deposits of copper corrosion products.•Voltammetry of microparticles measurements is also used.•Characterization of corrosion products in archaeological metal samples is provided.•Electrochemical grouping of samples suggests different provenances/manufacturing techniques. Application of electrochemical impedance measurements to microparticulate deposits of copper corrosion products attached to graphite electrodes in contact with 0.10M aqueous HClO4 electrolyte is described. The impedance measurements were sensitive to the applied potential and the amount of solid sample and were modeled taking into account the contribution of the uncovered base electrode. Several pairs of circuit elements provide monotonic variations which are able to characterize different corrosion compounds regardless the amount of microparticulate solid on the electrode. Application to a set of archaeological samples from the archaeological Roman site of Gadara (Jordan, 4th century AD) permitted to establish a grouping of such samples suggesting different provenances/manufacturing techniques.