Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0.8Co0.2O2 epitaxial film electrode synthesized by pulsed laser deposition method

An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of L...

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Published in	Electrochimica acta Vol. 53; no. 2; pp. 871 - 881
Main Authors	HIRAYAMA, Masaaki, SAKAMOTO, Kazuyuki, HIRAIDE, Tetsuya, MORI, Daisuke, YAMADA, Atsuo, KANNO, Ryoji, SONOYAMA, Noriyuki, TAMURA, Kazuhisa, MIZUKI, Jun'Ichiro
Format	Journal Article
Language	English
Published	Oxford Elsevier 01.12.2007
Subjects	Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Atomic force microscopy Cobalt Oxides Nickel Oxides In situ Laser deposition Solid electrolyte Lithium Oxides Electrode electrolyte interface X ray Electrode material Thin film Surface structure Characterization Reflectometry Chemical synthesis Cathode Secondary cell SEI layer Lithium battery Reflectivity Quaternary compound Pulsed laser Epitaxial thin film Thin layer electrode Morphology Cathode materials Reflectance
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Abstract	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of LiNi0.8Co0.2O2 synthesized by the pulsed laser deposition method. The orientation of the epitaxial film depends on the substrate plane; the 2D layer of LiNi0.8Co0.2O2 is parallel to the SrTiO3 (111) substrate ((003)LiCo0.2Ni0.8O2//(111)SrTiO3), while the 2D layer is perpendicular to the SrTiO3 (110) substrate ((110)LiCo0.2Ni0.8O2//(110)SrTiO3). These films provided an ideal reaction field suitable for detecting structure changes at the electrode/electrolyte interface during the electrochemical reaction. The X-ray reflectometry indicated a formation of a thin-film layer at the LiNi0.8Co0.2O2 (110)/electrolyte interface during the first charge-discharge cycle, while the LiNi0.8Co0.2O2 (003) surface showed an increase in the surface roughness without forming the surface thin-film layer. The reaction mechanism at the electrode/electrolyte interface is discussed based on our new experimental technique for lithium batteries.
AbstractList	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of LiNi0.8Co0.2O2 synthesized by the pulsed laser deposition method. The orientation of the epitaxial film depends on the substrate plane; the 2D layer of LiNi0.8Co0.2O2 is parallel to the SrTiO3 (111) substrate ((003)LiCo0.2Ni0.8O2//(111)SrTiO3), while the 2D layer is perpendicular to the SrTiO3 (110) substrate ((110)LiCo0.2Ni0.8O2//(110)SrTiO3). These films provided an ideal reaction field suitable for detecting structure changes at the electrode/electrolyte interface during the electrochemical reaction. The X-ray reflectometry indicated a formation of a thin-film layer at the LiNi0.8Co0.2O2 (110)/electrolyte interface during the first charge-discharge cycle, while the LiNi0.8Co0.2O2 (003) surface showed an increase in the surface roughness without forming the surface thin-film layer. The reaction mechanism at the electrode/electrolyte interface is discussed based on our new experimental technique for lithium batteries.
Author	MIZUKI, Jun'Ichiro HIRAYAMA, Masaaki YAMADA, Atsuo KANNO, Ryoji MORI, Daisuke SONOYAMA, Noriyuki SAKAMOTO, Kazuyuki TAMURA, Kazuhisa HIRAIDE, Tetsuya
Author_xml	– sequence: 1 givenname: Masaaki surname: HIRAYAMA fullname: HIRAYAMA, Masaaki organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 2 givenname: Kazuyuki surname: SAKAMOTO fullname: SAKAMOTO, Kazuyuki organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 3 givenname: Tetsuya surname: HIRAIDE fullname: HIRAIDE, Tetsuya organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 4 givenname: Daisuke surname: MORI fullname: MORI, Daisuke organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 5 givenname: Atsuo surname: YAMADA fullname: YAMADA, Atsuo organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 6 givenname: Ryoji surname: KANNO fullname: KANNO, Ryoji organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 7 givenname: Noriyuki surname: SONOYAMA fullname: SONOYAMA, Noriyuki organization: Graduate School of Engineering, Environmental Technology & Urban Planning, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan – sequence: 8 givenname: Kazuhisa surname: TAMURA fullname: TAMURA, Kazuhisa organization: Japan Atomic Energy Agency, Synchrotron Radiation Research Center, Kansai Research Establishment, 1-1-1 Kouto Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan – sequence: 9 givenname: Jun'Ichiro surname: MIZUKI fullname: MIZUKI, Jun'Ichiro organization: Japan Atomic Energy Agency, Synchrotron Radiation Research Center, Kansai Research Establishment, 1-1-1 Kouto Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan
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Keywords	Atomic force microscopy Cobalt Oxides Nickel Oxides In situ Laser deposition Solid electrolyte Lithium Oxides Electrode electrolyte interface X ray Electrode material Thin film Surface structure Characterization Reflectometry Chemical synthesis Cathode Secondary cell SEI layer Lithium battery Reflectivity Quaternary compound Pulsed laser Epitaxial thin film Thin layer electrode Morphology Cathode materials Reflectance
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Snippet	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray...
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SubjectTerms	Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology
Title	Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0.8Co0.2O2 epitaxial film electrode synthesized by pulsed laser deposition method
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