Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0.8Co0.2O2 epitaxial film electrode synthesized by pulsed laser deposition method

An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of L...

Full description

Saved in:

Bibliographic Details
Published in	Electrochimica acta Vol. 53; no. 2; pp. 871 - 881
Main Authors	HIRAYAMA, Masaaki, SAKAMOTO, Kazuyuki, HIRAIDE, Tetsuya, MORI, Daisuke, YAMADA, Atsuo, KANNO, Ryoji, SONOYAMA, Noriyuki, TAMURA, Kazuhisa, MIZUKI, Jun'Ichiro
Format	Journal Article
Language	English
Published	Oxford Elsevier 01.12.2007
Subjects	Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology Atomic force microscopy Cobalt Oxides Nickel Oxides In situ Laser deposition Solid electrolyte Lithium Oxides Electrode electrolyte interface X ray Electrode material Thin film Surface structure Characterization Reflectometry Chemical synthesis Cathode Secondary cell SEI layer Lithium battery Reflectivity Quaternary compound Pulsed laser Epitaxial thin film Thin layer electrode Morphology Cathode materials Reflectance
Online Access	Get full text

Cover

Loading…

Abstract	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of LiNi0.8Co0.2O2 synthesized by the pulsed laser deposition method. The orientation of the epitaxial film depends on the substrate plane; the 2D layer of LiNi0.8Co0.2O2 is parallel to the SrTiO3 (111) substrate ((003)LiCo0.2Ni0.8O2//(111)SrTiO3), while the 2D layer is perpendicular to the SrTiO3 (110) substrate ((110)LiCo0.2Ni0.8O2//(110)SrTiO3). These films provided an ideal reaction field suitable for detecting structure changes at the electrode/electrolyte interface during the electrochemical reaction. The X-ray reflectometry indicated a formation of a thin-film layer at the LiNi0.8Co0.2O2 (110)/electrolyte interface during the first charge-discharge cycle, while the LiNi0.8Co0.2O2 (003) surface showed an increase in the surface roughness without forming the surface thin-film layer. The reaction mechanism at the electrode/electrolyte interface is discussed based on our new experimental technique for lithium batteries.
AbstractList	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray reflectometry and two-dimensional model electrodes with a restricted lattice plane. The electrode was constructed with an epitaxial film of LiNi0.8Co0.2O2 synthesized by the pulsed laser deposition method. The orientation of the epitaxial film depends on the substrate plane; the 2D layer of LiNi0.8Co0.2O2 is parallel to the SrTiO3 (111) substrate ((003)LiCo0.2Ni0.8O2//(111)SrTiO3), while the 2D layer is perpendicular to the SrTiO3 (110) substrate ((110)LiCo0.2Ni0.8O2//(110)SrTiO3). These films provided an ideal reaction field suitable for detecting structure changes at the electrode/electrolyte interface during the electrochemical reaction. The X-ray reflectometry indicated a formation of a thin-film layer at the LiNi0.8Co0.2O2 (110)/electrolyte interface during the first charge-discharge cycle, while the LiNi0.8Co0.2O2 (003) surface showed an increase in the surface roughness without forming the surface thin-film layer. The reaction mechanism at the electrode/electrolyte interface is discussed based on our new experimental technique for lithium batteries.
Author	MIZUKI, Jun'Ichiro HIRAYAMA, Masaaki YAMADA, Atsuo KANNO, Ryoji MORI, Daisuke SONOYAMA, Noriyuki SAKAMOTO, Kazuyuki TAMURA, Kazuhisa HIRAIDE, Tetsuya
Author_xml	– sequence: 1 givenname: Masaaki surname: HIRAYAMA fullname: HIRAYAMA, Masaaki organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 2 givenname: Kazuyuki surname: SAKAMOTO fullname: SAKAMOTO, Kazuyuki organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 3 givenname: Tetsuya surname: HIRAIDE fullname: HIRAIDE, Tetsuya organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 4 givenname: Daisuke surname: MORI fullname: MORI, Daisuke organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 5 givenname: Atsuo surname: YAMADA fullname: YAMADA, Atsuo organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 6 givenname: Ryoji surname: KANNO fullname: KANNO, Ryoji organization: Department Of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatuta, Midori-ku, Yokohama 226-8502, Japan – sequence: 7 givenname: Noriyuki surname: SONOYAMA fullname: SONOYAMA, Noriyuki organization: Graduate School of Engineering, Environmental Technology & Urban Planning, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan – sequence: 8 givenname: Kazuhisa surname: TAMURA fullname: TAMURA, Kazuhisa organization: Japan Atomic Energy Agency, Synchrotron Radiation Research Center, Kansai Research Establishment, 1-1-1 Kouto Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan – sequence: 9 givenname: Jun'Ichiro surname: MIZUKI fullname: MIZUKI, Jun'Ichiro organization: Japan Atomic Energy Agency, Synchrotron Radiation Research Center, Kansai Research Establishment, 1-1-1 Kouto Sayo-cho, Sayo-gun, Hyogo 679-5148, Japan
BackLink	http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19214853$$DView record in Pascal Francis
BookMark	eNpFkUuLFDEUhYOMYM_obzAb3VVNHvVILaXxBY2zUXAXUqkbO006KZMUWPOn_IumehoHDuQGvnNuyLlFNz54QOgtJTUltLs_1eBAZ1VUM0L6-qLmBdpR0fOKi3a4QTtCKK-aTnSv0G1KJ1LAric79Hd_VLF4IdpHlW3wOBh8CYxhgvvr5NYM2PpCGaUBL8n6X-WOk80L_llFteIIZmPDGXJcsfITPthvltRiH0jNHhiG2Wb1xyqHjXXn5x04rT4fIdlHmPC44nlxqUxOJYh4gjmUJdu7SvAxTK_RS6MK8OZ63qEfnz5-33-pDg-fv-4_HCrdMJGrUbEeDO3E0GoFtB1GTgbVAuMEmh5Yw7ghmvdGk46PbGSMam3M1NO2EVpTfofeP-XOMfxeIGV5tkmDc8pDWJIscVzwbgP7J1DHkFL5BTlHe1ZxlZTIrSB5kv8LkltB8qKmON9dV6iklTNReW3Ts31gtBEt5_8ALSuaog
CODEN	ELCAAV
CitedBy_id	crossref_primary_10_1002_aenm_202302402 crossref_primary_10_1016_j_tsf_2016_05_017 crossref_primary_10_1021_am5032055 crossref_primary_10_5796_electrochemistry_78_413 crossref_primary_10_1021_acs_jpclett_2c02032 crossref_primary_10_1149_2_0211602jes crossref_primary_10_1016_j_jpowsour_2008_10_037 crossref_primary_10_1016_j_tsf_2012_03_029 crossref_primary_10_1021_acsaem_0c01973 crossref_primary_10_1021_am508512q crossref_primary_10_1021_acs_chemmater_1c02803 crossref_primary_10_1380_jsssj_37_52 crossref_primary_10_1039_D0CP06422J crossref_primary_10_1021_cm8033559 crossref_primary_10_5796_electrochemistry_83_701 crossref_primary_10_1021_ja105389t crossref_primary_10_1039_C6RA17390J crossref_primary_10_1016_j_electacta_2013_04_142 crossref_primary_10_5796_electrochemistry_84_802 crossref_primary_10_1016_j_elecom_2012_02_016 crossref_primary_10_1002_asia_202000384 crossref_primary_10_1021_acs_jpcc_6b02523 crossref_primary_10_1039_C7CS00180K crossref_primary_10_1007_s11581_017_2064_3 crossref_primary_10_1111_jace_14579 crossref_primary_10_1063_5_0062329 crossref_primary_10_1021_acs_chemrev_3c00331 crossref_primary_10_1007_s10008_008_0685_1 crossref_primary_10_3390_coatings9060386 crossref_primary_10_1016_j_jpowsour_2019_01_067 crossref_primary_10_1149_2_0951713jes crossref_primary_10_1021_acsami_5b05500 crossref_primary_10_1088_1742_6596_502_1_012054 crossref_primary_10_1002_celc_202100891 crossref_primary_10_1016_j_jpowsour_2012_11_008 crossref_primary_10_1039_c0dt01477j crossref_primary_10_1039_C3EE42704H crossref_primary_10_1016_j_jpowsour_2008_08_073 crossref_primary_10_1016_j_jpowsour_2015_12_133 crossref_primary_10_1039_b920271d crossref_primary_10_5796_electrochemistry_22_00079 crossref_primary_10_1246_cl_180773 crossref_primary_10_1016_j_electacta_2014_11_087 crossref_primary_10_1149_2_0111513jes crossref_primary_10_1002_celc_201500155 crossref_primary_10_1016_j_jpowsour_2012_02_044
Cites_doi	10.1149/1.1393357 10.1016/S0378-7753(03)00593-7 10.1149/1.1391688 10.1016/0039-6028(88)90314-7 10.1149/1.1838758 10.1016/0378-7753(89)80176-4 10.1016/j.electacta.2004.03.049 10.1016/0025-5408(80)90012-4 10.1021/la981048h 10.1016/S0378-7753(99)00247-5 10.1149/1.1738471 10.1149/1.1697905 10.1016/S0378-7753(01)00701-7 10.1103/PhysRev.95.359 10.1016/S0378-7753(00)00666-2 10.1016/S0022-0728(96)04862-0 10.1149/1.2086855 10.1016/0013-4686(91)85203-J 10.1016/j.jpowsour.2007.06.233 10.1016/0378-7753(89)80175-2 10.1149/1.1867652 10.1016/j.jpowsour.2003.09.009 10.1103/PhysRevLett.65.1466 10.1149/1.1763771 10.1016/S1388-2481(02)00388-0 10.1149/1.2128859 10.1016/S0378-7753(99)00216-5 10.1149/1.1763141 10.1149/1.1505636 10.1149/1.1896325 10.1016/j.jpowsour.2007.03.034
ContentType	Journal Article
Copyright	2008 INIST-CNRS
Copyright_xml	– notice: 2008 INIST-CNRS
DBID	IQODW AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M
DOI	10.1016/j.electacta.2007.07.074
DatabaseName	Pascal-Francis CrossRef Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace
DatabaseTitle	CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX
DatabaseTitleList	Materials Research Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Applied Sciences Engineering Chemistry
EISSN	1873-3859
EndPage	881
ExternalDocumentID	10_1016_j_electacta_2007_07_074 19214853
GroupedDBID	--K --M -~X .~1 08R 0R~ 1B1 1RT 1~. 1~5 29G 4.4 41~ 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABEFU ABFNM ABFRF ABMAC ABNUV ABPIF ABPTK ABTAH ABXDB ABYKQ ACBEA ACDAQ ACGFO ACGFS ACIWK ACNCT ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADIYS ADMUD AEBSH AEFWE AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AI. AIDUJ AIEXJ AIKHN AITUG AJBFU AJOXV AJQLL AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BKOJK BLXMC CS3 DU5 EBS EFJIC EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMU HZ~ H~9 IHE IQODW J1W KOM M36 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SC5 SCB SCH SDF SDG SDP SES SEW SPC SPCBC SSG SSK SSZ T5K T9H TWZ UPT VH1 VOH WH7 WUQ XFK XOL XPP YK3 ZMT ZY4 ~02 ~G- AAXKI AAYXX ABJNI AFJKZ AKRWK CITATION HVGLF LPU 7SR 7U5 8BQ 8FD JG9 L7M
ID	FETCH-LOGICAL-c428t-ba27ef16895cae159b309a5e230e47e2423f0c37fc063b2b221ccffd71548cc13
ISSN	0013-4686
IngestDate	Fri Oct 25 02:21:04 EDT 2024 Thu Sep 26 18:51:57 EDT 2024 Sun Oct 29 17:07:13 EDT 2023
IsPeerReviewed	true
IsScholarly	true
Issue	2
Keywords	Atomic force microscopy Cobalt Oxides Nickel Oxides In situ Laser deposition Solid electrolyte Lithium Oxides Electrode electrolyte interface X ray Electrode material Thin film Surface structure Characterization Reflectometry Chemical synthesis Cathode Secondary cell SEI layer Lithium battery Reflectivity Quaternary compound Pulsed laser Epitaxial thin film Thin layer electrode Morphology Cathode materials Reflectance
Language	English
License	CC BY 4.0
LinkModel	OpenURL
MergedId	FETCHMERGED-LOGICAL-c428t-ba27ef16895cae159b309a5e230e47e2423f0c37fc063b2b221ccffd71548cc13
Notes	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
PQID	30938361
PQPubID	23500
PageCount	11
ParticipantIDs	proquest_miscellaneous_30938361 crossref_primary_10_1016_j_electacta_2007_07_074 pascalfrancis_primary_19214853
PublicationCentury	2000
PublicationDate	2007-12-01
PublicationDateYYYYMMDD	2007-12-01
PublicationDate_xml	– month: 12 year: 2007 text: 2007-12-01 day: 01
PublicationDecade	2000
PublicationPlace	Oxford
PublicationPlace_xml	– name: Oxford
PublicationTitle	Electrochimica acta
PublicationYear	2007
Publisher	Elsevier
Publisher_xml	– name: Elsevier
References	Nagy (10.1016/j.electacta.2007.07.074_bib21) 1991; 36 Menetrier (10.1016/j.electacta.2007.07.074_bib16) 2004; 7 10.1016/j.electacta.2007.07.074_bib1_2 Andersson (10.1016/j.electacta.2007.07.074_bib10) 2002; 149 Bar-Tow (10.1016/j.electacta.2007.07.074_bib14) 1999; 146 Abraham (10.1016/j.electacta.2007.07.074_bib31) 2002; 4 Chen (10.1016/j.electacta.2007.07.074_bib9) 2001; 96 Samant (10.1016/j.electacta.2007.07.074_bib19) 1988; 193 Kanno (10.1016/j.electacta.2007.07.074_bib1_3) 1989; 26 Braun (10.1016/j.electacta.2007.07.074_bib24) 1997 Kanamura (10.1016/j.electacta.2007.07.074_bib7) 1996; 419 Peled (10.1016/j.electacta.2007.07.074_bib4) 1979; 126 Fong (10.1016/j.electacta.2007.07.074_bib5) 1990; 137 Schechter (10.1016/j.electacta.2007.07.074_bib13) 1999; 15 Mohri (10.1016/j.electacta.2007.07.074_bib1_4) 1989; 26 Song (10.1016/j.electacta.2007.07.074_bib30) 2004; 151 Abe (10.1016/j.electacta.2007.07.074_bib2) 2004; 151 Araki (10.1016/j.electacta.2007.07.074_bib15) 2003; 124 Mizushima (10.1016/j.electacta.2007.07.074_bib1_1) 1980; 15 Parratt (10.1016/j.electacta.2007.07.074_bib23) 1954; 95 Hirayama (10.1016/j.electacta.2007.07.074_bib26) 2007; 168 Ogumi (10.1016/j.electacta.2007.07.074_bib3) 2004; 127 Matsumoto (10.1016/j.electacta.2007.07.074_bib27) 1999; 81/82 Ocko (10.1016/j.electacta.2007.07.074_bib20) 1990; 65 Moshtev (10.1016/j.electacta.2007.07.074_bib28) 1999; 81/82 Amine (10.1016/j.electacta.2007.07.074_bib8) 2001; 97/98 Liu (10.1016/j.electacta.2007.07.074_bib29) 2004; 7 Wu (10.1016/j.electacta.2007.07.074_bib12) 2005; 152 Aubach (10.1016/j.electacta.2007.07.074_bib6) 2000; 147 Lei (10.1016/j.electacta.2007.07.074_bib18) 2005; 152 10.1016/j.electacta.2007.07.074_bib22 10.1016/j.electacta.2007.07.074_bib25 Edstrom (10.1016/j.electacta.2007.07.074_bib11) 2004; 50 Aurbach (10.1016/j.electacta.2007.07.074_bib17) 1998; 145
References_xml	– ident: 10.1016/j.electacta.2007.07.074_bib1_2 – volume: 147 start-page: 1322 year: 2000 ident: 10.1016/j.electacta.2007.07.074_bib6 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1393357 contributor: fullname: Aubach – volume: 124 start-page: 124 year: 2003 ident: 10.1016/j.electacta.2007.07.074_bib15 publication-title: J. Power Sources doi: 10.1016/S0378-7753(03)00593-7 contributor: fullname: Araki – volume: 146 start-page: 824 year: 1999 ident: 10.1016/j.electacta.2007.07.074_bib14 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1391688 contributor: fullname: Bar-Tow – volume: 193 start-page: L29 year: 1988 ident: 10.1016/j.electacta.2007.07.074_bib19 publication-title: Surf. Sci. Lett. doi: 10.1016/0039-6028(88)90314-7 contributor: fullname: Samant – volume: 145 start-page: 3024 year: 1998 ident: 10.1016/j.electacta.2007.07.074_bib17 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1838758 contributor: fullname: Aurbach – volume: 26 start-page: 545 year: 1989 ident: 10.1016/j.electacta.2007.07.074_bib1_4 publication-title: J. Power Sources doi: 10.1016/0378-7753(89)80176-4 contributor: fullname: Mohri – volume: 50 start-page: 397 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib11 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2004.03.049 contributor: fullname: Edstrom – volume: 15 start-page: 783 year: 1980 ident: 10.1016/j.electacta.2007.07.074_bib1_1 publication-title: Mater. Res. Bull. doi: 10.1016/0025-5408(80)90012-4 contributor: fullname: Mizushima – volume: 15 start-page: 3334 year: 1999 ident: 10.1016/j.electacta.2007.07.074_bib13 publication-title: Langmuir doi: 10.1021/la981048h contributor: fullname: Schechter – volume: 81/82 start-page: 434 year: 1999 ident: 10.1016/j.electacta.2007.07.074_bib28 publication-title: J. Power Sources doi: 10.1016/S0378-7753(99)00247-5 contributor: fullname: Moshtev – volume: 7 start-page: A190 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib29 publication-title: Electrochem. Solid-State Lett. doi: 10.1149/1.1738471 contributor: fullname: Liu – volume: 7 start-page: A140 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib16 publication-title: Solid State Lett. doi: 10.1149/1.1697905 contributor: fullname: Menetrier – volume: 97/98 start-page: 684 year: 2001 ident: 10.1016/j.electacta.2007.07.074_bib8 publication-title: J. Power Sources doi: 10.1016/S0378-7753(01)00701-7 contributor: fullname: Amine – volume: 95 start-page: 359 year: 1954 ident: 10.1016/j.electacta.2007.07.074_bib23 publication-title: Phys. Rev. doi: 10.1103/PhysRev.95.359 contributor: fullname: Parratt – volume: 96 start-page: 321 year: 2001 ident: 10.1016/j.electacta.2007.07.074_bib9 publication-title: J. Power Sources doi: 10.1016/S0378-7753(00)00666-2 contributor: fullname: Chen – volume: 419 start-page: 77 year: 1996 ident: 10.1016/j.electacta.2007.07.074_bib7 publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(96)04862-0 contributor: fullname: Kanamura – volume: 137 start-page: 2209 year: 1990 ident: 10.1016/j.electacta.2007.07.074_bib5 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2086855 contributor: fullname: Fong – volume: 36 start-page: 209 year: 1991 ident: 10.1016/j.electacta.2007.07.074_bib21 publication-title: Electrochim. Acta doi: 10.1016/0013-4686(91)85203-J contributor: fullname: Nagy – ident: 10.1016/j.electacta.2007.07.074_bib25 doi: 10.1016/j.jpowsour.2007.06.233 – volume: 26 start-page: 535 year: 1989 ident: 10.1016/j.electacta.2007.07.074_bib1_3 publication-title: J. Power Sources doi: 10.1016/0378-7753(89)80175-2 contributor: fullname: Kanno – ident: 10.1016/j.electacta.2007.07.074_bib22 – volume: 152 start-page: A774 year: 2005 ident: 10.1016/j.electacta.2007.07.074_bib18 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1867652 contributor: fullname: Lei – volume: 127 start-page: 72 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib3 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2003.09.009 contributor: fullname: Ogumi – volume: 65 start-page: 1466 year: 1990 ident: 10.1016/j.electacta.2007.07.074_bib20 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.65.1466 contributor: fullname: Ocko – volume: 151 start-page: A1162 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib30 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1763771 contributor: fullname: Song – year: 1997 ident: 10.1016/j.electacta.2007.07.074_bib24 contributor: fullname: Braun – volume: 4 start-page: 620 year: 2002 ident: 10.1016/j.electacta.2007.07.074_bib31 publication-title: Electrochem. Commun. doi: 10.1016/S1388-2481(02)00388-0 contributor: fullname: Abraham – volume: 126 start-page: 2047 year: 1979 ident: 10.1016/j.electacta.2007.07.074_bib4 publication-title: J. Electrochem. Soc. doi: 10.1149/1.2128859 contributor: fullname: Peled – volume: 81/82 start-page: 558 year: 1999 ident: 10.1016/j.electacta.2007.07.074_bib27 publication-title: J. Power Sources doi: 10.1016/S0378-7753(99)00216-5 contributor: fullname: Matsumoto – volume: 151 start-page: A1120 year: 2004 ident: 10.1016/j.electacta.2007.07.074_bib2 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1763141 contributor: fullname: Abe – volume: 149 start-page: A1358 year: 2002 ident: 10.1016/j.electacta.2007.07.074_bib10 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1505636 contributor: fullname: Andersson – volume: 152 start-page: A1041 year: 2005 ident: 10.1016/j.electacta.2007.07.074_bib12 publication-title: J. Electrochem. Soc. doi: 10.1149/1.1896325 contributor: fullname: Wu – volume: 168 start-page: 493 year: 2007 ident: 10.1016/j.electacta.2007.07.074_bib26 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2007.03.034 contributor: fullname: Hirayama
SSID	ssj0007670
Score	2.1456866
Snippet	An in situ experimental technique was developed for detecting structure changes at the electrode/electrolyte interface of lithium cell using synchrotron X-ray...
SourceID	proquest crossref pascalfrancis
SourceType	Aggregation Database Index Database
StartPage	871
SubjectTerms	Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology
Title	Characterization of electrode/electrolyte interface using in situ X-ray reflectometry and LiNi0.8Co0.2O2 epitaxial film electrode synthesized by pulsed laser deposition method
URI	https://search.proquest.com/docview/30938361
Volume	53
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1fb9MwELfKeACEEAwQ5c_wA29VSuL8cfuIKqYKsfGySX2LbNcW2damahKJ9oGvxEfiq3COHSfZJsGQoihNlHPS-9l355x_h9AHulwmSaSUB7aPe5GCOIWB3fYoD2LGAxErpgPFk9Nkfh59WcSLweB3J2upKvlY7G9dV_I_WoVzoFe9SvYOmnVC4QQcg35hDxqG_T_peObYlvfO87N1bTSb7rE9vtqVsuaF2CoG3bgq7DqWIiur0cLbst0I7GQ9f7-S5dYwMn3NTjN_PJnl_ph8IyOpq4v80NPrKrtata1oygPwIYtsb1zZTQW2djkCn7wuPd7khNlK1b3vAEaE-J5pxgJN6uEsxDyDZ2IrZhYTFQy8XDcTxC4ZoCs3mSD7ale11_RtmaURlmVR7ZzAk7xZUJ8V1aXsTXXQTtqIHb6D0IsSy51th2_DNWxhSjpj8cTUdmnMuqkMc8NimMmLi3H9v-lXtbSWeotaI9kkBlyznS6jsUmWu0idIF3hk6b1Ft1D9wmMhHoIHv9sc5BoQv2mxIZ-r14C4q1P1HOfHm9YAT1ZmRIsN7yJ2kU6e4qe2NgGfzJAfYYGcn2IHsyakoKH6FGH_fI5-nUdvjhX2AHrYwe82IEX1-CF31iDF9fgxT3wYgAv7oMXO_BiDd62DdwBL-Y7bMCLa_DiFrzYgPcFOj_-fDabe7Z-iCcgqC49zgiVKkgm01gwCX47D_0piyVE3TKiUkcSyhchVQL8dE44IYEQSi2pDuOFCMKX6GCdr-UrhGOi4ELI4oDTiPh0qihV8WRKgqUA8dEQ-Y1a0o2hiUn_AokhOuqpr70PpEbgRQ_R-0afKehJf8hja5lXRaqzFyZhEry-e6tv0MO2Z71FB-W2ku_ArS75UQ3NP5Yg2cU
link.rule.ids	315,783,787,27936,27937
linkProvider	Elsevier
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Characterization+of+electrode%2Felectrolyte+interface+using+in+situ+X-ray+reflectometry+and+LiNi0.8Co0.2O2+epitaxial+film+electrode+synthesized+by+pulsed+laser+deposition+method&rft.jtitle=Electrochimica+acta&rft.au=Hirayama%2C+Masaaki&rft.au=Sakamoto%2C+Kazuyuki&rft.au=Hiraide%2C+Tetsuya&rft.au=Mori%2C+Daisuke&rft.date=2007-12-01&rft.issn=0013-4686&rft.volume=53&rft.issue=2&rft.spage=871&rft.epage=881&rft_id=info:doi/10.1016%2Fj.electacta.2007.07.074&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_electacta_2007_07_074
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-4686&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-4686&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-4686&client=summon