Fe-aminoclay-entrapping electrospun polyacrylonitrile nanofibers (FeAC-PAN NFs) for environmental engineering applications
Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto a...
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| Published in | The Korean journal of chemical engineering Vol. 32; no. 9; pp. 1727 - 1732 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.09.2015
한국화학공학회 |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0256-1115 1975-7220 |
| DOI | 10.1007/s11814-015-0136-5 |
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| Abstract | Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto as-prepared PAN NFs. Taking into consideration both the Fe
3+
source in FeAC and the improved surface hydrophilicity, the feasibility of Fentonlike reaction for decolorization of cationic model dye methylene blue (MB) under 6 hrs UV-light irradiation was established. In the case where FeAC-PAN NFs were enhanced by hydrogen peroxide (H
2
O
2
) injection, the apparent kinetic reaction rates were increased relative to those for the PAN NFs. Thus, our flexible FeAC-PAN NF mats can be effectively utilized in water/waste treatment and other environmental engineering applications. |
|---|---|
| AbstractList | Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto as-prepared PAN NFs. Taking into consideration both the Fe
3+
source in FeAC and the improved surface hydrophilicity, the feasibility of Fentonlike reaction for decolorization of cationic model dye methylene blue (MB) under 6 hrs UV-light irradiation was established. In the case where FeAC-PAN NFs were enhanced by hydrogen peroxide (H
2
O
2
) injection, the apparent kinetic reaction rates were increased relative to those for the PAN NFs. Thus, our flexible FeAC-PAN NF mats can be effectively utilized in water/waste treatment and other environmental engineering applications. Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto as-prepared PAN NFs. Taking into consideration both the Fe3+ source in FeAC and the improved surface hydrophilicity, the feasibility of Fentonlike reaction for decolorization of cationic model dye methylene blue (MB) under 6 hrs UV-light irradiation was established. In the case where FeAC-PAN NFs were enhanced by hydrogen peroxide (H2O2) injection, the apparent kinetic reaction rates were increased relative to those for the PAN NFs. Thus, our flexible FeAC-PAN NF mats can be effectively utilized in water/waste treatment and other environmental engineering applications. KCI Citation Count: 5 |
| Author | Kim, Moon Il Song, Dongsu Lee, Hyun Uk Park, Seung Bin Lee, Jae-Young Choi, Saehae Lee, Young-Chul Lee, Go-Woon |
| Author_xml | – sequence: 1 givenname: Jae-Young surname: Lee fullname: Lee, Jae-Young organization: Korea Railroad Research Institute (KRRI) – sequence: 2 givenname: Saehae surname: Choi fullname: Choi, Saehae organization: Sustainable Bioresource Research Center, Korea Research Institute of Bioscience & Biotechnology (KRIBB) – sequence: 3 givenname: Dongsu surname: Song fullname: Song, Dongsu organization: Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST) – sequence: 4 givenname: Seung Bin surname: Park fullname: Park, Seung Bin organization: Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST) – sequence: 5 givenname: Moon Il surname: Kim fullname: Kim, Moon Il organization: Department of BioNano Technology, Gachon University – sequence: 6 givenname: Go-Woon surname: Lee fullname: Lee, Go-Woon organization: Quality Management Team, Korea Institute of Energy Research (KIER) – sequence: 7 givenname: Hyun Uk surname: Lee fullname: Lee, Hyun Uk email: leeho@kbsi.re.kr organization: Advanced Nano-Surface Research Group, Korea Basic Science Institute (KBSI) – sequence: 8 givenname: Young-Chul surname: Lee fullname: Lee, Young-Chul email: dreamdbs@gachon.ac.kr organization: Department of BioNano Technology, Gachon University |
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| CitedBy_id | crossref_primary_10_1016_j_cep_2019_107785 crossref_primary_10_1016_j_crci_2018_11_012 crossref_primary_10_1016_j_cej_2024_158717 crossref_primary_10_1016_j_chemosphere_2024_143480 crossref_primary_10_1007_s13204_017_0595_6 crossref_primary_10_1016_j_cej_2022_140309 |
| Cites_doi | 10.1016/j.progpolymsci.2011.07.001 10.1016/j.apcatb.2013.06.030 10.1039/c3ta01443f 10.1007/s11814-014-0142-z 10.1080/15583720802022182 10.1016/j.cej.2014.09.116 10.1016/j.jhazmat.2011.08.077 10.1021/cm970274u 10.1038/srep04594 10.1089/ten.2006.12.1197 10.1039/c0jm00432d 10.1016/j.polymdegradstab.2011.04.012 10.1016/j.ijpharm.2009.03.022 10.1016/j.jhazmat.2011.03.093 10.1002/app.1969.070130815 10.1021/am505751z 10.1016/j.jcis.2013.03.072 10.1016/j.jcis.2011.09.088 10.1021/am900590j 10.1002/app.32019 10.1021/nn403003b 10.1002/mame.201200290 10.1016/j.apcatb.2013.05.066 10.1039/c3cs60426h 10.1007/s10853-013-7705-y 10.1038/srep01292 10.1016/j.apsusc.2008.03.049 |
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| Copyright | Korean Institute of Chemical Engineers, Seoul, Korea 2015 |
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| Keywords | Fenton-like Reaction Polyacrylonitrile Nanofibers (PAN NFs) Fe-aminoclay (FeAC) Water Treatment One-pot Synthesis |
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| Snippet | Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of... |
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| SubjectTerms | Biotechnology Catalysis Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Materials Science Rapid Communication 화학공학 |
| Title | Fe-aminoclay-entrapping electrospun polyacrylonitrile nanofibers (FeAC-PAN NFs) for environmental engineering applications |
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