PEM fuel cell electrocatalysts based on transition metal macrocyclic compounds

• Published in: Coordination chemistry reviews Vol. 315; pp. 153 - 177
• Main Authors: Liu, Yuyu, Yue, Xiuping, Li, Kaixi, Qiao, Jinli, Wilkinson, David P., Zhang, Jiujun
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.05.2016; Elsiever
• Subjects: Electrocatalysts; Oxygen reduction reaction; Polymer electrolyte membrane fuel cell; Transition metal macrocycle complex; PP; MCV; CoPP(s); DMSO; XRD; MPP; PBE; DFT; Pc; EDX; TMPP; TPFC; PEMFC(s); OMC; Electrocatalysts; APFP; Py; LSV; DCM; DWCNT; Transition metal macrocycle complex; SEM; TBAP; RGO; SWCNT(s); MWCNT(s); CNT; PANI; NHE; DPX; ORR; RDE; TPP; XPS; FePP(s); RRDE; GCE; GO; TFMSA; TMPyP; Polymer electrolyte membrane fuel cell; CV; ERGO; TAA; TMM; TSPc; Oxygen reduction reaction; TMPc(s); TM

•The paper provides an overview of transition metal macrocyclic (TMM) complex-based electrocatalysts used in ORRs in PEMFCs.•Performances of TMM catalysts, including both ORR activity rates and stabilities, are discussed.•The effects of different types and natures of metals, macrocyclic ligands, and...