Formation and structural transition of molecular self-assembly on solid surface investigated by scanning tunneling microscopy

The spontaneous formation of ordered self-assembly on solid supports is not only an intriguing subject for fundamental surface science study, but also closely related to many emerging technologically important applications, especially in the field of nanotechnology. With the help of scanning tunneli...

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Published inMaterials science & engineering. R, Reports : a review journal Vol. 70; no. 3; pp. 169 - 187
Main Authors Wang, Dong, Wan, Li-Jun, Bai, Chun-Li
Format Journal Article Conference Proceeding
LanguageEnglish
Published Amsterdam Elsevier B.V 22.11.2010
Elsevier
Subjects
Architecture
Assembly
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Materials science
Methods of nanofabrication
Molecular structure
Nanotechnology
Physics
Scanning tunneling microscopy
Self assembly
Solid surfaces
Specific phase transitions
Spontaneous
Structural transitions in nanoscale materials
Supramolecular and biochemical assembly
Surface and interface
Scanning tunneling microscopy
Self-assembly
Surface and interface
Weak interactions
Molecular structure
Phase transformations
Self-assembled layers
Intermolecular interaction
Interfaces
Reviews
Molecular assembly
Supramolecular structure
Nanotechnology
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Abstract The spontaneous formation of ordered self-assembly on solid supports is not only an intriguing subject for fundamental surface science study, but also closely related to many emerging technologically important applications, especially in the field of nanotechnology. With the help of scanning tunneling microscopy (STM) at sub-molecular resolution, the detailed structural information within the self-assembled monolayers can be obtained, which allows us to have an insight into how the interplay between the intermolecular weak interactions and the substrate–molecule interactions governs the formation of molecular self-assembly. In this review, the structural transition of self-assembly in response to the subtle differences in the molecular structures and/or the environment change will be presented. The fundamental understanding about the driving force controlling the assembly process promotes the development of various means to tune the structural transition of supramolecular assembly on solid surfaces and fabricate the sophisticated architectures. Finally, some future directions in the field are outlined.
AbstractList The spontaneous formation of ordered self-assembly on solid supports is not only an intriguing subject for fundamental surface science study, but also closely related to many emerging technologically important applications, especially in the field of nanotechnology. With the help of scanning tunneling microscopy (STM) at sub-molecular resolution, the detailed structural information within the self-assembled monolayers can be obtained, which allows us to have an insight into how the interplay between the intermolecular weak interactions and the substrate-molecule interactions governs the formation of molecular self-assembly. In this review, the structural transition of self-assembly in response to the subtle differences in the molecular structures and/or the environment change will be presented. The fundamental understanding about the driving force controlling the assembly process promotes the development of various means to tune the structural transition of supramolecular assembly on solid surfaces and fabricate the sophisticated architectures. Finally, some future directions in the field are outlined.
Author Wang, Dong
Wan, Li-Jun
Bai, Chun-Li
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  email: wanlijun@iccas.ac.cn
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  givenname: Chun-Li
  surname: Bai
  fullname: Bai, Chun-Li
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Issue 3
Keywords Scanning tunneling microscopy
Self-assembly
Surface and interface
Weak interactions
Molecular structure
Phase transformations
Self-assembled layers
Intermolecular interaction
Interfaces
Reviews
Molecular assembly
Supramolecular structure
Nanotechnology
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Snippet The spontaneous formation of ordered self-assembly on solid supports is not only an intriguing subject for fundamental surface science study, but also closely...
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SubjectTerms Architecture
Assembly
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Materials science
Methods of nanofabrication
Molecular structure
Nanotechnology
Physics
Scanning tunneling microscopy
Self assembly
Solid surfaces
Specific phase transitions
Spontaneous
Structural transitions in nanoscale materials
Supramolecular and biochemical assembly
Surface and interface
Title Formation and structural transition of molecular self-assembly on solid surface investigated by scanning tunneling microscopy
URI https://dx.doi.org/10.1016/j.mser.2010.06.016
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