A trichromatic MOF composite for multidimensional ratiometric luminescent sensing
Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easil...
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| Published in | Chemical science (Cambridge) Vol. 9; no. 11; pp. 2918 - 2926 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
21.03.2018
|
| Subjects | |
| Online Access | Get full text |
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| Abstract | Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite (
W2
) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF
via
ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in
W2
, while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes.
A trichromatic MOF composite utilizes its MOF matrix and two encapsulated cations collectively to achieve unprecedented multi-dimensional ratiometric luminescent sensing with high selectivity and sensitivity. |
|---|---|
| AbstractList | Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite (W2) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2, while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes.Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite (W2) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2, while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite ( W2 ) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2 , while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite ( ) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in , while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite ( W2 ) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2 , while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. A trichromatic MOF composite utilizes its MOF matrix and two encapsulated cations collectively to achieve unprecedented multi-dimensional ratiometric luminescent sensing with high selectivity and sensitivity. Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite (W2) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2, while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. A trichromatic MOF composite utilizes its MOF matrix and two encapsulated cations collectively to achieve unprecedented multi-dimensional ratiometric luminescent sensing with high selectivity and sensitivity. Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single or dual emissions responsive to analyte molecules, demonstrate limited sensitivity and selectivity because the single emissions can be easily affected by many non-analyte factors, while the dual emissions can only offer single-ratiometric luminescent sensing. Here we report a white-light-emitting trichromatic MOF composite ( W2 ) as the first multidimensional ratiometric luminescent probe. It is facilely synthesized by simultaneously incorporating red- and green-emitting iridium and ruthenium complex cations as encapsulated luminescent modules (ELMs) into a porous blue-emitting MOF via ion exchange. Specific volatile organic solvents (VOSs) can cause VOS-dependent changes to the MOF-to-ELM energy transfer efficiencies in W2 , while nitroaromatic (NAC) vapors intriguingly and unprecedentedly quench the three emissions at different rates, both of which enable visible luminescent sensing. Each VOS can be correlated to a unique combination of the two MOF-to-ELM ratios of emission-peak heights, enabling a two-dimensional (2D) code recognition. Furthermore, the time-dependent evolution of the two ratios upon exposure to selective NAC vapors can be mapped out, achieving the first 3D code recognition. Both the synthetic and sensing strategies can be further implemented to develop low-cost and effective luminescent probes. |
| Author | Duan, Chun-Ying Zhao, He Zhou, Huajun Sun, Ying-Ji Ni, Jun Zhang, Jian-Jun Liu, Shu-Qin Li, Yan-Qin |
| AuthorAffiliation | State Key Laboratory of Structural Chemistry Chinese Academy of Sciences University of Arkansas High Density Electronics Center Dalian University of Technology State Key Laboratory of Fine Chemicals Fujian Institute of Research on the Structure of Matter Chemistry College |
| AuthorAffiliation_xml | – sequence: 0 name: State Key Laboratory of Structural Chemistry – sequence: 0 name: State Key Laboratory of Fine Chemicals – sequence: 0 name: Chinese Academy of Sciences – sequence: 0 name: University of Arkansas – sequence: 0 name: Chemistry College – sequence: 0 name: High Density Electronics Center – sequence: 0 name: Fujian Institute of Research on the Structure of Matter – sequence: 0 name: Dalian University of Technology – name: d State Key Laboratory of Structural Chemistry , Fujian Institute of Research on the Structure of Matter , Chinese Academy of Sciences , Fuzhou , 350002 , China – name: c State Key Laboratory of Fine Chemicals , Dalian University of Technology , Dalian , 116024 , China . Email: cyduan@dlut.edu.cn – name: a Chemistry College , Dalian University of Technology , Dalian 116024 , China . Email: zhangjj@dlut.edu.cn – name: b High Density Electronics Center , University of Arkansas , Fayetteville , Arkansas 72701 , USA . Email: hxz001@uark.edu |
| Author_xml | – sequence: 1 givenname: He surname: Zhao fullname: Zhao, He – sequence: 2 givenname: Jun surname: Ni fullname: Ni, Jun – sequence: 3 givenname: Jian-Jun surname: Zhang fullname: Zhang, Jian-Jun – sequence: 4 givenname: Shu-Qin surname: Liu fullname: Liu, Shu-Qin – sequence: 5 givenname: Ying-Ji surname: Sun fullname: Sun, Ying-Ji – sequence: 6 givenname: Huajun surname: Zhou fullname: Zhou, Huajun – sequence: 7 givenname: Yan-Qin surname: Li fullname: Li, Yan-Qin – sequence: 8 givenname: Chun-Ying surname: Duan fullname: Duan, Chun-Ying |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29732075$$D View this record in MEDLINE/PubMed |
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| Snippet | Low-cost, high-performance luminescent probes with wide application potential have been actively pursued. Conventional luminescent probes, which rely on single... A trichromatic MOF composite utilizes its MOF matrix and two encapsulated cations collectively to achieve unprecedented multi-dimensional ratiometric... |
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| SubjectTerms | Chemistry Detection Iridium Light emission Low cost Metal-organic frameworks Recognition Ruthenium Sensitivity analysis White light |
| Title | A trichromatic MOF composite for multidimensional ratiometric luminescent sensing |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/29732075 https://www.proquest.com/docview/2014026490 https://www.proquest.com/docview/2035707256 https://pubmed.ncbi.nlm.nih.gov/PMC5914538 |
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