Two 3D Coordination Frameworks Based on Benzobisimidazole Linkers Generated under Similar Conditions: Synthesis, Structures and Thermal Properties

Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different frame...

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Published inEuropean journal of inorganic chemistry Vol. 2014; no. 31; pp. 5362 - 5369
Main Authors Biswas, Shyam, Liu, Ying-Ya, Tonigold, Markus, Weil, Matthias, Volkmer, Dirk
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.11.2014
WILEY‐VCH Verlag
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ISSN1434-1948
1099-0682
DOI10.1002/ejic.201402552

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Abstract Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four‐connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra‐ and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively. The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole‐based CoII and ZnII coordination polymers are presented.
AbstractList Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H sub(2)-BBIM)(SO sub(4))].DMSO (1) (H sub(2)-BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H sub(2)-BBIM)(SO sub(4))(DMS O) sub(0.5)] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB sub(4) topological nets, respectively, in which the four-connected tetrahedral {MN sub(2)O sub(2)} (M super(II) = Zn, Co) coordination units are located at the vertices and the edges are occupied by H sub(2)-BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra- and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X-ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable-temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 degree C, respectively. The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole-based Co super(II) and Zn super(II) coordination polymers are presented.
Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four‐connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra‐ and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively. The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole‐based CoII and ZnII coordination polymers are presented.
Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H 2 ‐BBIM)(SO 4 )] · DMSO ( 1 ) (H 2 ‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H 2 ‐BBIM)(SO 4 )(DMSO) 0.5 ] ( 2 ) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB 4 topological nets, respectively, in which the four‐connected tetrahedral {MN 2 O 2 } (M II = Zn, Co) coordination units are located at the vertices and the edges are occupied by H 2 ‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1 , whereas both tetra‐ and pentacoordination is present in 2 . The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively.
Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H2-BBIM)(SO4)]·DMSO (1) (H2-BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2-BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four-connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2-BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra- and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X-ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable-temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively.
Author Liu, Ying-Ya
Tonigold, Markus
Volkmer, Dirk
Biswas, Shyam
Weil, Matthias
Author_xml – sequence: 1
  givenname: Shyam
  surname: Biswas
  fullname: Biswas, Shyam
  email: sbiswas@iitg.ernet.in
  organization: Indian Institute of Technology Guwahati, Department of Chemistry, Guwahati, 781039 Assam, India, http://www.iitg.ernet.in/sbiswas/
– sequence: 2
  givenname: Ying-Ya
  surname: Liu
  fullname: Liu, Ying-Ya
  organization: State Key Laboratory of Fine Chemicals, Dalian University of Technology, 116024, Dalian, China
– sequence: 3
  givenname: Markus
  surname: Tonigold
  fullname: Tonigold, Markus
  organization: Current address: Clariant Produkte (Deutschland) GmbH, Waldheimer Strasse 13, 83052 Bruckmuehl, Germany
– sequence: 4
  givenname: Matthias
  surname: Weil
  fullname: Weil, Matthias
  organization: Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, 1060 Vienna, Austria
– sequence: 5
  givenname: Dirk
  surname: Volkmer
  fullname: Volkmer, Dirk
  organization: Institute of Physics, Chair of Solid State Science, Augsburg University, Universitätsstrasse 1, 86135 Augsburg, Germany
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CitedBy_id crossref_primary_10_1021_acs_inorgchem_9b03709
crossref_primary_10_1002_ejic_201701015
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2002; 58
2014; 413
2001; 101
1994; 23
2008; 37
1974
1999; 283
2009; 48
2010; 20
2001
2002; 41
2004; 38
2002; 102
1999; 183
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2008; 319
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1978; 100
2003; 48
2007; 6
1999; 55
2008; 20
2005; 38
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2010; 9
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2007; 19
2002; 36
2007; 129
2009; 65
2013; 49
2005; 631
2011; 40
2008; 14
2009
2007
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2006
1995
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1975; 31
2013; 341
2004; 306
2007; 13
1998; 37
1973; 137
2012; 112
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2006; 45
1999; 38
1988; 27
2005; 127
2008; 47
1988; 110
2003; 423
2008; 453
2001; 34
2003; 300
2009; 38
2008; 130
2007; 46
1968
2006; 103
1966
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Snippet Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds...
Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H 2...
Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds...
Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H...
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SubjectTerms Cobalt
Crystal structure
Diamonds
Dimethyl sulfoxide
Graph theory
Infrared spectroscopy
Ligands
N li­gands
Polymers
Synthesis
Thermal properties
X rays
Zeolites
Zinc
Title Two 3D Coordination Frameworks Based on Benzobisimidazole Linkers Generated under Similar Conditions: Synthesis, Structures and Thermal Properties
URI https://api.istex.fr/ark:/67375/WNG-4MGW6PVS-6/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fejic.201402552
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Volume 2014
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