Two 3D Coordination Frameworks Based on Benzobisimidazole Linkers Generated under Similar Conditions: Synthesis, Structures and Thermal Properties
Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different frame...
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Published in | European journal of inorganic chemistry Vol. 2014; no. 31; pp. 5362 - 5369 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Weinheim
WILEY-VCH Verlag
01.11.2014
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
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ISSN | 1434-1948 1099-0682 |
DOI | 10.1002/ejic.201402552 |
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Abstract | Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four‐connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra‐ and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively.
The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole‐based CoII and ZnII coordination polymers are presented. |
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AbstractList | Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H sub(2)-BBIM)(SO sub(4))].DMSO (1) (H sub(2)-BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H sub(2)-BBIM)(SO sub(4))(DMS O) sub(0.5)] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB sub(4) topological nets, respectively, in which the four-connected tetrahedral {MN sub(2)O sub(2)} (M super(II) = Zn, Co) coordination units are located at the vertices and the edges are occupied by H sub(2)-BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra- and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X-ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable-temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 degree C, respectively. The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole-based Co super(II) and Zn super(II) coordination polymers are presented. Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H2‐BBIM)(SO4)]·DMSO (1) (H2‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2‐BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four‐connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra‐ and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively. The syntheses, crystal structures, and thermal and spectroscopic properties of two benzobisimidazole‐based CoII and ZnII coordination polymers are presented. Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H 2 ‐BBIM)(SO 4 )] · DMSO ( 1 ) (H 2 ‐BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H 2 ‐BBIM)(SO 4 )(DMSO) 0.5 ] ( 2 ) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB 4 topological nets, respectively, in which the four‐connected tetrahedral {MN 2 O 2 } (M II = Zn, Co) coordination units are located at the vertices and the edges are occupied by H 2 ‐BBIM ligands and sulfate anions. Only tetracoordination is observed in 1 , whereas both tetra‐ and pentacoordination is present in 2 . The phase purity of the compounds was ascertained by X‐ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable‐temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively. Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H2-BBIM)(SO4)]·DMSO (1) (H2-BBIM = benzobisimidazole; DMSO = dimethyl sulfoxide) and [Co(H2-BBIM)(SO4)(DMSO)0.5] (2) possess two different framework structures, although both of them have been synthesized under similar conditions. Compounds 1 and 2 exhibit cubic diamondoid and tetragonal CrB4 topological nets, respectively, in which the four-connected tetrahedral {MN2O2} (MII = Zn, Co) coordination units are located at the vertices and the edges are occupied by H2-BBIM ligands and sulfate anions. Only tetracoordination is observed in 1, whereas both tetra- and pentacoordination is present in 2. The phase purity of the compounds was ascertained by X-ray powder diffraction (XRPD) analysis, infrared spectroscopy, and elemental analysis. Variable-temperature XRPD analysis indicated that 1 and 2 are stable up to 90 and 140 °C, respectively. |
Author | Liu, Ying-Ya Tonigold, Markus Volkmer, Dirk Biswas, Shyam Weil, Matthias |
Author_xml | – sequence: 1 givenname: Shyam surname: Biswas fullname: Biswas, Shyam email: sbiswas@iitg.ernet.in organization: Indian Institute of Technology Guwahati, Department of Chemistry, Guwahati, 781039 Assam, India, http://www.iitg.ernet.in/sbiswas/ – sequence: 2 givenname: Ying-Ya surname: Liu fullname: Liu, Ying-Ya organization: State Key Laboratory of Fine Chemicals, Dalian University of Technology, 116024, Dalian, China – sequence: 3 givenname: Markus surname: Tonigold fullname: Tonigold, Markus organization: Current address: Clariant Produkte (Deutschland) GmbH, Waldheimer Strasse 13, 83052 Bruckmuehl, Germany – sequence: 4 givenname: Matthias surname: Weil fullname: Weil, Matthias organization: Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, 1060 Vienna, Austria – sequence: 5 givenname: Dirk surname: Volkmer fullname: Volkmer, Dirk organization: Institute of Physics, Chair of Solid State Science, Augsburg University, Universitätsstrasse 1, 86135 Augsburg, Germany |
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CitedBy_id | crossref_primary_10_1021_acs_inorgchem_9b03709 crossref_primary_10_1002_ejic_201701015 |
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Snippet | Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds... Herein, we present two benzobisimidazole‐based 3D open coordination framework structures. Single‐crystal X‐ray analyses reveal that the title compounds [Zn(H 2... Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds... Herein, we present two benzobisimidazole-based 3D open coordination framework structures. Single-crystal X-ray analyses reveal that the title compounds [Zn(H... |
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SubjectTerms | Cobalt Crystal structure Diamonds Dimethyl sulfoxide Graph theory Infrared spectroscopy Ligands N ligands Polymers Synthesis Thermal properties X rays Zeolites Zinc |
Title | Two 3D Coordination Frameworks Based on Benzobisimidazole Linkers Generated under Similar Conditions: Synthesis, Structures and Thermal Properties |
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