A review of polymeric composite membranes for gas separation and energy production

[Display omitted] Membrane-based technologies for gas and vapor separations have been industrialized for more than three decades due to (1) the invention of asymmetric composite membranes and (2) their superior energy-efficient and environment-friendly characteristics. However, industries demand mor...

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Published inProgress in polymer science Vol. 97; p. 101141
Main Authors Liang, Can Zeng, Chung, Tai-Shung, Lai, Juin-Yih
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.10.2019
Subjects
Aging/plasticization
Composite membrane
Gas transport
Gas/vapor separation
Phase inversion
Thin film composite
Phase inversion
PAS
PVP
HT
GPU
PPO
STP
TFC
PEBA
Gas transport
Gas/vapor separation
Thin film composite
SI
FFV
NIPS
CA
VIPS
TIPS
UV
PSF
MOF
PTFE
IP
Composite membrane
PTMSP
CN
PVDF
ATRP
CVD
PA
PEG
Aging/plasticization
PE
PEI
PIM
ZIF
ALD
PI
SEM
RM
PAN
PDMS
PES
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Abstract [Display omitted] Membrane-based technologies for gas and vapor separations have been industrialized for more than three decades due to (1) the invention of asymmetric composite membranes and (2) their superior energy-efficient and environment-friendly characteristics. However, industries demand more robust and productive composite membranes to meet the harsh conditions in new or emerging applications. The fabrication of thin film composite (TFC) membranes consisting of an ultrathin selective layer and a strong porous substrate will likely play the pivotal role to meet the future demands. In this review, we revisit the basis of composite membranes for gas and vapor separations with the aim to produce next-generation high-performance composite membranes. This review focuses on (1) the fundamentals of gas transport theories through composite membranes, (2) fabrication techniques, and (3) performance characteristics and stability of composite membranes. We examine, elucidate and explore the state-of-the-art techniques for the fabrication of composite membranes. Based on the resistance model, we derive a new generalized equation for gas permeance, which is simple, informative and applicable to composite membranes. We also outline the directions, challenges and key areas for future R&D in the field of gas/vapor-separation composite membranes.
AbstractList [Display omitted] Membrane-based technologies for gas and vapor separations have been industrialized for more than three decades due to (1) the invention of asymmetric composite membranes and (2) their superior energy-efficient and environment-friendly characteristics. However, industries demand more robust and productive composite membranes to meet the harsh conditions in new or emerging applications. The fabrication of thin film composite (TFC) membranes consisting of an ultrathin selective layer and a strong porous substrate will likely play the pivotal role to meet the future demands. In this review, we revisit the basis of composite membranes for gas and vapor separations with the aim to produce next-generation high-performance composite membranes. This review focuses on (1) the fundamentals of gas transport theories through composite membranes, (2) fabrication techniques, and (3) performance characteristics and stability of composite membranes. We examine, elucidate and explore the state-of-the-art techniques for the fabrication of composite membranes. Based on the resistance model, we derive a new generalized equation for gas permeance, which is simple, informative and applicable to composite membranes. We also outline the directions, challenges and key areas for future R&D in the field of gas/vapor-separation composite membranes.
ArticleNumber 101141
Author Liang, Can Zeng
Chung, Tai-Shung
Lai, Juin-Yih
Author_xml – sequence: 1
  givenname: Can Zeng
  surname: Liang
  fullname: Liang, Can Zeng
  organization: Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore
– sequence: 2
  givenname: Tai-Shung
  surname: Chung
  fullname: Chung, Tai-Shung
  email: chencts@nus.edu.sg
  organization: Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore
– sequence: 3
  givenname: Juin-Yih
  surname: Lai
  fullname: Lai, Juin-Yih
  organization: Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei, Taiwan
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Snippet [Display omitted] Membrane-based technologies for gas and vapor separations have been industrialized for more than three decades due to (1) the invention of...
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SubjectTerms Aging/plasticization
Composite membrane
Gas transport
Gas/vapor separation
Phase inversion
Thin film composite
Title A review of polymeric composite membranes for gas separation and energy production
URI https://dx.doi.org/10.1016/j.progpolymsci.2019.06.001
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