Impedance characteristics and conductivity of CNT/ABS nanocomposites
Electrical impedance characteristics of multi-walled carbon nanotube (MWCNT)/acrylonitril-butadiene-styrene nanocomposite was studied as a function of MWCNT concentration in the frequency range of 100-106 Hz. The nanocomposites were prepared by solution processing and characterized to have good disp...
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| Published in | Journal of physics. D, Applied physics Vol. 46; no. 38; pp. 385305 - 1-8 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Bristol
IOP Publishing
25.09.2013
Institute of Physics |
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| Abstract | Electrical impedance characteristics of multi-walled carbon nanotube (MWCNT)/acrylonitril-butadiene-styrene nanocomposite was studied as a function of MWCNT concentration in the frequency range of 100-106 Hz. The nanocomposites were prepared by solution processing and characterized to have good dispersion of the nanofiller within the polymer matrix as observed by the transmission electron microscopy. In the frequency range of 1-104 Hz, the alternating current (ac) conductivity versus frequency plot of the 0.25 wt% MWCNT nanocomposite exhibited a direct current (dc) plateau indicating that there is a segregated network within this nanocomposite. In the low-frequency region, the bode diagram of the real part of impedance and ac conductivity of the nanocomposites filled with 0.25 wt% up to 4 wt% MWCNT showed a frequency independent plateau followed by an increase obeying the universal dynamic response indicating that conduction in this MWCNT concentration range might be due to tunnelling in addition to the direct contact between filler nanoparticles. For nanocomposites filled with at least 7 wt% MWCNT, the ac conductivity was frequency independent over the entire frequency range (up to 106 Hz) revealing that conduction is due to direct contact between nanoparticles. |
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| AbstractList | Electrical impedance characteristics of multi-walled carbon nanotube (MWCNT)/acrylonitril-butadiene-styrene nanocomposite was studied as a function of MWCNT concentration in the frequency range of 100-106 Hz. The nanocomposites were prepared by solution processing and characterized to have good dispersion of the nanofiller within the polymer matrix as observed by the transmission electron microscopy. In the frequency range of 1-104 Hz, the alternating current (ac) conductivity versus frequency plot of the 0.25 wt% MWCNT nanocomposite exhibited a direct current (dc) plateau indicating that there is a segregated network within this nanocomposite. In the low-frequency region, the bode diagram of the real part of impedance and ac conductivity of the nanocomposites filled with 0.25 wt% up to 4 wt% MWCNT showed a frequency independent plateau followed by an increase obeying the universal dynamic response indicating that conduction in this MWCNT concentration range might be due to tunnelling in addition to the direct contact between filler nanoparticles. For nanocomposites filled with at least 7 wt% MWCNT, the ac conductivity was frequency independent over the entire frequency range (up to 106 Hz) revealing that conduction is due to direct contact between nanoparticles. Electrical impedance characteristics of multi-walled carbon nanotube (MWCNT)/acrylonitril-butadiene-styrene nanocomposite was studied as a function of MWCNT concentration in the frequency range of 10 super(0)-10 super(6) Hz. The nanocomposites were prepared by solution processing and characterized to have good dispersion of the nanofiller within the polymer matrix as observed by the transmission electron microscopy. In the frequency range of 1-10 super(4) Hz, the alternating current (ac) conductivity versus frequency plot of the 0.25 wt% MWCNT nanocomposite exhibited a direct current (dc) plateau indicating that there is a segregated network within this nanocomposite. In the low-frequency region, the bode diagram of the real part of impedance and ac conductivity of the nanocomposites filled with 0.25 wt% up to 4 wt% MWCNT showed a frequency independent plateau followed by an increase obeying the universal dynamic response indicating that conduction in this MWCNT concentration range might be due to tunnelling in addition to the direct contact between filler nanoparticles. For nanocomposites filled with at least 7 wt% MWCNT, the ac conductivity was frequency independent over the entire frequency range (up to 10 super(6) Hz) revealing that conduction is due to direct contact between nanoparticles. |
| Author | Al-Anid, Haya K El-Ghanem, Hasan M Husain, Yazan A Jawad, Saadi Abdul Al-Saleh, Mohammed H |
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| Keywords | Electrical conductivity Material processing Fillers Tunnel effect Carbon nanotubes Dispersions Butadiene Nanoparticles Vibrations Quantity ratio Transmission electron microscopy Nanocomposites Multiwalled nanotube Direct current Polymers Nanostructured materials Electrical characteristic Alternating current |
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| SubjectTerms | Carbon nanotubes Contact Cross-disciplinary physics: materials science; rheology Dielectric properties Direct current Dispersions Exact sciences and technology Frequency ranges Impedance Impedance spectroscopy Materials science Nanocomposites Nanocrystalline materials Nanoparticles Nanopowders Nanoscale materials and structures: fabrication and characterization Nanostructure Nanotubes Other materials Physics Polymer nanocomposite Specific materials |
| Title | Impedance characteristics and conductivity of CNT/ABS nanocomposites |
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