Photo-induced reforming of alcohols with improved hydrogen apparent quantum yield on TiO2 nanotubes loaded with ultra-small Pt nanoparticles
Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetro...
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Published in | International journal of hydrogen energy Vol. 38; no. 34; pp. 14440 - 14450 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Kidlington
Elsevier Ltd
13.11.2013
Elsevier |
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Abstract | Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetron sputtering (DC-MS) technique. The photocatalytic hydrogen rate achieved an optimum value for a loading of about 1 wt% of Pt. Apparent quantum yield for hydrogen generation was measured for methanol and ethanol water solutions reaching a maximum of 16% under irradiation with a wavelength of 313 nm in methanol/water solution (1/8 v/v). Pt NPs loaded on TiO2 NTs represented also a true water splitting catalyst under UV irradiation and pure distilled water. DC-MS method appears to be a technologically simple, ecologically benign and potentially low-cost process for production of an efficient photocatalyst loaded with ultra-small NPs with precise size control.
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•Improved photo-induced reforming of alcohols for hydrogen production at room temperature.•Ultra-small platinum nanoparticles were loaded on TiO2 nanotubes by DC-magnetron sputtering technique.•Up to 16% apparent quantum efficiency for hydrogen production at 313 nm on 1.1–1.3 nm Pt NPs loaded on TiO2 nanotubes. |
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AbstractList | Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetron sputtering (DC-MS) technique. The photocatalytic hydrogen rate achieved an optimum value for a loading of about 1 wt% of Pt. Apparent quantum yield for hydrogen generation was measured for methanol and ethanol water solutions reaching a maximum of 16% under irradiation with a wavelength of 313 nm in methanol/water solution (1/8 v/v). Pt NPs loaded on TiO2 NTs represented also a true water splitting catalyst under UV irradiation and pure distilled water. DC-MS method appears to be a technologically simple, ecologically benign and potentially low-cost process for production of an efficient photocatalyst loaded with ultra-small NPs with precise size control.
[Display omitted]
•Improved photo-induced reforming of alcohols for hydrogen production at room temperature.•Ultra-small platinum nanoparticles were loaded on TiO2 nanotubes by DC-magnetron sputtering technique.•Up to 16% apparent quantum efficiency for hydrogen production at 313 nm on 1.1–1.3 nm Pt NPs loaded on TiO2 nanotubes. |
Author | Migowski, Pedro Teixeira, Sérgio R. de Moraes, Diogo P. Scheffer, Francine R. Baptista, Daniel L. Machado, Guilherme J. Feil, Adriano F. Dupont, Jairton Languer, Mariana P. Weibel, Daniel E. |
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Keywords | Water splitting TiO2 nanotubes Platinum Photocatalysis Hydrogen production Apparent quantum yield Hydrogen Nanoparticle Nanotube Reforming Quantum yield nanotubes Chemical decomposition TiO Titanium oxide |
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Snippet | Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt... |
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SubjectTerms | Alternative fuels. Production and utilization Apparent quantum yield Applied sciences Energy Exact sciences and technology Fuels Hydrogen Hydrogen production Photocatalysis Platinum TiO2 nanotubes Water splitting |
Title | Photo-induced reforming of alcohols with improved hydrogen apparent quantum yield on TiO2 nanotubes loaded with ultra-small Pt nanoparticles |
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