Photo-induced reforming of alcohols with improved hydrogen apparent quantum yield on TiO2 nanotubes loaded with ultra-small Pt nanoparticles

Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetro...

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Published inInternational journal of hydrogen energy Vol. 38; no. 34; pp. 14440 - 14450
Main Authors Languer, Mariana P., Scheffer, Francine R., Feil, Adriano F., Baptista, Daniel L., Migowski, Pedro, Machado, Guilherme J., de Moraes, Diogo P., Dupont, Jairton, Teixeira, Sérgio R., Weibel, Daniel E.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 13.11.2013
Elsevier
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Abstract Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetron sputtering (DC-MS) technique. The photocatalytic hydrogen rate achieved an optimum value for a loading of about 1 wt% of Pt. Apparent quantum yield for hydrogen generation was measured for methanol and ethanol water solutions reaching a maximum of 16% under irradiation with a wavelength of 313 nm in methanol/water solution (1/8 v/v). Pt NPs loaded on TiO2 NTs represented also a true water splitting catalyst under UV irradiation and pure distilled water. DC-MS method appears to be a technologically simple, ecologically benign and potentially low-cost process for production of an efficient photocatalyst loaded with ultra-small NPs with precise size control. [Display omitted] •Improved photo-induced reforming of alcohols for hydrogen production at room temperature.•Ultra-small platinum nanoparticles were loaded on TiO2 nanotubes by DC-magnetron sputtering technique.•Up to 16% apparent quantum efficiency for hydrogen production at 313 nm on 1.1–1.3 nm Pt NPs loaded on TiO2 nanotubes.
AbstractList Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt nanoparticles (NPs) loaded on TiO2 nanotubes (NTs). The Pt NPs with diameters between 1.1 and 1.3 nm were deposited on TiO2 NTs by DC-magnetron sputtering (DC-MS) technique. The photocatalytic hydrogen rate achieved an optimum value for a loading of about 1 wt% of Pt. Apparent quantum yield for hydrogen generation was measured for methanol and ethanol water solutions reaching a maximum of 16% under irradiation with a wavelength of 313 nm in methanol/water solution (1/8 v/v). Pt NPs loaded on TiO2 NTs represented also a true water splitting catalyst under UV irradiation and pure distilled water. DC-MS method appears to be a technologically simple, ecologically benign and potentially low-cost process for production of an efficient photocatalyst loaded with ultra-small NPs with precise size control. [Display omitted] •Improved photo-induced reforming of alcohols for hydrogen production at room temperature.•Ultra-small platinum nanoparticles were loaded on TiO2 nanotubes by DC-magnetron sputtering technique.•Up to 16% apparent quantum efficiency for hydrogen production at 313 nm on 1.1–1.3 nm Pt NPs loaded on TiO2 nanotubes.
Author Migowski, Pedro
Teixeira, Sérgio R.
de Moraes, Diogo P.
Scheffer, Francine R.
Baptista, Daniel L.
Machado, Guilherme J.
Feil, Adriano F.
Dupont, Jairton
Languer, Mariana P.
Weibel, Daniel E.
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  givenname: Mariana P.
  surname: Languer
  fullname: Languer, Mariana P.
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
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  givenname: Francine R.
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  fullname: Scheffer, Francine R.
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
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  givenname: Adriano F.
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  fullname: Feil, Adriano F.
  organization: Instituto de Física, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15051, 91501-970 Porto Alegre, RS, Brazil
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  givenname: Daniel L.
  surname: Baptista
  fullname: Baptista, Daniel L.
  organization: Instituto de Física, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15051, 91501-970 Porto Alegre, RS, Brazil
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  givenname: Pedro
  surname: Migowski
  fullname: Migowski, Pedro
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
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  givenname: Guilherme J.
  surname: Machado
  fullname: Machado, Guilherme J.
  organization: Instituto de Física, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15051, 91501-970 Porto Alegre, RS, Brazil
– sequence: 7
  givenname: Diogo P.
  surname: de Moraes
  fullname: de Moraes, Diogo P.
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
– sequence: 8
  givenname: Jairton
  surname: Dupont
  fullname: Dupont, Jairton
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
– sequence: 9
  givenname: Sérgio R.
  surname: Teixeira
  fullname: Teixeira, Sérgio R.
  organization: Instituto de Física, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15051, 91501-970 Porto Alegre, RS, Brazil
– sequence: 10
  givenname: Daniel E.
  surname: Weibel
  fullname: Weibel, Daniel E.
  email: danielw@iq.ufrgs.br
  organization: Instituto de Química, Universidade Federal do Rio Grande do Sul, UFRGS, Avenida Bento Gonçalves 9500, P.O. Box 15003, 91501-970 Porto Alegre, RS, Brazil
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Issue 34
Keywords Water splitting
TiO2 nanotubes
Platinum
Photocatalysis
Hydrogen production
Apparent quantum yield
Hydrogen
Nanoparticle
Nanotube
Reforming
Quantum yield
nanotubes
Chemical decomposition
TiO
Titanium oxide
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Snippet Photo-induced reforming of methanol, ethanol, glycerol and phenol at room temperature for hydrogen production was investigated with the use of ultra-small Pt...
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SubjectTerms Alternative fuels. Production and utilization
Apparent quantum yield
Applied sciences
Energy
Exact sciences and technology
Fuels
Hydrogen
Hydrogen production
Photocatalysis
Platinum
TiO2 nanotubes
Water splitting
Title Photo-induced reforming of alcohols with improved hydrogen apparent quantum yield on TiO2 nanotubes loaded with ultra-small Pt nanoparticles
URI https://dx.doi.org/10.1016/j.ijhydene.2013.09.018
Volume 38
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