Decay Resistance of Citric Acid Cross-Linked Paper
Paper pots are widely used in vegetable transplantation in agricultural cultivation and must have sufficient strength to withstand separation and mechanical works that occur during transplantation. Therefore, biodegradation owing to soil microorganisms during seedling growth must be inhibited. In th...
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| Published in | Journal of Fiber Science and Technology Vol. 80; no. 9; pp. 197 - 203 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
The Society of Fiber Science and Technology, Japan
10.09.2024
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Paper pots are widely used in vegetable transplantation in agricultural cultivation and must have sufficient strength to withstand separation and mechanical works that occur during transplantation. Therefore, biodegradation owing to soil microorganisms during seedling growth must be inhibited. In this study, hydrolysis owing to cellulase was inhibited by applying an arbitray mixture of citric acid and sodium hypophosphite to paper and then heat-treating it. This inhibition of hydrolysis resulted from the formation of a cross-linked structure between the cellulose hydroxyl groups of the paper (wood pulp) and citric acid through ester bonds. The decay-resistant paper produced by this method will be useful as a base paper for the production of paper pots. |
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| AbstractList | Paper pots are widely used in vegetable transplantation in agricultural cultivation and must have sufficient strength to withstand separation and mechanical works that occur during transplantation. Therefore, biodegradation owing to soil microorganisms during seedling growth must be inhibited. In this study, hydrolysis owing to cellulase was inhibited by applying an arbitray mixture of citric acid and sodium hypophosphite to paper and then heat-treating it. This inhibition of hydrolysis resulted from the formation of a cross-linked structure between the cellulose hydroxyl groups of the paper (wood pulp) and citric acid through ester bonds. The decay-resistant paper produced by this method will be useful as a base paper for the production of paper pots. |
| ArticleNumber | 2024-0022 |
| Author | Nakagawa, Takuya Uchino, Hirokatsu Watanabe, Toshihiro |
| Author_xml | – sequence: 1 fullname: Nakagawa, Takuya organization: Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589 Japan – sequence: 1 fullname: Uchino, Hirokatsu organization: Nippon Beet Sugar Manufacturing Co., Ltd., Minami9-13, Inada-cho, Obihiro 080-0831 Japan – sequence: 1 fullname: Watanabe, Toshihiro organization: Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589 Japan |
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| Cites_doi | 10.1177/004051750107100303 10.2115/fiber.65.67 10.1016/j.carbpol.2013.10.002 10.1016/j.reactfunctpolym.2015.03.007 |
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| References | M. Yamana and M. Seto, Special Publication No. 54-22882 H. Terasawa and M. Osaki, Development and evaluation of paper for seedling raising pots produced by crosslinking wood polysaccharide using DMDHEU, SEN’I GAKKAISHI 65(2), 67 (2009). C. M. Herron and D. J. Cooper, Individualized polycarboxylic acid crosslinked fibers. US Patent 5,183,707 (1993). P. Cuadro et al., Cross-linkling of cellulose and poly (ethylene glycol) with citric acid. React. Funct. Polym., 90, 21 (2015). C. M. Herron et al., Process for pepering individualized, polycarboxylic acid crosslinked ficers. US Patent 5, 190, 563 (1993). C. Q. Yang, FTIR spectroscopy study of ester crosslinking of cotton cellulose catalyzed by sodium hypophosphite, Textile Res. J., 71(3), 201 (2001). P. Widsten et al., Citric acid crosslinking of paper products for improved high humidity perfprmance, Carbohydr. Polym., 101, 998 (2014). H. H. Espy, The mechanism of wet-strength development in paper: a review, Tappi Journal, 78(4), 90 (1995). A. Masuda, Y. Sasaki, and M. Tanimura, JP 48-52527 H. Terasawa, M. Tanimura, and S. Ito, JP 5-268838 D. F. Caulfield, Ester crosslinking to improve wet performance of paper using multifumctional carboxylic acids, butaneteracarboxylic and citic acid, Tappi Journal, 77(3), 205 (1993). 11 1 2 3 4 5 6 7 8 9 10 |
| References_xml | – reference: H. H. Espy, The mechanism of wet-strength development in paper: a review, Tappi Journal, 78(4), 90 (1995). – reference: H. Terasawa, M. Tanimura, and S. Ito, JP 5-268838 – reference: C. Q. Yang, FTIR spectroscopy study of ester crosslinking of cotton cellulose catalyzed by sodium hypophosphite, Textile Res. J., 71(3), 201 (2001). – reference: P. Widsten et al., Citric acid crosslinking of paper products for improved high humidity perfprmance, Carbohydr. Polym., 101, 998 (2014). – reference: A. Masuda, Y. Sasaki, and M. Tanimura, JP 48-52527 – reference: C. M. Herron et al., Process for pepering individualized, polycarboxylic acid crosslinked ficers. US Patent 5, 190, 563 (1993). – reference: C. M. Herron and D. J. Cooper, Individualized polycarboxylic acid crosslinked fibers. US Patent 5,183,707 (1993). – reference: H. Terasawa and M. Osaki, Development and evaluation of paper for seedling raising pots produced by crosslinking wood polysaccharide using DMDHEU, SEN’I GAKKAISHI 65(2), 67 (2009). – reference: D. F. Caulfield, Ester crosslinking to improve wet performance of paper using multifumctional carboxylic acids, butaneteracarboxylic and citic acid, Tappi Journal, 77(3), 205 (1993). – reference: P. Cuadro et al., Cross-linkling of cellulose and poly (ethylene glycol) with citric acid. React. Funct. Polym., 90, 21 (2015). – reference: M. Yamana and M. Seto, Special Publication No. 54-22882 – ident: 2 – ident: 3 – ident: 10 doi: 10.1177/004051750107100303 – ident: 4 doi: 10.2115/fiber.65.67 – ident: 5 – ident: 1 – ident: 7 doi: 10.1016/j.carbpol.2013.10.002 – ident: 6 – ident: 9 – ident: 8 – ident: 11 doi: 10.1016/j.reactfunctpolym.2015.03.007 |
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| Snippet | Paper pots are widely used in vegetable transplantation in agricultural cultivation and must have sufficient strength to withstand separation and mechanical... |
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| Title | Decay Resistance of Citric Acid Cross-Linked Paper |
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