Cryo-XPS study of xanthate adsorption on pyrite

The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both dixanthogen and metal‐xanthate complexes has been suggested. In this study, both room temperature X‐ray photoelectron spectroscopy (XPS) (RT‐XPS) a...

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Published in	Surface and interface analysis Vol. 45; no. 4; pp. 805 - 810
Main Authors	Deng, Meijiao, Karpuzov, Dimitre, Liu, Qingxia, Xu, Zhenghe
Format	Journal Article
Language	English
Published	Chichester Blackwell Publishing Ltd 01.04.2013 Wiley Wiley Subscription Services, Inc
Subjects	Activation Adsorption adsorption of xanthate Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Copper Cryo-XPS Electron and ion emission by liquids and solids; impact phenomena Exact sciences and technology flotation Hydrophobicity Photoemission and photoelectron spectra Physics Pyrite Solid surfaces and solid-solid interfaces Surface chemistry Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) X-ray photoelectron spectroscopy xanthate XPS Liquid state pH value Inorganic compounds Xanthates adsorption of xanthate Transition element compounds xanthate Nitrogen Iron sulfide Cryo-XPS Pyrite Transition elements XPS Copper flotation X-ray photoelectron spectra
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Abstract	The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both dixanthogen and metal‐xanthate complexes has been suggested. In this study, both room temperature X‐ray photoelectron spectroscopy (XPS) (RT‐XPS) and liquid nitrogen temperature XPS (Cryo‐XPS) were used to study interactions between pyrite and xanthate. While dixanthogen was not detected by RT‐XPS, it was successfully identified through C1s and S 2p peaks using Cryo‐XPS. The impact of pH and copper activation on adsorption of xanthate on pyrite was also investigated. It was found that at low pH, dixanthogen is the dominant species of xanthate adsorption on pyrite. At high pH, metal‐xanthate complexes were found to be prevalent on pyrite surfaces, which are responsible for the surface hydrophobicity. Copper activation showed a significant effect on xanthate adsorption on Cu‐activated pyrite, resulting in mostly the formation of Cu‐xanthate complexes rather than dixanthogen, mainly in the form of Cu(I)‐isopropyl xanthate complex (CuIPX). Copyright © 2012 John Wiley & Sons, Ltd.
AbstractList	The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both dixanthogen and metal‐xanthate complexes has been suggested. In this study, both room temperature X‐ray photoelectron spectroscopy (XPS) (RT‐XPS) and liquid nitrogen temperature XPS (Cryo‐XPS) were used to study interactions between pyrite and xanthate. While dixanthogen was not detected by RT‐XPS, it was successfully identified through C1s and S 2p peaks using Cryo‐XPS. The impact of pH and copper activation on adsorption of xanthate on pyrite was also investigated. It was found that at low pH, dixanthogen is the dominant species of xanthate adsorption on pyrite. At high pH, metal‐xanthate complexes were found to be prevalent on pyrite surfaces, which are responsible for the surface hydrophobicity. Copper activation showed a significant effect on xanthate adsorption on Cu‐activated pyrite, resulting in mostly the formation of Cu‐xanthate complexes rather than dixanthogen, mainly in the form of Cu(I)‐isopropyl xanthate complex (CuIPX). Copyright © 2012 John Wiley & Sons, Ltd. The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both dixanthogen and metal-xanthate complexes has been suggested. In this study, both room temperature X-ray photoelectron spectroscopy (XPS) (RT-XPS) and liquid nitrogen temperature XPS (Cryo-XPS) were used to study interactions between pyrite and xanthate. While dixanthogen was not detected by RT-XPS, it was successfully identified through C1s and S 2p peaks using Cryo-XPS. The impact of pH and copper activation on adsorption of xanthate on pyrite was also investigated. It was found that at low pH, dixanthogen is the dominant species of xanthate adsorption on pyrite. At high pH, metal-xanthate complexes were found to be prevalent on pyrite surfaces, which are responsible for the surface hydrophobicity. Copper activation showed a significant effect on xanthate adsorption on Cu-activated pyrite, resulting in mostly the formation of Cu-xanthate complexes rather than dixanthogen, mainly in the form of Cu(I)-isopropyl xanthate complex (CuIPX). Copyright [copy 2012 John Wiley & Sons, Ltd. The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both dixanthogen and metal-xanthate complexes has been suggested. In this study, both room temperature X-ray photoelectron spectroscopy (XPS) (RT-XPS) and liquid nitrogen temperature XPS (Cryo-XPS) were used to study interactions between pyrite and xanthate. While dixanthogen was not detected by RT-XPS, it was successfully identified through C1s and S 2p peaks using Cryo-XPS. The impact of pH and copper activation on adsorption of xanthate on pyrite was also investigated. It was found that at low pH, dixanthogen is the dominant species of xanthate adsorption on pyrite. At high pH, metal-xanthate complexes were found to be prevalent on pyrite surfaces, which are responsible for the surface hydrophobicity. Copper activation showed a significant effect on xanthate adsorption on Cu-activated pyrite, resulting in mostly the formation of Cu-xanthate complexes rather than dixanthogen, mainly in the form of Cu(I)-isopropyl xanthate complex (CuIPX). Copyright © 2012 John Wiley & Sons, Ltd. [PUBLICATION ABSTRACT]
Author	Deng, Meijiao Karpuzov, Dimitre Liu, Qingxia Xu, Zhenghe
Author_xml	– sequence: 1 givenname: Meijiao surname: Deng fullname: Deng, Meijiao organization: Chemical and Materials Engineering, University of Alberta, AB, T6G 2 G6, Edmonton, Canada – sequence: 2 givenname: Dimitre surname: Karpuzov fullname: Karpuzov, Dimitre email: Correspondence to: Dimitre Karpuzov, Chemical and Materials Engineering, University of Alberta, Edmonton, AB, Canada T6G 2 G6., karpuzov@ualberta.ca organization: Chemical and Materials Engineering, University of Alberta, AB, T6G 2 G6, Edmonton, Canada – sequence: 3 givenname: Qingxia surname: Liu fullname: Liu, Qingxia organization: Chemical and Materials Engineering, University of Alberta, AB, T6G 2 G6, Edmonton, Canada – sequence: 4 givenname: Zhenghe surname: Xu fullname: Xu, Zhenghe organization: Chemical and Materials Engineering, University of Alberta, AB, T6G 2 G6, Edmonton, Canada
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Copyright	Copyright © 2012 John Wiley & Sons, Ltd. 2014 INIST-CNRS Copyright © 2013 John Wiley & Sons, Ltd.
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Keywords	Liquid state pH value Inorganic compounds Xanthates adsorption of xanthate Transition element compounds xanthate Nitrogen Iron sulfide Cryo-XPS Pyrite Transition elements XPS Copper flotation X-ray photoelectron spectra
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Snippet	The adsorption of xanthate on pyrite has been extensively studied. However, the adsorption mechanisms remain a subject of controversy. Formation of both...
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SubjectTerms	Activation Adsorption adsorption of xanthate Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Copper Cryo-XPS Electron and ion emission by liquids and solids; impact phenomena Exact sciences and technology flotation Hydrophobicity Photoemission and photoelectron spectra Physics Pyrite Solid surfaces and solid-solid interfaces Surface chemistry Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties) X-ray photoelectron spectroscopy xanthate XPS
Title	Cryo-XPS study of xanthate adsorption on pyrite
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