Tris(trimethylsilyl)phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries

Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi sub(0.5)Co sub(0.2)-Mn sub(0.3)O sub(2) cycling at high cut-off potential in LiPF sub(6)-based electrolyte. Linear sweep voltammetry (LSV) results reveal that TMSP oxidizes prior to the decomposition of ca...

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Published in	Journal of power sources Vol. 248; pp. 1306 - 1311
Main Authors	Yan, Guochun, Li, Xinhai, Wang, Zhixing, Guo, Huajun, Wang, Chao
Format	Journal Article
Language	English
Published	Amsterdam Elsevier 2014
Subjects	Additives Applied sciences Cathodes Cut-off Cycles Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemical impedance spectroscopy Electrolytes Exact sciences and technology High voltages Lithium-ion batteries Materials X-ray photoelectron spectroscopy Phosphates Lithium ion batteries Cobalt Oxides Cathode Nickel Oxides Lithium Oxides Film formation Secondary cell Tris(trimethylsilyl)phosphate Electrode material Phosphorus Compounds Additive Inorganic anion High voltage Lithium nickel cobalt manganese oxide Manganese Oxides Film forming properties
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Abstract	Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi sub(0.5)Co sub(0.2)-Mn sub(0.3)O sub(2) cycling at high cut-off potential in LiPF sub(6)-based electrolyte. Linear sweep voltammetry (LSV) results reveal that TMSP oxidizes prior to the decomposition of carbonate solvents in electrolyte. When TMSP is incorporated into the electrolyte, the electrochemical performance of LiNi sub(0.5)Co sub(0.2)Mn sub(0.3)O sub(2) is enhanced significantly. The initial discharge capacity of LiNi sub(0.5)Co sub(0.3)Mn sub(0.3)O sub(2) cathode material cycling in the electrolyte with 1 % TMSP is increased from 173.4 to 191.0 mAh g super(-1) compared with that without TMSP between 3.0 and 4.5 V (vs. Li/Li super(+)) at 0.1 C(1 C = 170 mA g super(-1)). In addition, it exhibits a capacity-retention of 90.9% at 1 C after 100 cycles, while that without TMSP is 77.0%. TEM, XPS, and EIS analyses confirm that the film derived from TMSP protects LiNi sub(0.5)Co sub(0.2)Mn sub(0.3)O sub(2) material from eroding by HF effectively, and reduces the interface impedance.
AbstractList	Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi sub(0.5)Co sub(0.2)-Mn sub(0.3)O sub(2) cycling at high cut-off potential in LiPF sub(6)-based electrolyte. Linear sweep voltammetry (LSV) results reveal that TMSP oxidizes prior to the decomposition of carbonate solvents in electrolyte. When TMSP is incorporated into the electrolyte, the electrochemical performance of LiNi sub(0.5)Co sub(0.2)Mn sub(0.3)O sub(2) is enhanced significantly. The initial discharge capacity of LiNi sub(0.5)Co sub(0.3)Mn sub(0.3)O sub(2) cathode material cycling in the electrolyte with 1 % TMSP is increased from 173.4 to 191.0 mAh g super(-1) compared with that without TMSP between 3.0 and 4.5 V (vs. Li/Li super(+)) at 0.1 C(1 C = 170 mA g super(-1)). In addition, it exhibits a capacity-retention of 90.9% at 1 C after 100 cycles, while that without TMSP is 77.0%. TEM, XPS, and EIS analyses confirm that the film derived from TMSP protects LiNi sub(0.5)Co sub(0.2)Mn sub(0.3)O sub(2) material from eroding by HF effectively, and reduces the interface impedance. Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi0.5Co0.2Mn0.3O2 cycling at high cut-off potential in LiPF6-based electrolyte. Linear sweep voltammetry (LSV) results reveal that TMSP oxidizes prior to the decomposition of carbonate solvents in electrolyte. When TMSP is incorporated into the electrolyte, the electrochemical performance of LiNi0.5Co0.2Mn0.3O2 is enhanced significantly. The initial discharge capacity of LiNi0.5Co0.2Mn0.3O2 cathode material cycling in the electrolyte with 1% TMSP is increased from 173.4 to 191.0 mAh g-1 compared with that without TMSP between 3.0 and 4.5 V (vs. Li/Li+) at 0.1 C (1 C = 170 mA g-1). In addition, it exhibits a capacity-retention of 90.9% at 1 C after 100 cycles, while that without TMSP is 77.0%. TEM, XPS, and EIS analyses confirm that the film derived from TMSP protects LiNi0.5Co0.2Mn0.3O2 material from eroding by HF effectively, and reduces the interface impedance.
Author	Yan, Guochun Li, Xinhai Guo, Huajun Wang, Chao Wang, Zhixing
Author_xml	– sequence: 1 givenname: Guochun surname: Yan fullname: Yan, Guochun – sequence: 2 givenname: Xinhai surname: Li fullname: Li, Xinhai – sequence: 3 givenname: Zhixing surname: Wang fullname: Wang, Zhixing – sequence: 4 givenname: Huajun surname: Guo fullname: Guo, Huajun – sequence: 5 givenname: Chao surname: Wang fullname: Wang, Chao
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Keywords	Phosphates Lithium ion batteries Cobalt Oxides Cathode Nickel Oxides Lithium Oxides Film formation Secondary cell Tris(trimethylsilyl)phosphate Electrode material Phosphorus Compounds Additive Inorganic anion High voltage Lithium nickel cobalt manganese oxide Manganese Oxides Film forming properties
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Snippet	Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi0.5Co0.2Mn0.3O2 cycling at high cut-off potential in LiPF6-based... Tris(trimethylsilyl)phosphate (TMSP) is investigated as a novel film-forming additive for LiNi sub(0.5)Co sub(0.2)-Mn sub(0.3)O sub(2) cycling at high cut-off...
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SubjectTerms	Additives Applied sciences Cathodes Cut-off Cycles Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Electrochemical impedance spectroscopy Electrolytes Exact sciences and technology High voltages Lithium-ion batteries Materials X-ray photoelectron spectroscopy
Title	Tris(trimethylsilyl)phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries
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