Morphology and properties of organoclay modified polycarbonate/poly(methyl methacrylate) blend
Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and organically modified montmorillonite (OMMT). The morphology of OMMT modified PC/PMMA blend with two different weight percents of OMMT was studied using...
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| Published in | Polymer engineering and science Vol. 46; no. 8; pp. 1121 - 1129 |
|---|---|
| Main Authors | , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
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Hoboken
Wiley Subscription Services, Inc., A Wiley Company
01.08.2006
Wiley Subscription Services Society of Plastics Engineers, Inc Blackwell Publishing Ltd |
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| Abstract | Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and organically modified montmorillonite (OMMT). The morphology of OMMT modified PC/PMMA blend with two different weight percents of OMMT was studied using scanning electron microscopy, transmission electron microscopy (TEM), and X‐ray diffraction (XRD). The size of the phase‐separated domains decreased dramatically with increasing the content of OMMT. XRD patterns and TEM observations revealed that silicate layers were intercalated and nicely dispersed in the blend matrix. Differential scanning calorimetry analyses showed efficient mixing of two immiscible polymers in the presence of OMMT. The blend nanocomposites showed greatly improved mechanical properties when compared with the same blend sample without OMMT. Finally, the opaque immiscible PC/PMMA blend became translucent after modification with OMMT addition. POLYM. ENG. SCI., 46:1121–1129, 2006. © 2006 Society of Plastics Engineers |
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| AbstractList | Virgin and organoclay modified polycarbonate (PC)/ poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt-mixing of PC, PMMA, and organically modified montmorillonite (OMMT). The morphology of OMMT modified PC/PMMA blend with two different weight percents of OMMT was studied using scanning electron microscopy, transmission electron microscopy (TEM), and X-ray diffraction (XRD). The size of the phase-separated domains decreased dramatically with increasing the content of OMMT. XRD patterns and TEM observations revealed that silicate layers were intercalated and nicely dispersed in the blend matrix. Differential scanning calorimetry analyses showed efficient mixing of two immiscible polymers in the presence of OMMT. The blend nanocomposites showed greatly improved mechanical properties when compared with the same blend sample without OMMT. Finally, the opaque immiscible PC/PMMA blend became translucent after modification with OMMT addition. [PUBLICATION ABSTRACT] Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and organically modified montmorillonite (OMMT). The morphology of OMMT modified PC/PMMA blend with two different weight percents of OMMT was studied using scanning electron microscopy, transmission electron microscopy (TEM), and X‐ray diffraction (XRD). The size of the phase‐separated domains decreased dramatically with increasing the content of OMMT. XRD patterns and TEM observations revealed that silicate layers were intercalated and nicely dispersed in the blend matrix. Differential scanning calorimetry analyses showed efficient mixing of two immiscible polymers in the presence of OMMT. The blend nanocomposites showed greatly improved mechanical properties when compared with the same blend sample without OMMT. Finally, the opaque immiscible PC/PMMA blend became translucent after modification with OMMT addition. POLYM. ENG. SCI., 46:1121–1129, 2006. © 2006 Society of Plastics Engineers Abstract Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and organically modified montmorillonite (OMMT). The morphology of OMMT modified PC/PMMA blend with two different weight percents of OMMT was studied using scanning electron microscopy, transmission electron microscopy (TEM), and X‐ray diffraction (XRD). The size of the phase‐separated domains decreased dramatically with increasing the content of OMMT. XRD patterns and TEM observations revealed that silicate layers were intercalated and nicely dispersed in the blend matrix. Differential scanning calorimetry analyses showed efficient mixing of two immiscible polymers in the presence of OMMT. The blend nanocomposites showed greatly improved mechanical properties when compared with the same blend sample without OMMT. Finally, the opaque immiscible PC/PMMA blend became translucent after modification with OMMT addition. POLYM. ENG. SCI., 46:1121–1129, 2006. © 2006 Society of Plastics Engineers |
| Audience | Academic |
| Author | Bousmina, M. Ray, S. Sinha Maazouz, A. |
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| Keywords | Clay Mixing Organic clay Polymer blends Montmorillonite Dispersion degree Methyl methacrylate polymer Mechanical properties Dispersion reinforced material Experimental study Property processing relationship Composite material Heterogeneous mixture Structure processing relationship Morphology Concentration effect Nanocomposite Polycarbonate |
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| Snippet | Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and organically... Abstract Virgin and organoclay modified polycarbonate (PC)/poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt‐mixing of PC, PMMA, and... Virgin and organoclay modified polycarbonate (PC)/ poly(methyl methacrylate) (PMMA) (30/70 w/w) blends were prepared by melt-mixing of PC, PMMA, and... |
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| SubjectTerms | Applied sciences Composites Differential scanning calorimetry Epoxy resins Exact sciences and technology Forms of application and semi-finished materials Matrix Mechanical properties Molecular weight Polymer blends Polymer industry, paints, wood Polymeric composites Scanning electron microscopy Technology of polymers Thermogravimetric analysis |
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| Title | Morphology and properties of organoclay modified polycarbonate/poly(methyl methacrylate) blend |
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