Determination and Monitoring of Tetracycline and Degradation Products in Landfill Leachate

Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4‐epitetracycline (ET...

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Published inClean : soil, air, water Vol. 44; no. 4; pp. 444 - 450
Main Authors Topal, Murat, Arslan Topal, Emine Işıl
Format Journal Article
LanguageEnglish
Published Weinheim Blackwell Publishing Ltd 01.04.2016
Wiley Subscription Services, Inc
Subjects
Antibiotics
LC-MS-MS
Leachate basin
Metabolites
Solid waste
MED, Turkey
Online AccessGet full text

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Abstract Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4‐epitetracycline (ETC), and 4‐epianhydrotetracycline (EATC) in the leachate basin of landfill located in Elazığ City, Turkey. For this aim, leachate samples are taken from the leachate basin every week (wk) during March and April 2014. Maximum TC, ETC, EATC, and ATC concentrations in leachate samples are 2.47 ± 0.12 (wk 3), 10.3 ± 0.5 (wk 3), 37.1 ± 1.8 (wk 1), and 6.43 ± 0.32 μg/L (wk 8). The concentrations of TC and DPs followed the decreasing order of EATC > ETC > ATC > TC. As a result, it is determined that the concentrations of TC and DPs are at μg/L levels in the leachate basin of landfill. Tetracyclines (TCs) have importance because of their common usage, toxicity, and potential to enter the receiving environment. This study determines TC and the degradation products (DPs) in the leachate basin of a landfill. The concentrations of TC and DPs follows the decreasing order of 4‐epianhydrotetracycline > 4‐epitetracycline > anhydrotetracycline > TC. The concentrations of TC and DPs are at µg/L levels.
AbstractList Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4‐epitetracycline (ETC), and 4‐epianhydrotetracycline (EATC) in the leachate basin of landfill located in Elazığ City, Turkey. For this aim, leachate samples are taken from the leachate basin every week (wk) during March and April 2014. Maximum TC, ETC, EATC, and ATC concentrations in leachate samples are 2.47 ± 0.12 (wk 3), 10.3 ± 0.5 (wk 3), 37.1 ± 1.8 (wk 1), and 6.43 ± 0.32 μg/L (wk 8). The concentrations of TC and DPs followed the decreasing order of EATC > ETC > ATC > TC. As a result, it is determined that the concentrations of TC and DPs are at μg/L levels in the leachate basin of landfill. Tetracyclines (TCs) have importance because of their common usage, toxicity, and potential to enter the receiving environment. This study determines TC and the degradation products (DPs) in the leachate basin of a landfill. The concentrations of TC and DPs follows the decreasing order of 4‐epianhydrotetracycline > 4‐epitetracycline > anhydrotetracycline > TC. The concentrations of TC and DPs are at µg/L levels.
Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4‐epitetracycline (ETC), and 4‐epianhydrotetracycline (EATC) in the leachate basin of landfill located in Elazığ City, Turkey. For this aim, leachate samples are taken from the leachate basin every week (wk) during March and April 2014. Maximum TC, ETC, EATC, and ATC concentrations in leachate samples are 2.47 ± 0.12 (wk 3), 10.3 ± 0.5 (wk 3), 37.1 ± 1.8 (wk 1), and 6.43 ± 0.32 μg/L (wk 8). The concentrations of TC and DPs followed the decreasing order of EATC > ETC > ATC > TC. As a result, it is determined that the concentrations of TC and DPs are at μg/L levels in the leachate basin of landfill.
Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4-epitetracycline (ETC), and 4-epianhydrotetracycline (EATC) in the leachate basin of landfill located in Elazi City, Turkey. For this aim, leachate samples are taken from the leachate basin every week (wk) during March and April 2014. Maximum TC, ETC, EATC, and ATC concentrations in leachate samples are 2.47±0.12 (wk 3), 10.3±0.5 (wk 3), 37.1±1.8 (wk 1), and 6.43±0.32µg/L (wk 8). The concentrations of TC and DPs followed the decreasing order of EATC>ETC>ATC>TC. As a result, it is determined that the concentrations of TC and DPs are at µg/L levels in the leachate basin of landfill.
Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim of this study is the determination of concentrations of TC and degradation products (DPs) as anhydrotetracycline (ATC), 4-epitetracycline (ETC), and 4-epianhydrotetracycline (EATC) in the leachate basin of landfill located in Elazi City, Turkey. For this aim, leachate samples are taken from the leachate basin every week (wk) during March and April 2014. Maximum TC, ETC, EATC, and ATC concentrations in leachate samples are 2.47 plus or minus 0.12 (wk 3), 10.3 plus or minus 0.5 (wk 3), 37.1 plus or minus 1.8 (wk 1), and 6.43 plus or minus 0.32 mu g/L (wk 8). The concentrations of TC and DPs followed the decreasing order of EATC>ETC>ATC>TC. As a result, it is determined that the concentrations of TC and DPs are at mu g/L levels in the leachate basin of landfill. Tetracyclines (TCs) have importance because of their common usage, toxicity, and potential to enter the receiving environment. This study determines TC and the degradation products (DPs) in the leachate basin of a landfill. The concentrations of TC and DPs follows the decreasing order of 4-epianhydrotetracycline>4-epitetracycline>anhydrotet racycline>TC. The concentrations of TC and DPs are at mu g/L levels.
Author Topal, Murat
Arslan Topal, Emine Işıl
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  givenname: Emine Işıl
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  organization: Faculty of Engineering, Department of Environmental Engineering, University of Firat, Elazığ, Turkey
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Snippet Tetracyclines (TCs) have importance because of their common usage, high potential to reach the receiving environments, and toxicity for the organisms. The aim...
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SubjectTerms Antibiotics
LC-MS-MS
Leachate basin
Metabolites
Solid waste
Title Determination and Monitoring of Tetracycline and Degradation Products in Landfill Leachate
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