Syntheses and Structures of Acetyl-Acetonato-Alumo-Diphenylsilanolates with Magnesium(II), Iron(II), Iron(III), Cobalt(II), and Nickel(II)

• Published in: Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 642; no. 3; pp. 204 - 210
• Main Authors: Veith, Michael, Smail-Bubel, Hakima, Nadig, Sandra, Huch, Volker
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 01.02.2016; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Subjects: Acetylacetonate/silanolate; Aluminum; Iron-cobalt-nickel; Ligands; Magnesium; Metal aluminates; Nickel; X-ray diffraction

Bis(acetylacetonate)alumo‐oxo‐tetraphenyldisiloxane‐metal(II) dihydrates [(acac)2Al(O–SiPh2–O–SiPh2–O)]2M(H2O)2 (M = Mg, Fe, Co, Ni) were obtained from the corresponding acetyl‐acetonate‐dihydrates (acac)2M(H2O)2 by reaction with the alumosiloxane [O–Ph2Si–O–SiPh2–O]4Al4(OH)4. These new compounds di...