Superhydrophobic surfaces via controlling the morphology of ZnO micro/nano complex structure

ZnO micro/nano complex structure films, including reticulate papillary nodes, petal-like and flake-hole, have been self-assembled by a hydrothermal technique at different temperatures without metal catalysts. The wettability of the above film surfaces was modified with a simple coating of heptadecaf...

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Published inChinese physics B Vol. 19; no. 5; pp. 466 - 471
Main Author 公茂刚 许小亮 杨周 刘艳松 刘玲
Format Journal Article
LanguageEnglish
Published IOP Publishing 01.05.2010
Subjects
Contact angle
Morphology
Nanocomposites
Nanomaterials
Nanostructure
Toluene
Wettability
Zinc oxide
ZnO薄膜
微形貌
氧化锌薄膜
水接触角
疏水表面
纳米复合结构
表面生长
Online AccessGet full text
ISSN1674-1056
2058-3834
DOI10.1088/1674-1056/19/5/056701

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Abstract ZnO micro/nano complex structure films, including reticulate papillary nodes, petal-like and flake-hole, have been self-assembled by a hydrothermal technique at different temperatures without metal catalysts. The wettability of the above film surfaces was modified with a simple coating of heptadecafluorodecyltrimethoxy-silane in toluene. After modifying, the surface of ZnO film grown at 50℃ was converted from superhydrophilic with a water contact angle lower than 5° to superhydrophobic with a water contact angle of 165° Additionally, the surface of reticulate papillary nodes ZnO film grown at 100 ℃ had excellent superhydrophobicity, with a water contact angle of 173° and a sliding angle lower than 2° Furthermore, the water contact angle on the surface of petal-like and flake-hole ZnO films grown at 150℃ and 200℃ were found to be 140° and 120°, respectively. The wettability for the samples was found to depend strongly on the surface morphology which results from the growth temperature.
AbstractList ZnO micro/nano complex structure films, including reticulate papillary nodes, petal-like and flake-hole, have been self-assembled by a hydrothermal technique at different temperatures without metal catalysts. The wettability of the above film surfaces was modified with a simple coating of heptadecafluorodecyltrimethoxy-silane in toluene. After modifying, the surface of ZnO film grown at 50 degree C was converted from superhydrophilic with a water contact angle lower than 5 degree to superhydrophobic with a water contact angle of 165 degree . Additionally, the surface of reticulate papillary nodes ZnO film grown at 100 degree C had excellent superhydrophobicity, with a water contact angle of 173 degree and a sliding angle lower than 2 degree . Furthermore, the water contact angle on the surface of petal-like and flake-hole ZnO films grown at 150 degree C and 200 degree C were found to be 140 degree and 120 degree , respectively. The wettability for the samples was found to depend strongly on the surface morphology which results from the growth temperature.
ZnO micro/nano complex structure films, including reticulate papillary nodes, petal-like and flake-hole, have been self-assembled by a hydrothermal technique at different temperatures without metal catalysts. The wettability of the above film surfaces was modified with a simple coating of heptadecafluorodecyltrimethoxy-silane in toluene. After modifying, the surface of ZnO film grown at 50℃ was converted from superhydrophilic with a water contact angle lower than 5° to superhydrophobic with a water contact angle of 165° Additionally, the surface of reticulate papillary nodes ZnO film grown at 100 ℃ had excellent superhydrophobicity, with a water contact angle of 173° and a sliding angle lower than 2° Furthermore, the water contact angle on the surface of petal-like and flake-hole ZnO films grown at 150℃ and 200℃ were found to be 140° and 120°, respectively. The wettability for the samples was found to depend strongly on the surface morphology which results from the growth temperature.
Author 公茂刚 许小亮 杨周 刘艳松 刘玲
AuthorAffiliation Department of Physics, University of Science and Technology of China, Hefei 230026, China
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SubjectTerms Contact angle
Morphology
Nanocomposites
Nanomaterials
Nanostructure
Toluene
Wettability
Zinc oxide
ZnO薄膜
微形貌
氧化锌薄膜
水接触角
疏水表面
纳米复合结构
表面生长
Title Superhydrophobic surfaces via controlling the morphology of ZnO micro/nano complex structure
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