Characterization of MnO2 positive electrode for Fuel Cell/Battery (FCB)
Manganese dioxide was evaluated for use as the positive electrode in fuel cell-secondary battery composite systems. Electrodes were fabricated by coating nickel foam with a mixture of MnO2 and carbon black, and the charge/discharge behaviour studied in three systems: as a secondary battery positive...
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| Published in | Journal of power sources Vol. 181; no. 1; pp. 177 - 181 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Lausanne
Elsevier Sequoia
15.06.2008
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| Abstract | Manganese dioxide was evaluated for use as the positive electrode in fuel cell-secondary battery composite systems. Electrodes were fabricated by coating nickel foam with a mixture of MnO2 and carbon black, and the charge/discharge behaviour studied in three systems: as a secondary battery positive electrode; as the positive electrode in an alkaline fuel cell; and as the positive electrode in a composite system. MnO2 exhibited redox behaviour when used as the positive electrode in a secondary battery and subjected to charge-discharge cycles. When used as the positive electrode in a fuel cell, with a H2 supply to the negative electrode and an O2 supply to the positive electrode, the current-voltage characteristics were comparable to those obtained using a nickel positive electrode. The cell was capable of producing power when the O2 supply was temporarily interrupted. 18 refs. |
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| AbstractList | Manganese dioxide was evaluated for use as the positive electrode in fuel cell-secondary battery composite systems. Electrodes were fabricated by coating nickel foam with a mixture of MnO2 and carbon black, and the charge/discharge behaviour studied in three systems: as a secondary battery positive electrode; as the positive electrode in an alkaline fuel cell; and as the positive electrode in a composite system. MnO2 exhibited redox behaviour when used as the positive electrode in a secondary battery and subjected to charge-discharge cycles. When used as the positive electrode in a fuel cell, with a H2 supply to the negative electrode and an O2 supply to the positive electrode, the current-voltage characteristics were comparable to those obtained using a nickel positive electrode. The cell was capable of producing power when the O2 supply was temporarily interrupted. 18 refs. |
| Author | FUSHIMI, Chihiro LEE, Sunmook TSUTSUMI, Atsushi CHOI, Bokkyu HAMASUNA, Nobuyuki |
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| Keywords | Characterization Manganese oxides Voltage current curve Cathode Manganese dioxide (MnO2),Fuel Cell/Battery (FCB),Fuel cell,Secondary battery Feasibility Electrode material Electric batteries Performance Discharge charge cycle Fuel cell |
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| SubjectTerms | Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Energy Energy. Thermal use of fuels Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc Exact sciences and technology Fuel cells |
| Title | Characterization of MnO2 positive electrode for Fuel Cell/Battery (FCB) |
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