A Segregation and Deprotection Approach for Hydrophilic Surfaces Using Amphiphilic Block Copolymers Possessing Polystyrene and Poly[(tri(ethylene glycol) methacrylate)] Segments
This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous surface segregation of polystyrene‐block‐poly[(tri(ethylene glycol) tert‐butyldimethylsilyl ether methacrylate)] (PS‐b‐PSi3MA) in a polystyrene (P...
Saved in:
| Published in | Macromolecular chemistry and physics Vol. 218; no. 12 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
01.06.2017
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous surface segregation of polystyrene‐block‐poly[(tri(ethylene glycol) tert‐butyldimethylsilyl ether methacrylate)] (PS‐b‐PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. When protected, the tert‐butyl‐terminated hydrophilic PSi3MA blocks segregate at the air or vacuum surface at elevated temperatures. The surface‐segregated structures can be fixed by cooling to room temperature followed by deprotection of the PSi3MA groups to provide surfaces fully covered by unprotected POH3MA, with OH groups on glassy robust PS. Such hydrophilic POH3MA brushes prevent the adsorption of human serum albumin and are expected to be useful in antifouling surfaces.
Spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) are fabricated through spontaneous surface segregation of polystyrene‐block‐poly[(tri(ethylene glycol) tert‐butyldimethylsilyl ether methacrylate)] (PS‐b‐PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. |
|---|---|
| AbstractList | This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous surface segregation of polystyrene‐
block
‐poly[(tri(ethylene glycol)
tert
‐butyldimethylsilyl ether methacrylate)] (PS‐
b
‐PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. When protected, the
tert
‐butyl‐terminated hydrophilic PSi3MA blocks segregate at the air or vacuum surface at elevated temperatures. The surface‐segregated structures can be fixed by cooling to room temperature followed by deprotection of the PSi3MA groups to provide surfaces fully covered by unprotected POH3MA, with OH groups on glassy robust PS. Such hydrophilic POH3MA brushes prevent the adsorption of human serum albumin and are expected to be useful in antifouling surfaces.
image This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous surface segregation of polystyrene-block-poly[(tri(ethylene glycol) tert-butyldimethylsilyl ether methacrylate)] (PS-b-PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. When protected, the tert-butyl-terminated hydrophilic PSi3MA blocks segregate at the air or vacuum surface at elevated temperatures. The surface-segregated structures can be fixed by cooling to room temperature followed by deprotection of the PSi3MA groups to provide surfaces fully covered by unprotected POH3MA, with OH groups on glassy robust PS. Such hydrophilic POH3MA brushes prevent the adsorption of human serum albumin and are expected to be useful in antifouling surfaces. This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous surface segregation of polystyrene‐block‐poly[(tri(ethylene glycol) tert‐butyldimethylsilyl ether methacrylate)] (PS‐b‐PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. When protected, the tert‐butyl‐terminated hydrophilic PSi3MA blocks segregate at the air or vacuum surface at elevated temperatures. The surface‐segregated structures can be fixed by cooling to room temperature followed by deprotection of the PSi3MA groups to provide surfaces fully covered by unprotected POH3MA, with OH groups on glassy robust PS. Such hydrophilic POH3MA brushes prevent the adsorption of human serum albumin and are expected to be useful in antifouling surfaces. Spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) are fabricated through spontaneous surface segregation of polystyrene‐block‐poly[(tri(ethylene glycol) tert‐butyldimethylsilyl ether methacrylate)] (PS‐b‐PSi3MA) in a polystyrene (PS) matrix followed by deprotection of PSi3MA to POH3MA at the PS/water interface. |
| Author | Ishizone, Takashi Oyane, Ayako Yokoyama, Hideaki Seki, Akiko |
| Author_xml | – sequence: 1 givenname: Akiko surname: Seki fullname: Seki, Akiko organization: Tokyo Institute of Technology – sequence: 2 givenname: Takashi surname: Ishizone fullname: Ishizone, Takashi email: tishizon@polymer.titech.ac.jp organization: Tokyo Institute of Technology – sequence: 3 givenname: Ayako surname: Oyane fullname: Oyane, Ayako organization: National Institute of Advanced Industrial Science and Technology – sequence: 4 givenname: Hideaki surname: Yokoyama fullname: Yokoyama, Hideaki email: yokoyama@molle.k.u-tokyo.ac.jp organization: The University of Tokyo |
| BookMark | eNqFUctOwzAQtFCRgMKVsyUu7SHFduI8jqE8ilREJeCEUOQ6mzbFiYOdCuWz-EOcFsGRkz3jmd31zgka1LoGhM4pmVBC2GUlZDNhhEaEkCA-QMeUM-r5ic8H7k4Y86jP2RE6sXbjJDFJomP0leInWBlYibbUNRZ1jq-hMboFuSPSxgEh17jQBs-63OhmXapS4qetKYQEi19sWa9wWjn-5-lKafmOp7rRqqvAWLzQ1oLd6RaOs21noIZdsx6_jlpTjqBdd6qnV6qTWo1x5RghTadEC-O3fswK6taeosNCKAtnP-cQvdzePE9n3vzx7n6azj0ZMD_2glDmTC5D4vOA0NitIfY5535OiwRkwpdREEVxLhMhHYoKCHjIJS0YzXkiluAP0cW-rlvAxxZsm2301tSuZUYTSqLAlQ2darJXSeM-aaDIGlNWwnQZJVkfS9bHkv3G4gzJ3vBZKuj-UWcP6XTx5_0Gf_iW-w |
| CitedBy_id | crossref_primary_10_1016_j_polymer_2020_122257 crossref_primary_10_1021_acsapm_9b00753 crossref_primary_10_1038_s41428_019_0273_5 crossref_primary_10_1093_bulcsj_uoae061 |
| Cites_doi | 10.1126/science.8493529 10.1021/la0258953 10.1021/mz300669q 10.1163/156856202320253910 10.1016/S0958-1669(99)80021-4 10.1021/ma050473w 10.1021/ja991049b 10.1021/ma0521699 10.1016/S0039-6028(01)01548-5 10.1016/S1359-6454(99)00299-2 10.1126/science.8134835 10.1021/ma0347971 10.1016/1054-8807(93)90054-6 10.1007/BF00306584 10.1021/ma702828n 10.1021/ac980764l 10.1016/0021-9797(91)90043-8 10.1021/ma970698 10.1021/la990018r 10.1016/S0079-6700(00)00012-5 10.1007/3-540-16422-7_6 10.1021/ma9519021 10.1021/jp972635z 10.1002/(SICI)1097-4636(200001)49:1<1::AID-JBM1>3.0.CO;2-9 10.1002/macp.1985.021860605 10.1006/jcis.1993.1299 10.1021/ma021257f 10.1146/annurev.ms.26.080196.002053 10.1021/la703934u 10.1038/nbt0695-565 10.1007/3-540-48838-3_1 10.1163/156856200744237 10.1021/ma9818836 10.1002/adma.200500945 10.1055/s-0038-1649474 |
| ContentType | Journal Article |
| Copyright | 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| Copyright_xml | – notice: 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| DBID | AAYXX CITATION 7SR 7U5 8FD JG9 L7M |
| DOI | 10.1002/macp.201700048 |
| DatabaseName | CrossRef Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitleList | CrossRef Materials Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1521-3935 |
| EndPage | n/a |
| ExternalDocumentID | 10_1002_macp_201700048 MACP201700048 |
| Genre | article |
| GrantInformation_xml | – fundername: Grant‐in‐Aids for the Scientific Research funderid: 15H03862; 20550108 |
| GroupedDBID | -~X .3N .GA .Y3 05W 0R~ 10A 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5VS 66C 6P2 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABEML ABIJN ABJNI ABLJU ABPVW ABTAH ACAHQ ACBWZ ACCFJ ACCZN ACGFS ACIWK ACPOU ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEIGN AEIMD AENEX AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFZJQ AHBTC AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BY8 CS3 D-E D-F DCZOG DPXWK DR1 DR2 DRFUL DRSTM DU5 EBS EJD F00 F01 F04 F5P FEDTE G-S G.N GNP GODZA GYXMG H.T H.X HBH HF~ HGLYW HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M6T MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PALCI Q.N Q11 QB0 QRW R.K RIWAO RJQFR RNS ROL RWB RWI RX1 RYL SAMSI SUPJJ TUS UB1 V2E W8V W99 WBKPD WFSAM WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XV2 ZY4 ZZTAW ~IA ~WT AAYXX CITATION 7SR 7U5 8FD JG9 L7M |
| ID | FETCH-LOGICAL-c4238-46cd2cb60354018393835553d1f9ec95b74778dc9acc957fe4565c1f21d59abe3 |
| IEDL.DBID | DR2 |
| ISSN | 1022-1352 |
| IngestDate | Thu Oct 10 18:12:58 EDT 2024 Fri Aug 23 02:06:25 EDT 2024 Sat Aug 24 01:00:03 EDT 2024 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 12 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c4238-46cd2cb60354018393835553d1f9ec95b74778dc9acc957fe4565c1f21d59abe3 |
| OpenAccessLink | https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/macp.201700048 |
| PQID | 1910744016 |
| PQPubID | 2034252 |
| PageCount | 9 |
| ParticipantIDs | proquest_journals_1910744016 crossref_primary_10_1002_macp_201700048 wiley_primary_10_1002_macp_201700048_MACP201700048 |
| PublicationCentury | 2000 |
| PublicationDate | June 2017 |
| PublicationDateYYYYMMDD | 2017-06-01 |
| PublicationDate_xml | – month: 06 year: 2017 text: June 2017 |
| PublicationDecade | 2010 |
| PublicationPlace | Weinheim |
| PublicationPlace_xml | – name: Weinheim |
| PublicationTitle | Macromolecular chemistry and physics |
| PublicationYear | 2017 |
| Publisher | Wiley Subscription Services, Inc |
| Publisher_xml | – name: Wiley Subscription Services, Inc |
| References | 2000; 49 2002; 18 2013; 2 2000; 25 2000; 48 1995; 13 1987; 4 1986; 79 2002; 13 2006; 39 1993; 260 1999; 121 2003; 36 1999; 149 1993; 2 1985; 186 1993; 17A 1991; 142 1982; 28 2000; 16 1990; 24 1993; 70 1997; 30 1994; 263 2000; 11 1999; 110 2002; 500 1999; 10 1999; 32 2008; 24 1998; 70 2008; 41 2005; 38 1998; 102 2005; 17 1996; 26 1993; 159 e_1_2_7_6_1 e_1_2_7_5_1 e_1_2_7_4_1 Sukhishvili S. A. (e_1_2_7_18_1) 1999; 110 e_1_2_7_3_1 Luscher E. F. (e_1_2_7_12_1) 1993; 70 e_1_2_7_8_1 e_1_2_7_7_1 e_1_2_7_17_1 e_1_2_7_40_1 e_1_2_7_2_1 e_1_2_7_15_1 e_1_2_7_1_1 e_1_2_7_14_1 Wang N. H. L. (e_1_2_7_16_1) 1993; 17 e_1_2_7_13_1 e_1_2_7_11_1 e_1_2_7_10_1 e_1_2_7_26_1 e_1_2_7_27_1 e_1_2_7_28_1 e_1_2_7_29_1 Williams D. F. (e_1_2_7_9_1) 1987 Mori Y. (e_1_2_7_20_1) 1982; 28 e_1_2_7_30_1 e_1_2_7_25_1 e_1_2_7_31_1 e_1_2_7_24_1 e_1_2_7_32_1 e_1_2_7_23_1 e_1_2_7_33_1 e_1_2_7_22_1 e_1_2_7_34_1 e_1_2_7_21_1 e_1_2_7_35_1 e_1_2_7_36_1 e_1_2_7_37_1 e_1_2_7_38_1 e_1_2_7_39_1 Ratner B. D. (e_1_2_7_19_1) 2000; 11 |
| References_xml | – volume: 13 start-page: 565 year: 1995 publication-title: Bio/Technology – volume: 30 start-page: 6947 year: 1997 publication-title: Macromolecules – volume: 2 start-page: 265 year: 2013 publication-title: ACS Macro Lett. – volume: 70 start-page: 5111 year: 1998 publication-title: Anal. Chem. – volume: 11 start-page: 110719 year: 2000 publication-title: J. Biomater. Sci. Polym. Ed. – volume: 25 start-page: 677 year: 2000 publication-title: J. Prog. Polym. Sci. – volume: 2 start-page: 137 year: 1993 publication-title: Cardiovasc. Pathol. – volume: 260 start-page: 920 year: 1993 publication-title: Science – volume: 49 start-page: 1 year: 2000 publication-title: J. Biomed. Mater. Res. – volume: 500 start-page: 61 year: 2002 publication-title: Surf. Sci. – volume: 17A start-page: 43 year: 1993 publication-title: J. Cell. Biochem. – volume: 186 start-page: 1157 year: 1985 publication-title: Makromol. Chem. – volume: 149 start-page: 1 year: 1999 publication-title: Adv. Polym. Sci. – volume: 79 start-page: 1 year: 1986 publication-title: Adv. Polym. Sci. – volume: 41 start-page: 2963 year: 2008 publication-title: Macromolecules – volume: 39 start-page: 962 year: 2006 publication-title: Macromolecules – volume: 24 start-page: 5527 year: 2008 publication-title: Langmuir – volume: 121 start-page: 10134 year: 1999 publication-title: J. Am. Chem. Soc. – volume: 142 start-page: 149 year: 1991 publication-title: J. Colloid Interface Sci. – volume: 28 start-page: 459 year: 1982 publication-title: Trans. ASAIO – volume: 26 start-page: 365 year: 1996 publication-title: Annu. Rev. Mater. Sci. – volume: 36 start-page: 8312 year: 2003 publication-title: Macromolecules – volume: 110 start-page: 10153 year: 1999 publication-title: Chem. Phys. – volume: 11 start-page: 1135 year: 2000 publication-title: J. Biomater. Sci., Polym. Ed. – volume: 159 start-page: 77 year: 1993 publication-title: J. Colloid Interface Sci. – volume: 16 start-page: 1793 year: 2000 publication-title: Langmuir – volume: 4 year: 1987 – volume: 36 start-page: 42 year: 2003 publication-title: Macromolecules – volume: 18 start-page: 8862 year: 2002 publication-title: Langmuir – volume: 70 start-page: 234 year: 1993 publication-title: Thromb. Haemostasis – volume: 102 start-page: 426 year: 1998 publication-title: J. Phys. Chem. B – volume: 263 start-page: 1715 year: 1994 publication-title: Science – volume: 30 start-page: 3051 year: 1997 publication-title: Macromolecules – volume: 48 start-page: 263 year: 2000 publication-title: Acta Mater. – volume: 32 start-page: 6298 year: 1999 publication-title: Macromolecules – volume: 24 start-page: 333 year: 1990 publication-title: Polym. Bull. – volume: 17 start-page: 2329 year: 2005 publication-title: Adv. Mater. – volume: 10 start-page: 123 year: 1999 publication-title: Curr. Opin. Biotechnol. – volume: 13 start-page: 367 year: 2002 publication-title: J. Biomater. Sci., Polym. Ed. – volume: 38 start-page: 5180 year: 2005 publication-title: Macromolecules – ident: e_1_2_7_5_1 doi: 10.1126/science.8493529 – ident: e_1_2_7_23_1 doi: 10.1021/la0258953 – ident: e_1_2_7_30_1 doi: 10.1021/mz300669q – ident: e_1_2_7_21_1 doi: 10.1163/156856202320253910 – ident: e_1_2_7_6_1 doi: 10.1016/S0958-1669(99)80021-4 – ident: e_1_2_7_33_1 doi: 10.1021/ma050473w – ident: e_1_2_7_24_1 doi: 10.1021/ja991049b – ident: e_1_2_7_34_1 doi: 10.1021/ma0521699 – ident: e_1_2_7_1_1 doi: 10.1016/S0039-6028(01)01548-5 – ident: e_1_2_7_4_1 doi: 10.1016/S1359-6454(99)00299-2 – volume: 28 start-page: 459 year: 1982 ident: e_1_2_7_20_1 publication-title: Trans. ASAIO contributor: fullname: Mori Y. – ident: e_1_2_7_8_1 doi: 10.1126/science.8134835 – ident: e_1_2_7_35_1 doi: 10.1021/ma0347971 – ident: e_1_2_7_11_1 doi: 10.1016/1054-8807(93)90054-6 – ident: e_1_2_7_31_1 doi: 10.1007/BF00306584 – volume: 110 start-page: 10153 year: 1999 ident: e_1_2_7_18_1 publication-title: Chem. Phys. contributor: fullname: Sukhishvili S. A. – volume-title: Definitions in Biomaterials: Progress in Biomedical Engineering year: 1987 ident: e_1_2_7_9_1 contributor: fullname: Williams D. F. – ident: e_1_2_7_36_1 doi: 10.1021/ma702828n – ident: e_1_2_7_14_1 doi: 10.1021/ac980764l – ident: e_1_2_7_25_1 doi: 10.1016/0021-9797(91)90043-8 – ident: e_1_2_7_32_1 doi: 10.1021/ma970698 – ident: e_1_2_7_17_1 doi: 10.1021/la990018r – ident: e_1_2_7_26_1 doi: 10.1016/S0079-6700(00)00012-5 – ident: e_1_2_7_10_1 doi: 10.1007/3-540-16422-7_6 – ident: e_1_2_7_29_1 doi: 10.1021/ma9519021 – ident: e_1_2_7_22_1 doi: 10.1021/jp972635z – ident: e_1_2_7_15_1 doi: 10.1002/(SICI)1097-4636(200001)49:1<1::AID-JBM1>3.0.CO;2-9 – volume: 17 start-page: 43 year: 1993 ident: e_1_2_7_16_1 publication-title: J. Cell. Biochem. contributor: fullname: Wang N. H. L. – volume: 11 start-page: 110719 year: 2000 ident: e_1_2_7_19_1 publication-title: J. Biomater. Sci. Polym. Ed. contributor: fullname: Ratner B. D. – ident: e_1_2_7_40_1 doi: 10.1002/macp.1985.021860605 – ident: e_1_2_7_28_1 doi: 10.1006/jcis.1993.1299 – ident: e_1_2_7_39_1 doi: 10.1021/ma021257f – ident: e_1_2_7_2_1 doi: 10.1146/annurev.ms.26.080196.002053 – ident: e_1_2_7_37_1 doi: 10.1021/la703934u – ident: e_1_2_7_7_1 doi: 10.1038/nbt0695-565 – ident: e_1_2_7_3_1 doi: 10.1007/3-540-48838-3_1 – ident: e_1_2_7_13_1 doi: 10.1163/156856200744237 – ident: e_1_2_7_27_1 doi: 10.1021/ma9818836 – ident: e_1_2_7_38_1 doi: 10.1002/adma.200500945 – volume: 70 start-page: 234 year: 1993 ident: e_1_2_7_12_1 publication-title: Thromb. Haemostasis doi: 10.1055/s-0038-1649474 contributor: fullname: Luscher E. F. |
| SSID | ssj0008097 |
| Score | 2.2497056 |
| Snippet | This paper fabricates spontaneously formed hydrophilic polymer brushes composed of poly[(tri(ethylene glycol) methacrylate)] (POH3MA) through spontaneous... |
| SourceID | proquest crossref wiley |
| SourceType | Aggregation Database Publisher |
| SubjectTerms | Adsorption anionic polymerization Antifouling block copolymer Block copolymers Brushes Chemical industry Cooling Ethylene glycol Polystyrene resins Robustness Segments Serum albumin Surface chemistry surface segregation |
| Title | A Segregation and Deprotection Approach for Hydrophilic Surfaces Using Amphiphilic Block Copolymers Possessing Polystyrene and Poly[(tri(ethylene glycol) methacrylate)] Segments |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fmacp.201700048 https://www.proquest.com/docview/1910744016 |
| Volume | 218 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3dS8MwEA_ii774Lc4v8iDoHqr9XvdYpzIEZTgFQaSkl2QMZyfd9jD_K_9D79J2U18EfWvSpE25S_K76-V3jB25CJKFctA2Qbxr-RCGloi0thyQEm0xz9eGXf_mNmw_-NePweOXU_wFP8TM4UYzw6zXNMFFOjqbk4a-CiC-SeKXQy3ERdjxGhTTdXE354-K7CK7CoWsOwg1KtZG2z373v37rjSHml8Bq9lxrlaZqMZaBJq8nE7G6Sm8_6Bx_M_HrLGVEo7yuNCfdbagsg221KqywG2yj5h3FdrkPSNBLjLJL1RJ7kAVcclJzhH88vZU5sM3ctEA705yTeFe3AQl8Bi1pl_eOscN9IW3KD3DlNzmvDM0v56pXQfrRuQZz5R5GZWfTsZ5_0ShSg2oujeYovbWOSW_FpBPBwiX6880THNcb4s9XF3et9pWmebBAsRykeWHIF1IQ5tcUATY0GgOgsCTjm4qaAYpWjyNSEJTAJYaWhEIBUe7jgyaIlXeNlvMhpnaYTyyI4mAVUvQ4AcNmXoaRIDtQhtw4fJr7LgSc_JWsHkkBW-zm5AIkpkIamy_0oKknNWjBG1bmwgVnbDGXCPOX56S3MStzqy0-5dOe2yZrovotH22OM4n6gBx0Dg9NLr-CfFVAuw |
| link.rule.ids | 315,783,787,1378,27938,27939,46308,46732 |
| linkProvider | Wiley-Blackwell |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT9tAEB5RONALz1aE5x6QgIPB7zhHE0BpS1BUQKqEkGXP7iJEcJBJDuFf8Q-ZWdsJ9ILUHne8a681s95vxrPfAOy6BJJT5ZBvQnjX8jEMrTTS2nJQSvLFPF8bdv3uRdi59n_-CepsQj4LU_JDTAJuvDLM95oXOAekj6asoY8pMuEkE8yRGX6BOVrzHhcxOPk9ZZCK7LK-CietOwQ2at5G2z36OP7jvjQFm-8hq9lzzhYhq2dbppo8HI6G2SG-_EXk-F-vswQLFSIVcWlCyzCj8hWYb9eF4FbhNRaXitzyO6NEkeZSnKiK34EFcUVLLgj_is5YFoMnjtKguBwVmjO-hMlLEDEZzn116Zj20AfR5goNY46ci97A_H3mfj2SPXNwPFfmYdy-2R8W9_uKrKrP4rv-mAz4QHD96xSLcZ8Q88EtT9Oc2PsG12enV-2OVVV6sJDgXGT5IUoXs9DmKBRjNvKbgyDwpKNbCltBRk5PM5LYSpFaTa0Yh6KjXUcGrTRT3neYzQe5WgMR2ZEkzKolavSDpsw8jWlA_UIb6dvlN2Cv1nPyVBJ6JCV1s5uwCpKJChqwWZtBUi3s54TcW5s5FZ2wAa7R5yd3Sbpxuzdprf_LoB2Y71x1z5PzHxe_NuAry8tktU2YHRYjtUWwaJhtG8N_AxDdBwY |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LT9tAEB61VKK9QEtbNZSWPSABB4PfcY4maRTagiIeElJVWevZXYRIncgkh_Rf8Q-ZWdsJ9FKpPe54115rZr3fjGe_AdjxCSRL7ZFvQnjXCTGOHZkY43ioFPliQWgsu_7JaTy4DL9eRVePTvFX_BCLgBuvDPu95gU-UeZwSRr6SyLzTTK_HFnhc3gRxoHLSV29syWBVOJW5VU4Z90jrNHQNrr-4dPxT7elJdZ8jFjtltNfB9lMtso0uT2YTfMD_P0Hj-P_vM1rWKvxqEgrA3oDz3SxAS-7TRm4t3CfinNNTvm1VaGQhRI9XbM7sCCtSckFoV8xmKtyPOEYDYrzWWk430vYrASRktnc1JeOaAe9FV2uzzDnuLkYju2_Z-43JNkdh8YLbR_G7R970_JmT5NNjVh8PZqT-e4Lrn4tsZyPCC_v_-Rp2vN67-Cy_-WiO3DqOg8OEphLnDBG5WMeuxyDYsRGXnMURYHyTEdjJ8rJ5WknCjsSqdU2mlEoesb3VNSRuQ7ew0oxLvQHEImbKEKsRqHBMGqrPDAoI-oXu0hfrrAFu42as0lF55FVxM1-xirIFipowVZjBVm9rO8ycm5dZlT04hb4Vp1_uUt2knaHi9bmvwzahtVhr599Pz799hFesbjKVNuClWk5058IE03zz9bsHwD7LQW1 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+Segregation+and+Deprotection+Approach+for+Hydrophilic+Surfaces+Using+Amphiphilic+Block+Copolymers+Possessing+Polystyrene+and+Poly%5B%28tri%28ethylene+glycol%29+methacrylate%29%5D+Segments&rft.jtitle=Macromolecular+chemistry+and+physics&rft.au=Seki%2C+Akiko&rft.au=Ishizone%2C+Takashi&rft.au=Oyane%2C+Ayako&rft.au=Yokoyama%2C+Hideaki&rft.date=2017-06-01&rft.pub=Wiley+Subscription+Services%2C+Inc&rft.issn=1022-1352&rft.eissn=1521-3935&rft.volume=218&rft.issue=12&rft_id=info:doi/10.1002%2Fmacp.201700048&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1022-1352&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1022-1352&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1022-1352&client=summon |