Successful UV‐Induced RICFP of Epoxy‐Composites

The UV‐curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in cationic photopolymerization of epoxy monomers has been recently overcome by introducing a novel radical induced cationic frontal polymerizatio...

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Published inMacromolecular chemistry and physics Vol. 218; no. 18
Main Authors Klikovits, Nicolas, Liska, Robert, D'Anna, Alessandra, Sangermano, Marco
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 01.09.2017
Subjects
Bisphenol A
bisphenol‐A diglycidyl ether
Cationic polymerization
Composite materials
epoxy composites
Film thickness
Formulations
Mechanical properties
Monomers
Photopolymerization
Polymer matrix composites
Polymerization
Propagation (polymerization)
radical induced cationic frontal polymerization
silica nanopowder
Silicon dioxide
Thermal analysis
UV‐curing
Online AccessGet full text
ISSN1022-1352
1521-3935
DOI10.1002/macp.201700313

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Abstract The UV‐curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in cationic photopolymerization of epoxy monomers has been recently overcome by introducing a novel radical induced cationic frontal polymerization (RICFP) system within this research group. The possibility to cure epoxides in bulk by UV‐light promoted here presents the novel approach to photocured composites. In the present work, the recently established RICFP system is applied on SiO2‐filled epoxy formulations based on bisphenol‐A diglycidyl ether. The influence of filler content on frontal propagation is examined in RICFP experiments. The composite materials are also investigated by dynamic mechanical thermal analysis to determine mechanical properties of the frontally polymerized products. UV‐cured bulk epoxy composites are successfully produced by bubble‐free radical induced cationic frontal polymerization (RICFP) and investigated regarding the frontal polymerization behavior. SiO2 nanopowder is used as filler to demonstrate the limits of heat‐insulating materials for RICFP composites.
AbstractList The UV‐curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in cationic photopolymerization of epoxy monomers has been recently overcome by introducing a novel radical induced cationic frontal polymerization (RICFP) system within this research group. The possibility to cure epoxides in bulk by UV‐light promoted here presents the novel approach to photocured composites. In the present work, the recently established RICFP system is applied on SiO2‐filled epoxy formulations based on bisphenol‐A diglycidyl ether. The influence of filler content on frontal propagation is examined in RICFP experiments. The composite materials are also investigated by dynamic mechanical thermal analysis to determine mechanical properties of the frontally polymerized products. UV‐cured bulk epoxy composites are successfully produced by bubble‐free radical induced cationic frontal polymerization (RICFP) and investigated regarding the frontal polymerization behavior. SiO2 nanopowder is used as filler to demonstrate the limits of heat‐insulating materials for RICFP composites.
The UV‐curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in cationic photopolymerization of epoxy monomers has been recently overcome by introducing a novel radical induced cationic frontal polymerization (RICFP) system within this research group. The possibility to cure epoxides in bulk by UV‐light promoted here presents the novel approach to photocured composites. In the present work, the recently established RICFP system is applied on SiO 2 ‐filled epoxy formulations based on bisphenol‐A diglycidyl ether. The influence of filler content on frontal propagation is examined in RICFP experiments. The composite materials are also investigated by dynamic mechanical thermal analysis to determine mechanical properties of the frontally polymerized products.
The UV-curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in cationic photopolymerization of epoxy monomers has been recently overcome by introducing a novel radical induced cationic frontal polymerization (RICFP) system within this research group. The possibility to cure epoxides in bulk by UV-light promoted here presents the novel approach to photocured composites. In the present work, the recently established RICFP system is applied on SiO2-filled epoxy formulations based on bisphenol-A diglycidyl ether. The influence of filler content on frontal propagation is examined in RICFP experiments. The composite materials are also investigated by dynamic mechanical thermal analysis to determine mechanical properties of the frontally polymerized products.
Author Liska, Robert
D'Anna, Alessandra
Sangermano, Marco
Klikovits, Nicolas
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  fullname: D'Anna, Alessandra
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  fullname: Sangermano, Marco
  email: marco.sangermano@polito.it
  organization: Politecnico di Torino
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Snippet The UV‐curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in...
The UV-curing of epoxy monomers by cationic photopolymerization is a powerful method for the production of polymer materials. The limit of film thickness in...
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SubjectTerms Bisphenol A
bisphenol‐A diglycidyl ether
Cationic polymerization
Composite materials
epoxy composites
Film thickness
Formulations
Mechanical properties
Monomers
Photopolymerization
Polymer matrix composites
Polymerization
Propagation (polymerization)
radical induced cationic frontal polymerization
silica nanopowder
Silicon dioxide
Thermal analysis
UV‐curing
Title Successful UV‐Induced RICFP of Epoxy‐Composites
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fmacp.201700313
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