A 3D bi-functional porous N-doped carbon microtube sponge electrocatalyst for oxygen reduction and oxygen evolution reactions

A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial cotton. Due to its unique structure with a micron-scale hollow core and well-graphitized and interconnected porous walls, the NCMT sponge exhibit...

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Published inEnergy & environmental science Vol. 9; no. 1; pp. 379 - 384
Main Authors Li, Jin-Cheng, Hou, Peng-Xiang, Zhao, Shi-Yong, Liu, Chang, Tang, Dai-Ming, Cheng, Min, Zhang, Feng, Cheng, Hui-Ming
Format Journal Article
LanguageEnglish
Published 01.01.2016
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Abstract A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial cotton. Due to its unique structure with a micron-scale hollow core and well-graphitized and interconnected porous walls, the NCMT sponge exhibits incomparable electrocatalytic activity for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) with a small potential difference of 0.63 V between the OER current density at 10 mA cm −2 and the ORR current density at −3 mA cm −2 , which is the best to date. A flexible, dictyophora-like sponge of porous N-doped carbon microtubes demonstrates excellent electrocatalytic activities for both the oxygen reduction reaction and oxygen evolution reaction.
AbstractList A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial cotton. Due to its unique structure with a micron-scale hollow core and well-graphitized and interconnected porous walls, the NCMT sponge exhibits incomparable electrocatalytic activity for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) with a small potential difference of 0.63 V between the OER current density at 10 mA cm −2 and the ORR current density at −3 mA cm −2 , which is the best to date.
A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial cotton. Due to its unique structure with a micron-scale hollow core and well-graphitized and interconnected porous walls, the NCMT sponge exhibits incomparable electrocatalytic activity for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) with a small potential difference of 0.63 V between the OER current density at 10 mA cm-2 and the ORR current density at -3 mA cm-2, which is the best to date.
A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial cotton. Due to its unique structure with a micron-scale hollow core and well-graphitized and interconnected porous walls, the NCMT sponge exhibits incomparable electrocatalytic activity for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) with a small potential difference of 0.63 V between the OER current density at 10 mA cm −2 and the ORR current density at −3 mA cm −2 , which is the best to date. A flexible, dictyophora-like sponge of porous N-doped carbon microtubes demonstrates excellent electrocatalytic activities for both the oxygen reduction reaction and oxygen evolution reaction.
Author Li, Jin-Cheng
Cheng, Hui-Ming
Hou, Peng-Xiang
Tang, Dai-Ming
Zhao, Shi-Yong
Cheng, Min
Liu, Chang
Zhang, Feng
AuthorAffiliation Shenyang National Laboratory for Materials Science
Institute of Metal Research
Chinese Academy of Sciences
AuthorAffiliation_xml – sequence: 0
  name: Shenyang National Laboratory for Materials Science
– sequence: 0
  name: Institute of Metal Research
– sequence: 0
  name: Chinese Academy of Sciences
Author_xml – sequence: 1
  givenname: Jin-Cheng
  surname: Li
  fullname: Li, Jin-Cheng
– sequence: 2
  givenname: Peng-Xiang
  surname: Hou
  fullname: Hou, Peng-Xiang
– sequence: 3
  givenname: Shi-Yong
  surname: Zhao
  fullname: Zhao, Shi-Yong
– sequence: 4
  givenname: Chang
  surname: Liu
  fullname: Liu, Chang
– sequence: 5
  givenname: Dai-Ming
  surname: Tang
  fullname: Tang, Dai-Ming
– sequence: 6
  givenname: Min
  surname: Cheng
  fullname: Cheng, Min
– sequence: 7
  givenname: Feng
  surname: Zhang
  fullname: Zhang, Feng
– sequence: 8
  givenname: Hui-Ming
  surname: Cheng
  fullname: Cheng, Hui-Ming
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Notes Electronic supplementary information (ESI) available. See DOI
10.1039/c6ee02169g
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Liang (C6EE02169G-(cit14)/*[position()=1]) 2013; 25
Ma (C6EE02169G-(cit34)/*[position()=1]) 2015; 54
Chen (C6EE02169G-(cit9)/*[position()=1]) 2012; 24
Wen (C6EE02169G-(cit33)/*[position()=1]) 2014; 53
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Yu (C6EE02169G-(cit19)/*[position()=1]) 2015; 206
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Snippet A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial...
A flexible, large-area three-dimensional porous N-doped carbon microtube (NCMT) sponge was prepared via a simple and low-cost process of pyrolyzing facial...
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SubjectTerms Carbon
Current density
Electrocatalysts
Evolution
Oxygen
Porous walls
Reduction
Sponges
Title A 3D bi-functional porous N-doped carbon microtube sponge electrocatalyst for oxygen reduction and oxygen evolution reactions
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