Heteroatom Doping: An Effective Way to Boost Sodium Ion Storage

In response to the change of energy landscape, sodium‐ion batteries (SIBs) are becoming one of the most promising power sources for the post‐lithium‐ion battery (LIB) era due to the cheap and abundant nature of sodium, and similar electrochemical properties to LIBs. The electrochemical performance o...

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Published inAdvanced energy materials Vol. 10; no. 27
Main Authors Li, Yu, Chen, Minghua, Liu, Bo, Zhang, Yan, Liang, Xinqi, Xia, Xinhui
Format Journal Article
LanguageEnglish
Published Weinheim Wiley Subscription Services, Inc 01.07.2020
Subjects
Aluminum
anodes
Boron
cathodes
Crystal structure
Doping
Electrochemical analysis
Electrode materials
Electrodes
Energy storage
Fluorine
heteroatoms
Ion storage
Lithium-ion batteries
Magnesium
Nitrogen
Power management
Power sources
Reaction kinetics
Rechargeable batteries
Sodium
Sodium-ion batteries
Storage batteries
Titanium
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Abstract In response to the change of energy landscape, sodium‐ion batteries (SIBs) are becoming one of the most promising power sources for the post‐lithium‐ion battery (LIB) era due to the cheap and abundant nature of sodium, and similar electrochemical properties to LIBs. The electrochemical performance of electrode materials for SIBs is closely bound up with their crystal structures and intrinsic electronic/ionic states. Apart from nanoscale design and conductive composite strategies, heteroatom doping is another effective way to enhance the intrinsic transfer characteristics of sodium ions and electrons in crystal structures to accelerate reaction kinetics and thereby achieve high performance. In this review, the recent advancements in heteroatom doping for sodium ion storage of electrode materials are reviewed. Specifically, different doping strategies including nonmetal element doping (e.g., nitrogen, sulfur, phosphorous, boron, fluorine), metal element doping (magnesium, titanium, iron, aluminum, nickel, copper, etc.), and dual/triple doping (such as N–S, N–P, N–S–P) are reviewed and summarized in detail. Furthermore, various doping methods are introduced and their advantages and disadvantages are discussed. The doping effect on crystal structure and intrinsic electronic/ionic state are illustrated and the relationship with capacity and energy/power density is interrogated. Finally, future development trends in doping strategies for advanced SIBs electrodes are analyzed. Heteroatom doping is an effective way to enhance the intrinsic transfer characteristics of sodium ions and electrons in crystal structures to accelerate reaction kinetics. Herein, an overview of recent advancements in understanding the heteroatom doping effect on sodium ion storage is presented. Different doping strategies are reviewed and summarized in detail. Future development trends in doping strategies are analyzed.
AbstractList In response to the change of energy landscape, sodium‐ion batteries (SIBs) are becoming one of the most promising power sources for the post‐lithium‐ion battery (LIB) era due to the cheap and abundant nature of sodium, and similar electrochemical properties to LIBs. The electrochemical performance of electrode materials for SIBs is closely bound up with their crystal structures and intrinsic electronic/ionic states. Apart from nanoscale design and conductive composite strategies, heteroatom doping is another effective way to enhance the intrinsic transfer characteristics of sodium ions and electrons in crystal structures to accelerate reaction kinetics and thereby achieve high performance. In this review, the recent advancements in heteroatom doping for sodium ion storage of electrode materials are reviewed. Specifically, different doping strategies including nonmetal element doping (e.g., nitrogen, sulfur, phosphorous, boron, fluorine), metal element doping (magnesium, titanium, iron, aluminum, nickel, copper, etc.), and dual/triple doping (such as N–S, N–P, N–S–P) are reviewed and summarized in detail. Furthermore, various doping methods are introduced and their advantages and disadvantages are discussed. The doping effect on crystal structure and intrinsic electronic/ionic state are illustrated and the relationship with capacity and energy/power density is interrogated. Finally, future development trends in doping strategies for advanced SIBs electrodes are analyzed.
In response to the change of energy landscape, sodium‐ion batteries (SIBs) are becoming one of the most promising power sources for the post‐lithium‐ion battery (LIB) era due to the cheap and abundant nature of sodium, and similar electrochemical properties to LIBs. The electrochemical performance of electrode materials for SIBs is closely bound up with their crystal structures and intrinsic electronic/ionic states. Apart from nanoscale design and conductive composite strategies, heteroatom doping is another effective way to enhance the intrinsic transfer characteristics of sodium ions and electrons in crystal structures to accelerate reaction kinetics and thereby achieve high performance. In this review, the recent advancements in heteroatom doping for sodium ion storage of electrode materials are reviewed. Specifically, different doping strategies including nonmetal element doping (e.g., nitrogen, sulfur, phosphorous, boron, fluorine), metal element doping (magnesium, titanium, iron, aluminum, nickel, copper, etc.), and dual/triple doping (such as N–S, N–P, N–S–P) are reviewed and summarized in detail. Furthermore, various doping methods are introduced and their advantages and disadvantages are discussed. The doping effect on crystal structure and intrinsic electronic/ionic state are illustrated and the relationship with capacity and energy/power density is interrogated. Finally, future development trends in doping strategies for advanced SIBs electrodes are analyzed. Heteroatom doping is an effective way to enhance the intrinsic transfer characteristics of sodium ions and electrons in crystal structures to accelerate reaction kinetics. Herein, an overview of recent advancements in understanding the heteroatom doping effect on sodium ion storage is presented. Different doping strategies are reviewed and summarized in detail. Future development trends in doping strategies are analyzed.
Author Xia, Xinhui
Li, Yu
Liang, Xinqi
Liu, Bo
Zhang, Yan
Chen, Minghua
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– sequence: 2
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  surname: Zhang
  fullname: Zhang, Yan
  organization: Zhejiang University
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  givenname: Xinqi
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  organization: Harbin University of Science and Technology
– sequence: 6
  givenname: Xinhui
  orcidid: 0000-0002-5976-5337
  surname: Xia
  fullname: Xia, Xinhui
  email: helloxxh@zju.edu.cn
  organization: Zhejiang University
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2020; 380
2016; 10
2017; 370
2020; 265
2016; 16
2016; 12
2016; 11
2016; 4
2018; 230
2016; 6
2016; 3
2020; 31
2016; 219
2019; 45
2020; 28
2019; 850
2015; 119
2016; 216
2016; 336
2016; 213
2016; 28
2019; 295
2016; 27
2016; 8
2016; 9
2020; 29
2019; 55
2016; 107
2018; 404
2019; 54
2017; 43
2016; 220
2008; 5
2017; 356
2017; 116
2020; 8
2020; 7
2017; 31
2019; 60
2014; 4
2015; 170
2020; 2
2014; 2
2017; 34
2017; 120
2014; 9
2017; 123
2017; 244
2014; 7
2014; 6
2014; 53
2015; 2
2015; 160
2019; 1900223
2015; 5
2015; 4
2015; 3
2017; 27
2020; 461
2015; 94
2019; 309
2015; 286
2017; 23
2019; 303
2019; 784
2019; 422
2018; 63
2017; 29
2014; 85
2015; 8
2015; 7
2000; 147
2020
2017; 10
2017; 13
2009; 9
2019; 779
2020; 67
2017; 342
2018; 54
2009; 1
2017; 223
2017; 224
2018; 57
2018; 165
2013; 3
2019; 93
2018; 281
2013; 1
2018; 282
2014; 26
2020; 448
2020; 562
2018; 45
2018; 44
2013; 6
2014; 23
2020; 449
2018; 48
2018; 6
2018; 177
2018; 8
2018; 292
2018; 5
2014; 16
2019; 795
2018; 30
2015; 91
2006; 160
2019; 790
2018; 31
2019; 794
2019; 7
2018; 29
2019; 9
2018; 28
2019; 3
2019; 6
2018; 743
2015; 51
2019; 1
2014; 272
2019; 464
2014; 43
2016; 99
2019; 333
2018; 12
2018; 11
2018; 10
2018; 14
2016; 172
2018; 13
2017; 5
2017; 7
2017; 8
2017; 1
2017; 4
2016; 76
2016; 73
2017; 198
2017; 9
2019; 364
2018; 130
2018; 375
2018; 139
2018; 378
2011; 21
2013; 273
2016; 191
2015; 15
2014; 116
2015; 17
2018; 140
2008; 18
2009; 131
2014; 114
2016; 55
2018; 273
2015; 25
2017; 96
2012; 2
2015; 27
2018; 277
2018; 279
2011; 47
2017; 188
2012; 6
1998; 102
2012; 5
2019; 496
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Snippet In response to the change of energy landscape, sodium‐ion batteries (SIBs) are becoming one of the most promising power sources for the post‐lithium‐ion...
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SubjectTerms Aluminum
anodes
Boron
cathodes
Crystal structure
Doping
Electrochemical analysis
Electrode materials
Electrodes
Energy storage
Fluorine
heteroatoms
Ion storage
Lithium-ion batteries
Magnesium
Nitrogen
Power management
Power sources
Reaction kinetics
Rechargeable batteries
Sodium
Sodium-ion batteries
Storage batteries
Titanium
Title Heteroatom Doping: An Effective Way to Boost Sodium Ion Storage
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Faenm.202000927
https://www.proquest.com/docview/2425493864
Volume 10
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