Conductive Copper Niobate: Superior Li+‐Storage Capability and Novel Li+‐Transport Mechanism
Niobates with shear ReO3 crystal structures are remarkably promising anode materials for Li+ batteries due to their large capacities, inherent safety, and high cycling stability. However, they generally suffer from limited rate capabilities rooted in their insufficient electronic and Li+ conductivit...
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| Published in | Advanced energy materials Vol. 9; no. 39 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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01.10.2019
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| Abstract | Niobates with shear ReO3 crystal structures are remarkably promising anode materials for Li+ batteries due to their large capacities, inherent safety, and high cycling stability. However, they generally suffer from limited rate capabilities rooted in their insufficient electronic and Li+ conductivities. Here, micrometer‐sized copper niobate (Cu2Nb34O87) bulk as a new anode material having a high electronic conductivity of 2.1 × 10−5 S cm−1 and an impressive average Li+ diffusion coefficient of ≈3.5 × 10−13 cm2 s−1 is exploited, which synergistically leads to an excellent rate capability (184 mAh g−1 at 10 C) while remaining a large reversible capacity and superior cycling stability. Moreover, the fast Li+ transport pathways of grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale) are demonstrated in Cu2Nb34O87. Therefore, these results could pave the way for practical application of Cu2Nb34O87 in high‐performance Li+ batteries.
Microsized Copper Niobate having a high electronic conductivity and an impressive average Li+ diffusion coefficient is fabricated via a conventional solid‐state reaction, which exhibits superior electrochemical performance as an anode material. Research on the Li+ transport reveals the fast Li+ transport pathways of the grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale). |
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| AbstractList | Niobates with shear ReO3 crystal structures are remarkably promising anode materials for Li+ batteries due to their large capacities, inherent safety, and high cycling stability. However, they generally suffer from limited rate capabilities rooted in their insufficient electronic and Li+ conductivities. Here, micrometer‐sized copper niobate (Cu2Nb34O87) bulk as a new anode material having a high electronic conductivity of 2.1 × 10−5 S cm−1 and an impressive average Li+ diffusion coefficient of ≈3.5 × 10−13 cm2 s−1 is exploited, which synergistically leads to an excellent rate capability (184 mAh g−1 at 10 C) while remaining a large reversible capacity and superior cycling stability. Moreover, the fast Li+ transport pathways of grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale) are demonstrated in Cu2Nb34O87. Therefore, these results could pave the way for practical application of Cu2Nb34O87 in high‐performance Li+ batteries.
Microsized Copper Niobate having a high electronic conductivity and an impressive average Li+ diffusion coefficient is fabricated via a conventional solid‐state reaction, which exhibits superior electrochemical performance as an anode material. Research on the Li+ transport reveals the fast Li+ transport pathways of the grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale). Niobates with shear ReO 3 crystal structures are remarkably promising anode materials for Li + batteries due to their large capacities, inherent safety, and high cycling stability. However, they generally suffer from limited rate capabilities rooted in their insufficient electronic and Li + conductivities. Here, micrometer‐sized copper niobate (Cu 2 Nb 34 O 87 ) bulk as a new anode material having a high electronic conductivity of 2.1 × 10 −5 S cm −1 and an impressive average Li + diffusion coefficient of ≈3.5 × 10 −13 cm 2 s −1 is exploited, which synergistically leads to an excellent rate capability (184 mAh g −1 at 10 C) while remaining a large reversible capacity and superior cycling stability. Moreover, the fast Li + transport pathways of grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale) are demonstrated in Cu 2 Nb 34 O 87 . Therefore, these results could pave the way for practical application of Cu 2 Nb 34 O 87 in high‐performance Li + batteries. Niobates with shear ReO3 crystal structures are remarkably promising anode materials for Li+ batteries due to their large capacities, inherent safety, and high cycling stability. However, they generally suffer from limited rate capabilities rooted in their insufficient electronic and Li+ conductivities. Here, micrometer‐sized copper niobate (Cu2Nb34O87) bulk as a new anode material having a high electronic conductivity of 2.1 × 10−5 S cm−1 and an impressive average Li+ diffusion coefficient of ≈3.5 × 10−13 cm2 s−1 is exploited, which synergistically leads to an excellent rate capability (184 mAh g−1 at 10 C) while remaining a large reversible capacity and superior cycling stability. Moreover, the fast Li+ transport pathways of grain boundary (micrometer scale) → lattice deformation area (nanometer scale) → (010) crystallographic plane (angstrom scale) are demonstrated in Cu2Nb34O87. Therefore, these results could pave the way for practical application of Cu2Nb34O87 in high‐performance Li+ batteries. |
| Author | Zhao, Xuebing Che, Renchao Li, Xiaohui Chen, Yongjun Li, Xiao Yang, Liting Pei, Ke Zhu, Xiangzhen You, Wenbin Lin, Chunfu |
| Author_xml | – sequence: 1 givenname: Liting surname: Yang fullname: Yang, Liting organization: Fudan University – sequence: 2 givenname: Xiangzhen surname: Zhu fullname: Zhu, Xiangzhen organization: Hainan University – sequence: 3 givenname: Xiaohui surname: Li fullname: Li, Xiaohui organization: Fudan University – sequence: 4 givenname: Xuebing surname: Zhao fullname: Zhao, Xuebing organization: Fudan University – sequence: 5 givenname: Ke surname: Pei fullname: Pei, Ke organization: Fudan University – sequence: 6 givenname: Wenbin surname: You fullname: You, Wenbin organization: Fudan University – sequence: 7 givenname: Xiao surname: Li fullname: Li, Xiao organization: Fudan University – sequence: 8 givenname: Yongjun surname: Chen fullname: Chen, Yongjun organization: Hainan University – sequence: 9 givenname: Chunfu orcidid: 0000-0003-0251-7938 surname: Lin fullname: Lin, Chunfu email: linchunfu@qdu.edu.cn organization: Hainan University – sequence: 10 givenname: Renchao orcidid: 0000-0002-6583-7114 surname: Che fullname: Che, Renchao email: rcche@fudan.edu.cn organization: Fudan University |
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| Snippet | Niobates with shear ReO3 crystal structures are remarkably promising anode materials for Li+ batteries due to their large capacities, inherent safety, and high... Niobates with shear ReO 3 crystal structures are remarkably promising anode materials for Li + batteries due to their large capacities, inherent safety, and... |
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| SubjectTerms | anode materials Anodes Conductivity Copper Crystal structure Crystallography Diffusion coefficient Electrode materials Grain boundaries in situ TEM lithium ion batteries lithium ionic transport Niobates Stability Transport |
| Title | Conductive Copper Niobate: Superior Li+‐Storage Capability and Novel Li+‐Transport Mechanism |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Faenm.201902174 https://www.proquest.com/docview/2306039211 |
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