Development of self-healing epoxy composites via incorporation of microencapsulated epoxy and mercaptan in poly(methyl methacrylate) shell
Self-healing composites based on epoxy resin containing poly(methyl methacrylate) (PMMA) microcapsules filled with healing agents were prepared. The effect of healing agents microcapsules on mechanical properties and self-healing behavior of epoxy composites were investigated in this work. Epoxy and...
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Published in | Polymer testing Vol. 73; pp. 395 - 403 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.02.2019
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Abstract | Self-healing composites based on epoxy resin containing poly(methyl methacrylate) (PMMA) microcapsules filled with healing agents were prepared. The effect of healing agents microcapsules on mechanical properties and self-healing behavior of epoxy composites were investigated in this work. Epoxy and mercaptan as curing agent were microencapsulated in PMMA shell as two-component healing agent through internal phase separation method, and then, epoxy composites containing 2.5, 5, 7.5 and 10 wt% of healing agent microcapsules were prepared. The fracture toughness and healing efficiency of these composites were measured using a tapered double cantilever beam (TDCB) specimen. The results indicated that about 80% healing efficiency was achieved with 10 wt% PMMA microcapsules at room temperature after 24 h. The tensile strength of the epoxy with 2.5 wt% PMMA microcapsules increased initially and then decreased gradually with increasing microcapsules content up to 10 wt% PMMA microcapsules. DSC results also indicated that this system has good potential for spontaneous self-healing performance at room temperature.
•Low viscosity epoxy and mercaptan were encapsulated in PMMA shell, separately.•Fracture toughness of epoxy composites increased by the crack pinning mechanism around the broken PMMA microcapsules.•Healing efficiency of epoxy composites increased with increase in PMMA microcapsules concentration. |
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AbstractList | Self-healing composites based on epoxy resin containing poly(methyl methacrylate) (PMMA) microcapsules filled with healing agents were prepared. The effect of healing agents microcapsules on mechanical properties and self-healing behavior of epoxy composites were investigated in this work. Epoxy and mercaptan as curing agent were microencapsulated in PMMA shell as two-component healing agent through internal phase separation method, and then, epoxy composites containing 2.5, 5, 7.5 and 10 wt% of healing agent microcapsules were prepared. The fracture toughness and healing efficiency of these composites were measured using a tapered double cantilever beam (TDCB) specimen. The results indicated that about 80% healing efficiency was achieved with 10 wt% PMMA microcapsules at room temperature after 24 h. The tensile strength of the epoxy with 2.5 wt% PMMA microcapsules increased initially and then decreased gradually with increasing microcapsules content up to 10 wt% PMMA microcapsules. DSC results also indicated that this system has good potential for spontaneous self-healing performance at room temperature.
•Low viscosity epoxy and mercaptan were encapsulated in PMMA shell, separately.•Fracture toughness of epoxy composites increased by the crack pinning mechanism around the broken PMMA microcapsules.•Healing efficiency of epoxy composites increased with increase in PMMA microcapsules concentration. |
Author | Picchioni, Francesco Navarchian, Amir H. Hayaty, Mehran Ahangaran, Fatemeh Pei, Yutao |
Author_xml | – sequence: 1 givenname: Fatemeh surname: Ahangaran fullname: Ahangaran, Fatemeh organization: Department of Applied Chemistry, Malek-ashtar University of Technology, Isfahan, 83145/115, I.R. Iran – sequence: 2 givenname: Mehran surname: Hayaty fullname: Hayaty, Mehran email: mehayaty@mut-es.ac.ir organization: Department of Applied Chemistry, Malek-ashtar University of Technology, Isfahan, 83145/115, I.R. Iran – sequence: 3 givenname: Amir H. surname: Navarchian fullname: Navarchian, Amir H. organization: Department of Chemical Engineering, Faculty of Engineering, University of Isfahan, Isfahan, 81746-73441, I.R. Iran – sequence: 4 givenname: Yutao orcidid: 0000-0002-1817-2228 surname: Pei fullname: Pei, Yutao organization: Department of Advanced Production Engineering, Engineering and Technology Institute Groningen, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands – sequence: 5 givenname: Francesco surname: Picchioni fullname: Picchioni, Francesco organization: Department of Chemical Engineering, University of Groningen, Nijenborgh 4, 9747, AG, Groningen, The Netherlands |
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Keywords | Mechanical properties Epoxy composite Healing agent Self-healing behavior PMMA microcapsule |
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Snippet | Self-healing composites based on epoxy resin containing poly(methyl methacrylate) (PMMA) microcapsules filled with healing agents were prepared. The effect of... |
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SubjectTerms | Epoxy composite Healing agent Mechanical properties PMMA microcapsule Self-healing behavior |
Title | Development of self-healing epoxy composites via incorporation of microencapsulated epoxy and mercaptan in poly(methyl methacrylate) shell |
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