Low-temperature steam reforming of methanol to produce hydrogen over various metal-doped molybdenum carbide catalysts

Various transition metals (M = Pt, Fe, Co, and Ni) were selected to support on molybdenum carbides by in-situ carburization metal-doped molybdenum oxide (M-MoOx) via temperature-programmed reaction (TPR) with a final temperature of 700 degree C in a reaction gas mixture of 20% CH4/H2. XRD analysis r...

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Published in	International journal of hydrogen energy Vol. 39; no. 1; pp. 258 - 266
Main Authors	Ma, Yufei, Guan, Guoqing, Shi, Chuan, Zhu, Aimin, Hao, Xiaogang, Wang, Zhongde, Kusakabe, Katsuki, Abudula, Abuliti
Format	Journal Article
Language	English
Published	Kidlington Elsevier 01.01.2014
Subjects	Alternative fuels. Production and utilization Applied sciences Catalysis Catalysts Conversion Doping Energy Exact sciences and technology Fuels Hydrogen Methyl alcohol Molybdenum carbides Phase transformations Platinum TPR method Steam reforming of methanol Hydrogen Transition metal Steam reforming Molybdenum carbide Molybdenum Catalyst Hydrogen production Low temperature Methanol
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Abstract	Various transition metals (M = Pt, Fe, Co, and Ni) were selected to support on molybdenum carbides by in-situ carburization metal-doped molybdenum oxide (M-MoOx) via temperature-programmed reaction (TPR) with a final temperature of 700 degree C in a reaction gas mixture of 20% CH4/H2. XRD analysis results indicated that I2-Mo2C phase was formed in the case of Fe, Co, or Ni doping while I--Mo2C phase was appeared with the I2-MoC1ax phase in the case of Pt doping. With the increase in Pt doping amount, more I--MoC1ax phase was produced. As-prepared metal doped molybdenum carbides were investigated as alternative catalysts for the steam reforming of methanol. Comparing with the undoped molybdenum carbide such as I2-Mo2C, metal-doped one showed higher methanol conversion and hydrogen yield. It is found that Pt doped molybdenum carbide had the highest catalytic activity and selectivity among the prepared catalysts and methanol conversion reached 100% even at a temperature as low as 200 degree C, and remained a long-time stability with a stable methanol conversion.
AbstractList	Various transition metals (M = Pt, Fe, Co, and Ni) were selected to support on molybdenum carbides by in-situ carburization metal-doped molybdenum oxide (M-MoOx) via temperature-programmed reaction (TPR) with a final temperature of 700 degree C in a reaction gas mixture of 20% CH4/H2. XRD analysis results indicated that I2-Mo2C phase was formed in the case of Fe, Co, or Ni doping while I--Mo2C phase was appeared with the I2-MoC1ax phase in the case of Pt doping. With the increase in Pt doping amount, more I--MoC1ax phase was produced. As-prepared metal doped molybdenum carbides were investigated as alternative catalysts for the steam reforming of methanol. Comparing with the undoped molybdenum carbide such as I2-Mo2C, metal-doped one showed higher methanol conversion and hydrogen yield. It is found that Pt doped molybdenum carbide had the highest catalytic activity and selectivity among the prepared catalysts and methanol conversion reached 100% even at a temperature as low as 200 degree C, and remained a long-time stability with a stable methanol conversion.
Author	Shi, Chuan Hao, Xiaogang Zhu, Aimin Kusakabe, Katsuki Ma, Yufei Abudula, Abuliti Guan, Guoqing Wang, Zhongde
Author_xml	– sequence: 1 givenname: Yufei surname: Ma fullname: Ma, Yufei – sequence: 2 givenname: Guoqing surname: Guan fullname: Guan, Guoqing – sequence: 3 givenname: Chuan surname: Shi fullname: Shi, Chuan – sequence: 4 givenname: Aimin surname: Zhu fullname: Zhu, Aimin – sequence: 5 givenname: Xiaogang surname: Hao fullname: Hao, Xiaogang – sequence: 6 givenname: Zhongde surname: Wang fullname: Wang, Zhongde – sequence: 7 givenname: Katsuki surname: Kusakabe fullname: Kusakabe, Katsuki – sequence: 8 givenname: Abuliti surname: Abudula fullname: Abudula, Abuliti
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Keywords	TPR method Steam reforming of methanol Hydrogen Transition metal Steam reforming Molybdenum carbide Molybdenum Catalyst Hydrogen production Low temperature Methanol
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Snippet	Various transition metals (M = Pt, Fe, Co, and Ni) were selected to support on molybdenum carbides by in-situ carburization metal-doped molybdenum oxide...
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SubjectTerms	Alternative fuels. Production and utilization Applied sciences Catalysis Catalysts Conversion Doping Energy Exact sciences and technology Fuels Hydrogen Methyl alcohol Molybdenum carbides Phase transformations Platinum
Title	Low-temperature steam reforming of methanol to produce hydrogen over various metal-doped molybdenum carbide catalysts
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