(Acetylacetonato-κ2O,O′)[1-(4-bromophenyl-κC2)-3-methylimidazol-2-ylidene-κC2]platinum(II)

The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square‐planar coordination environment around the PtII centre. In the solid state, the molecules are oriented in a par...

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Published inActa crystallographica. Section C, Crystal structure communications Vol. 68; no. 8; pp. m203 - m205
Main Authors Tenne, Mario, Unger, Yvonne, Strassner, Thomas
Format Journal Article
LanguageEnglish
Published 5 Abbey Square, Chester, Cheshire CH1 2HU, England International Union of Crystallography 01.08.2012
Subjects
Crystal structure
Crystallography
Distortion
Hydrogen bonding
Ligands
Solid state
Spectators
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Summary:The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square‐planar coordination environment around the PtII centre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π–π and C—H...π interactions, while close Pt...Pt contacts are not observed. The structure is only the second example for this new class of compounds.
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ark:/67375/WNG-JFDTZB2S-3
ArticleID:AYCEG3094
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270112027783