Intramolecular Orbital Interactions in 6,6′-Bi(1,4-dithiafulvenyl) Studied by Photoelectron Spectroscopy

• Published in: Bulletin of the Chemical Society of Japan Vol. 57; no. 9; pp. 2591 - 2595
• Main Authors: Kobayashi, Tsunetoshi, Yoshida, Zen-ichi, Awaji, Hiroshi, Kawase, Tokuzo, Yoneda, Shigeo
• Format: Journal Article
• Language: English
• Published: Tokyo The Chemical Society of Japan 01.09.1984; Chemical Society of Japan
• Subjects: Atomic and molecular physics; Exact sciences and technology; Molecular properties and interactions with photons; Photoelectron spectra; Physics; Five membered ring; Sulfur heterocycle; Ultraviolet radiation; Molecular structure; Photoelectron spectrum; Gaseous state; Ionization potential; Experimental study; Organic compounds

Photoelectron spectra of tetrathiafulvalene (TTF) and 6,6′-bi(1,4-dithiafulvenyl) (BDTF) were measured and compared with each other. The first photoelectron spectral band of BDTF is only slightly shifted relative to that of TTF, though the BDTF molecule is lengthened compared with the TTF molecule b...