Continuous electrical pumping membrane process for seawater lithium mining
Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concen...
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| Published in | Energy & environmental science Vol. 14; no. 5; pp. 3152 - 3159 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
01.01.2021
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (∼0.1-0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43 000 times (
i.e.
, from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry.
Lithium was enriched up to 10 000 ppm from seawater by a continuous electrical pumping membrane process and collected as battery-grade product by simple precipitation. |
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| AbstractList | Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (∼0.1–0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43 000 times (i.e., from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry. Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (∼0.1-0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43 000 times ( i.e. , from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry. Lithium was enriched up to 10 000 ppm from seawater by a continuous electrical pumping membrane process and collected as battery-grade product by simple precipitation. Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (∼0.1–0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43 000 times ( i.e. , from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry. |
| Author | Liu, Xiaowei Li, Zhen Wei, Ruicong Lai, Zhiping Guo, Dong Cao, Li Li, Xiang Huang, Kuo-Wei Li, Chunyang Li, Peipei |
| AuthorAffiliation | King Abdullah University of Science and Technology (KAUST) Division of Physicals Science and Engineering |
| AuthorAffiliation_xml | – name: Division of Physicals Science and Engineering – name: King Abdullah University of Science and Technology (KAUST) |
| Author_xml | – sequence: 1 givenname: Zhen surname: Li fullname: Li, Zhen – sequence: 2 givenname: Chunyang surname: Li fullname: Li, Chunyang – sequence: 3 givenname: Xiaowei surname: Liu fullname: Liu, Xiaowei – sequence: 4 givenname: Li surname: Cao fullname: Cao, Li – sequence: 5 givenname: Peipei surname: Li fullname: Li, Peipei – sequence: 6 givenname: Ruicong surname: Wei fullname: Wei, Ruicong – sequence: 7 givenname: Xiang surname: Li fullname: Li, Xiang – sequence: 8 givenname: Dong surname: Guo fullname: Guo, Dong – sequence: 9 givenname: Kuo-Wei surname: Huang fullname: Huang, Kuo-Wei – sequence: 10 givenname: Zhiping surname: Lai fullname: Lai, Zhiping |
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| SubjectTerms | Batteries Chemical analysis Economic analysis Lithium Lithium batteries Membrane processes Membranes Purity Seawater Selectivity Water analysis |
| Title | Continuous electrical pumping membrane process for seawater lithium mining |
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