Investigation of Parameter Control for Electrocatalytic Semihydrogenation in a Proton-Exchange Membrane Reactor Utilizing Bayesian Optimization
Owing to its applicability in sustainable engineering, flow electrochemical synthesis in a proton-exchange membrane (PEM) reactor has attracted considerable attention. Because the reactions in PEM reactors are performed under electro-organic and flow-synthetic conditions, a higher number of reaction...
Saved in:
| Published in | Frontiers in chemical engineering Vol. 3 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Frontiers Media S.A
26.01.2022
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Owing to its applicability in sustainable engineering, flow electrochemical synthesis in a proton-exchange membrane (PEM) reactor has attracted considerable attention. Because the reactions in PEM reactors are performed under electro-organic and flow-synthetic conditions, a higher number of reaction parameters exist compared to ordinary reactions. Thus, the optimization of such reactions requires significant amounts of energy, time, chemical and human resources. Herein, we show that the optimization of alkyne semihydrogenation in PEM reactors can be facilitated by means of Bayesian optimization, an applied mathematics strategy. Applying the optimized conditions, we also demonstrate the generation of a deuterated
Z
-alkene. |
|---|---|
| AbstractList | Owing to its applicability in sustainable engineering, flow electrochemical synthesis in a proton-exchange membrane (PEM) reactor has attracted considerable attention. Because the reactions in PEM reactors are performed under electro-organic and flow-synthetic conditions, a higher number of reaction parameters exist compared to ordinary reactions. Thus, the optimization of such reactions requires significant amounts of energy, time, chemical and human resources. Herein, we show that the optimization of alkyne semihydrogenation in PEM reactors can be facilitated by means of Bayesian optimization, an applied mathematics strategy. Applying the optimized conditions, we also demonstrate the generation of a deuterated Z-alkene. Owing to its applicability in sustainable engineering, flow electrochemical synthesis in a proton-exchange membrane (PEM) reactor has attracted considerable attention. Because the reactions in PEM reactors are performed under electro-organic and flow-synthetic conditions, a higher number of reaction parameters exist compared to ordinary reactions. Thus, the optimization of such reactions requires significant amounts of energy, time, chemical and human resources. Herein, we show that the optimization of alkyne semihydrogenation in PEM reactors can be facilitated by means of Bayesian optimization, an applied mathematics strategy. Applying the optimized conditions, we also demonstrate the generation of a deuterated Z -alkene. |
| Author | Atobe, Mahito Ashikari, Yosuke Yao, Yiyue Nagaki, Aiichiro Takahashi, Yusuke Tamaki, Takashi |
| Author_xml | – sequence: 1 givenname: Yosuke surname: Ashikari fullname: Ashikari, Yosuke – sequence: 2 givenname: Takashi surname: Tamaki fullname: Tamaki, Takashi – sequence: 3 givenname: Yusuke surname: Takahashi fullname: Takahashi, Yusuke – sequence: 4 givenname: Yiyue surname: Yao fullname: Yao, Yiyue – sequence: 5 givenname: Mahito surname: Atobe fullname: Atobe, Mahito – sequence: 6 givenname: Aiichiro surname: Nagaki fullname: Nagaki, Aiichiro |
| BookMark | eNpNkdFq3DAQRUVIIWmaD-ibfsBbaWTJ8mO7bJuFlIS2eTZjeeQo2FKQRenmJ_LL2eyGkqe5MzAHLucjO40pEmOfpVgpZdsv3lEcVyBArqxsGw0n7BxMoypopD19l8_Y5bI8CCGgsaqWcM6et_EvLSWMWEKKPHl-ixlnKpT5OsWS08R9ynwzkdsvDgtOuxIc_01zuN8NOY0Uj78hcuS3OZUUq80_d49xJP6T5j5jJP6L0JU96K6EKTyFOPJvuKMlYOQ3jyXM4elA-cQ-eJwWunybF-zu--bP-qq6vvmxXX-9rlwNolRgh8b0vnWeUAuoAQTZlmqnW2UkUg_eKaPrBo1spDFDTQrcoBGg77UV6oJtj9wh4UP3mMOMedclDN3hkPLYYd73nKiTxjmwKMRgZD1o3eu2b50hJY23gP2eJY8sl9OyZPL_eVJ0r4K6g6DuVVB3FKReAIJQieU |
| CitedBy_id | crossref_primary_10_1002_celc_202300315 crossref_primary_10_1016_j_jfluchem_2024_110294 crossref_primary_10_1039_D3RE00648D crossref_primary_10_3389_fceng_2022_964767 crossref_primary_10_1002_chem_202301738 crossref_primary_10_3762_bjoc_18_67 crossref_primary_10_1039_D3PY00709J crossref_primary_10_5059_yukigoseikyokaishi_82_2 |
| Cites_doi | 10.1021/acscatal.8b01682 10.1021/acs.accounts.9b00412 10.1007/bf00626308 10.1248/cpb.c17-00222 10.1016/j.carres.2020.108018 10.1002/cctc.201501269 10.5796/electrochemistry.74.585 10.1246/cl.160766 10.1007/978-1-4419-6996-5_132 10.1007/s41981-020-00125-2 10.1016/j.elecom.2020.106734 10.1016/0013-4686(95)00342-8 10.1246/bcsj.20180021 10.1038/s42004-019-0125-4 10.1021/acs.accounts.9b00497 10.1002/anie.201704146 10.1021/cr400133p 10.1002/chem.201905048 10.1055/s-0037-1611643 10.1016/j.apenergy.2010.09.030 10.1016/0013-4686(81)85163-8 10.1126/science.aar5169 10.1002/anie.201912419 10.1149/1945-7111/abaae7 10.1002/anie.202012085 10.1039/d1ob01197a 10.1002/anie.200700039 10.1038/s41586-021-03213-y 10.1002/cmtd.202100053 10.1038/s42004-021-00490-6 10.1021/cr3001753 10.1039/c9cc08526b 10.1126/science.abf2974 10.1021/jacs.0c06370 10.1021/acssuschemeng.9b01882 10.1039/c7sc02482g 10.1002/anie.202009757 10.1002/anie.202103233s 10.1002/anie.202002106 10.1016/j.memsci.2005.01.035 10.1039/d0re00411a 10.1021/jacs.0c08109 10.1002/chem.201903426 10.1021/acs.chemrev.7b00656 10.1002/anie.202003831 10.1021/acs.joc.1c01242 10.1021/jacs.0c11214 10.1021/acssuschemeng.0c02281 |
| ContentType | Journal Article |
| DBID | AAYXX CITATION DOA |
| DOI | 10.3389/fceng.2021.819752 |
| DatabaseName | CrossRef DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | CrossRef |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website |
| DeliveryMethod | fulltext_linktorsrc |
| EISSN | 2673-2718 |
| ExternalDocumentID | oai_doaj_org_article_16cc28a00d614d55b59b9c6e316f82ab 10_3389_fceng_2021_819752 |
| GroupedDBID | 9T4 AAFWJ AAYXX ACXDI AFPKN ALMA_UNASSIGNED_HOLDINGS CITATION GROUPED_DOAJ M~E OK1 |
| ID | FETCH-LOGICAL-c420t-28d76bf9cfea5024220e89e4c59361aeb2fc36547a617166d4e32cd5a22bb5803 |
| IEDL.DBID | DOA |
| ISSN | 2673-2718 |
| IngestDate | Thu Jul 04 21:05:11 EDT 2024 Fri Aug 23 01:36:06 EDT 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c420t-28d76bf9cfea5024220e89e4c59361aeb2fc36547a617166d4e32cd5a22bb5803 |
| OpenAccessLink | https://doaj.org/article/16cc28a00d614d55b59b9c6e316f82ab |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_16cc28a00d614d55b59b9c6e316f82ab crossref_primary_10_3389_fceng_2021_819752 |
| PublicationCentury | 2000 |
| PublicationDate | 2022-01-26 |
| PublicationDateYYYYMMDD | 2022-01-26 |
| PublicationDate_xml | – month: 01 year: 2022 text: 2022-01-26 day: 26 |
| PublicationDecade | 2020 |
| PublicationTitle | Frontiers in chemical engineering |
| PublicationYear | 2022 |
| Publisher | Frontiers Media S.A |
| Publisher_xml | – name: Frontiers Media S.A |
| References | Fukazawa (B13) 2021; 19 Ashikari (B4) 2019; 25 Sugisawa (B42) 2021; 1 Raoult (B33) 1984; 14 Sauermann (B36) 2018; 8 Fuchigami (B11) 2006; 74 Hu (B17) 2020; 142 Chinchilla (B7) 2014; 114 Ahn (B1) 2021; 4 Sivo (B40) 2021; 6 Atzrodt (B6) 2018; 57 Watanabe (B46) 2020; 26 Ogumi (B30) 1981; 26 Elsherbini (B10) 2019; 52 Nogami (B28) 2020; 167 Shida (B38) 2019; 2 Takano (B43) 2016; 45 Shields (B39) 2021; 590 Sawama (B37) 2018; 66 Moeller (B26) 2018; 118 Otake (B31) 2020; 59 Noël (B27) 2019; 52 Ichinari (B19) 2020; 59 Colella (B8) 2020; 59 Sato (B35) 2021; 86 Yano (B48) 2020; 492 Smitha (B41) 2005; 259 Atzrodt (B5) 2007; 46 Oger (B29) 2013; 113 Jőrissen (B21) 1996; 41 Johnson (B20) 2017; 8 Saito (B34) 2020; 142 Ibanez (B18) 2014 Mockus (B25) 2011 Fukazawa (B12) 2019; 7 Ahneman (B2) 2018; 360 Fukazawa (B15) 2020; 115 Kondo (B23) 2020; 56 Prieschl (B32) 2021; 11 Ashikari (B3) 2020; 142 Dong (B9) 2021; 371 Kishi (B22) 2020; 8 Fukazawa (B14) 2018; 91 Masui (B24) 2019; 30 Wu (B47) 2020; 59 Wang (B45) 2011; 88 Harenberg (B16) 2020; 60 Vilé (B44) 2016; 8 Zhou (B49) 2020; 60 |
| References_xml | – volume: 8 start-page: 7086 year: 2018 ident: B36 article-title: Electrocatalytic C-H Activation publication-title: ACS Catal. doi: 10.1021/acscatal.8b01682 contributor: fullname: Sauermann – volume: 52 start-page: 2858 year: 2019 ident: B27 article-title: The Fundamentals behind the Use of Flow Reactors in Electrochemistry publication-title: Acc. Chem. Res. doi: 10.1021/acs.accounts.9b00412 contributor: fullname: Noël – volume: 14 start-page: 639 year: 1984 ident: B33 article-title: Use of Ion Exchange Membranes in Preparative Organic Electrochemistry. L Anodic Methoxylation of Some Olefins publication-title: J. Appl. Electrochem. doi: 10.1007/bf00626308 contributor: fullname: Raoult – volume: 66 start-page: 21 year: 2018 ident: B37 article-title: New Gateways to the Platinum Group Metal-Catalyzed Direct Deuterium-Labeling Method Utilizing Hydrogen as a Catalyst Activator publication-title: Chem. Pharm. Bull. doi: 10.1248/cpb.c17-00222 contributor: fullname: Sawama – volume: 492 start-page: 108018 year: 2020 ident: B48 article-title: Total Synthesis of Myc-Iv(c16:0, S) via Automated Electrochemical Assembly publication-title: Carbohydr. Res. doi: 10.1016/j.carres.2020.108018 contributor: fullname: Yano – volume: 8 start-page: 21 year: 2016 ident: B44 article-title: Advances in the Design of Nanostructured Catalysts for Selective Hydrogenation publication-title: ChemCatChem doi: 10.1002/cctc.201501269 contributor: fullname: Vilé – volume: 74 start-page: 585 year: 2006 ident: B11 article-title: Development of New Methodologies toward Green Sustainable Organic Electrode Processes publication-title: Electrochemistry doi: 10.5796/electrochemistry.74.585 contributor: fullname: Fuchigami – volume: 45 start-page: 1437 year: 2016 ident: B43 article-title: Electrocatalytic Hydrogenation of O-Xylene in a PEM Reactor as a Study of a Model Reaction for Hydrogen Storage publication-title: Chem. Lett. doi: 10.1246/cl.160766 contributor: fullname: Takano – start-page: 964 volume-title: Encyclopedia of Applied Electrochemistry year: 2014 ident: B18 article-title: Green Electrochemistry doi: 10.1007/978-1-4419-6996-5_132 contributor: fullname: Ibanez – volume: 11 start-page: 117 year: 2021 ident: B32 article-title: A Continuous Flow Bromodimethylsulfonium Bromide Generator: Application to the Synthesis of 2-Arylaziridines from Styrenes publication-title: J. Flow Chem. doi: 10.1007/s41981-020-00125-2 contributor: fullname: Prieschl – volume: 115 start-page: 106734 year: 2020 ident: B15 article-title: Electrocatalytic Asymmetric Hydrogenation of α,β-unsaturated Acids in a PEM Reactor with Cinchona-Modified Palladium Catalysts publication-title: Electrochemistry Commun. doi: 10.1016/j.elecom.2020.106734 contributor: fullname: Fukazawa – volume: 41 start-page: 553 year: 1996 ident: B21 article-title: Ion Exchange Membranes as Solid Polymer Electrolytes (SPE) in Electro-Organic Syntheses without Supporting Electrolyte publication-title: Electrochim. Acta doi: 10.1016/0013-4686(95)00342-8 contributor: fullname: Jőrissen – volume: 91 start-page: 897 year: 2018 ident: B14 article-title: Electrocatalytic Hydrogenation of Toluene Using a Proton Exchange Membrane Reactor: Influence of Catalyst Materials on Product Selectivity publication-title: Bcsj doi: 10.1246/bcsj.20180021 contributor: fullname: Fukazawa – volume: 2 start-page: 24 year: 2019 ident: B38 article-title: Interplay of Arene Radical Cations with Anions and Fluorinated Alcohols in Hole Catalysis publication-title: Commun. Chem. doi: 10.1038/s42004-019-0125-4 contributor: fullname: Shida – volume: 52 start-page: 3287 year: 2019 ident: B10 article-title: Electroorganic Synthesis under Flow Conditions publication-title: Acc. Chem. Res. doi: 10.1021/acs.accounts.9b00497 contributor: fullname: Elsherbini – volume: 57 start-page: 1758 year: 2018 ident: B6 article-title: Deuterium- and Tritium-Labelled Compounds: Applications in the Life Sciences publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201704146 contributor: fullname: Atzrodt – volume: 114 start-page: 1783 year: 2014 ident: B7 article-title: Chemicals from Alkynes with Palladium Catalysts publication-title: Chem. Rev. doi: 10.1021/cr400133p contributor: fullname: Chinchilla – volume: 26 start-page: 186 year: 2020 ident: B46 article-title: A Practical Method for Continuous Production of sp3‐Rich Compounds from (Hetero)Aryl Halides and Redox‐Active Esters publication-title: Chem. Eur. J. doi: 10.1002/chem.201905048 contributor: fullname: Watanabe – volume: 30 start-page: 397 year: 2019 ident: B24 article-title: Kinetically Controlled Fischer Glycosidation under Flow Conditions: A New Method for Preparing Furanosides publication-title: Synlett doi: 10.1055/s-0037-1611643 contributor: fullname: Masui – volume: 88 start-page: 981 year: 2011 ident: B45 article-title: A Review of Polymer Electrolyte Membrane Fuel Cells: Technology, Applications, and Needs on Fundamental Research publication-title: Appl. Energ. doi: 10.1016/j.apenergy.2010.09.030 contributor: fullname: Wang – volume: 26 start-page: 1779 year: 1981 ident: B30 article-title: Application of the Spe Method to Organic Electrochemistry-II. Electrochemical Hydrogenation of Olefinic Double Bonds publication-title: Electrochimica Acta doi: 10.1016/0013-4686(81)85163-8 contributor: fullname: Ogumi – volume: 360 start-page: 186 year: 2018 ident: B2 article-title: Predicting Reaction Performance in C-N Cross-Coupling Using Machine Learning publication-title: Science doi: 10.1126/science.aar5169 contributor: fullname: Ahneman – volume: 59 start-page: 1567 year: 2020 ident: B19 article-title: A Novel Approach to Functionalization of Aryl Azides through the Generation and Reaction of Organolithium Species Bearing Masked Azides in Flow Microreactors publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201912419 contributor: fullname: Ichinari – volume-title: Bayesian Approach to Global Optimization year: 2011 ident: B25 contributor: fullname: Mockus – volume: 167 start-page: 155506 year: 2020 ident: B28 article-title: Highly Selective and Efficient Electrocatalytic Semihydrogenation of Diphenylacetylene in a PEM Reactor with Pt-Pd Alloy Cathode Catalysts publication-title: J. Electrochem. Soc. doi: 10.1149/1945-7111/abaae7 contributor: fullname: Nogami – volume: 60 start-page: 731 year: 2020 ident: B16 article-title: Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202012085 contributor: fullname: Harenberg – volume: 19 start-page: 7367 year: 2021 ident: B13 article-title: Electrocatalytic Hydrogenation of Benzoic Acids in a Proton-Exchange Membrane Reactor publication-title: Org. Biomol. Chem. doi: 10.1039/d1ob01197a contributor: fullname: Fukazawa – volume: 46 start-page: 7744 year: 2007 ident: B5 article-title: The Renaissance of H/D Exchange publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.200700039 contributor: fullname: Atzrodt – volume: 590 start-page: 89 year: 2021 ident: B39 article-title: Bayesian Reaction Optimization as a Tool for Chemical Synthesis publication-title: Nature doi: 10.1038/s41586-021-03213-y contributor: fullname: Shields – volume: 1 start-page: 484 year: 2021 ident: B42 article-title: Rapid and Mild One‐Flow Synthetic Approach to Unsymmetrical Sulfamides Guided by Bayesian Optimization publication-title: Chem. Methods doi: 10.1002/cmtd.202100053 contributor: fullname: Sugisawa – volume: 4 start-page: 53 year: 2021 ident: B1 article-title: Flow Parallel Synthesizer for Multiplex Synthesis of Aryl Diazonium Libraries via Efficient Parameter Screening publication-title: Commun. Chem. doi: 10.1038/s42004-021-00490-6 contributor: fullname: Ahn – volume: 113 start-page: 1313 year: 2013 ident: B29 article-title: Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough to Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules? publication-title: Chem. Rev. doi: 10.1021/cr3001753 contributor: fullname: Oger – volume: 56 start-page: 1259 year: 2020 ident: B23 article-title: Exploration of Flow Reaction Conditions Using Machine-Learning for Enantioselective Organocatalyzed Rauhut-Currier and [3+2] Annulation Sequence publication-title: Chem. Commun. doi: 10.1039/c9cc08526b contributor: fullname: Kondo – volume: 371 start-page: 507 year: 2021 ident: B9 article-title: Merging Shuttle Reactions and Paired Electrolysis for Reversible Vicinal Dihalogenations publication-title: Science doi: 10.1126/science.abf2974 contributor: fullname: Dong – volume: 142 start-page: 17039 year: 2020 ident: B3 article-title: A Synthetic Approach to Dimetalated Arenes Using Flow Microreactors and the Switchable Application to Chemoselective Cross-Coupling Reactions publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.0c06370 contributor: fullname: Ashikari – volume: 7 start-page: 11050 year: 2019 ident: B12 article-title: A New Approach to Stereoselective Electrocatalytic Semihydrogenation of Alkynes to Z-Alkenes Using a Proton-Exchange Membrane Reactor publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.9b01882 contributor: fullname: Fukazawa – volume: 8 start-page: 6493 year: 2017 ident: B20 article-title: High Turnover in Electro-Oxidation of Alcohols and Ethers with a Glassy Carbon-Supported Phenanthroimidazole Mediator publication-title: Chem. Sci. doi: 10.1039/c7sc02482g contributor: fullname: Johnson – volume: 59 start-page: 21170 year: 2020 ident: B47 article-title: Selective Transfer Semihydrogenation of Alkynes with H 2 O (D 2 O) as the H (D) Source over a Pd‐P Cathode publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202009757 contributor: fullname: Wu – volume: 60 start-page: 14620 year: 2020 ident: B49 article-title: Fabrication of Gradient and Patterned Organic Thin Films by Bipolar Electrolytic Micelle Disruption Using Redox-Active Surfactants publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202103233s contributor: fullname: Zhou – volume: 59 start-page: 12925 year: 2020 ident: B31 article-title: N‐Methylated Peptide Synthesis via Generation of an Acyl N‐Methylimidazolium Cation Accelerated by a Brønsted Acid publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202002106 contributor: fullname: Otake – volume: 259 start-page: 10 year: 2005 ident: B41 article-title: Solid Polymer Electrolyte Membranes for Fuel Cell Applications-A Review publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2005.01.035 contributor: fullname: Smitha – volume: 6 start-page: 756 year: 2021 ident: B40 article-title: From Circular Synthesis to Material Manufacturing: Advances, Challenges, and Future Steps for Using Flow Chemistry in Novel Application Area publication-title: React. Chem. Eng. doi: 10.1039/d0re00411a contributor: fullname: Sivo – volume: 142 start-page: 16546 year: 2020 ident: B34 article-title: Development of Robust Heterogeneous Chiral Rhodium Catalysts Utilizing Acid-Base and Electrostatic Interactions for Efficient Continuous-Flow Asymmetric Hydrogenations publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.0c08109 contributor: fullname: Saito – volume: 25 start-page: 15239 year: 2019 ident: B4 article-title: Oxo‐Thiolation of Cationically Polymerizable Alkenes Using Flow Microreactors publication-title: Chem. Eur. J. doi: 10.1002/chem.201903426 contributor: fullname: Ashikari – volume: 118 start-page: 4817 year: 2018 ident: B26 article-title: Using Physical Organic Chemistry to Shape the Course of Electrochemical Reactions publication-title: Chem. Rev. doi: 10.1021/acs.chemrev.7b00656 contributor: fullname: Moeller – volume: 59 start-page: 10924 year: 2020 ident: B8 article-title: Fluoro‐Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202003831 contributor: fullname: Colella – volume: 86 start-page: 16035 year: 2021 ident: B35 article-title: Application of an Electrochemical Microflow Reactor for Cyanosilylation: Machine Learning-Assisted Exploration of Suitable Reaction Conditions for Semi-large-scale Synthesis publication-title: J. Org. Chem. doi: 10.1021/acs.joc.1c01242 contributor: fullname: Sato – volume: 142 start-page: 20979 year: 2020 ident: B17 article-title: Electroreductive Olefin-Ketone Coupling publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.0c11214 contributor: fullname: Hu – volume: 8 start-page: 11532 year: 2020 ident: B22 article-title: Green Synthesis of Methyl Formate via Electrolysis of Pure Methanol publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.0c02281 contributor: fullname: Kishi |
| SSID | ssj0002783412 |
| Score | 2.2864811 |
| Snippet | Owing to its applicability in sustainable engineering, flow electrochemical synthesis in a proton-exchange membrane (PEM) reactor has attracted considerable... |
| SourceID | doaj crossref |
| SourceType | Open Website Aggregation Database |
| SubjectTerms | Bayesian optimization electrocatalyst electrosynthesis proton-exchange membrane reactor semihydrogenation |
| Title | Investigation of Parameter Control for Electrocatalytic Semihydrogenation in a Proton-Exchange Membrane Reactor Utilizing Bayesian Optimization |
| URI | https://doaj.org/article/16cc28a00d614d55b59b9c6e316f82ab |
| Volume | 3 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1NS8NAEF2kJy-iqFi_2IMnITbZZLfJ0ZaWIlSLWugt7MdEKzaRUsF68C_4l53JVqknL15yCNklvFl25u3OvGHsTNjY4kKIA3TPcZDECQQmjXSQKCe1cRjBOjrvGF6rwTi5msjJWqsvygnz8sAeuFZEib2pDkOHjsRJaWRmMqsgjlSRCm3q3TeSa2TqyV-n4fYs_DUmsrCsVVgoH5APiugCnWBbil-OaE2vv3Ys_W22tYoI-aX_kx22AeUu-1zTv6hKXhV8pCmNClHgXZ9dzjHc5D3fxaY-hFniBPwOZtPHpZtXuDD82GnJNR_NK-oV3Hvzhb58CDOkySXwW6gb7vDxYvo8fUc_xjt6CVRZyW9wN5mtyjT32Ljfu-8OglXvhMAmIlwEInVtZYrMFqAl-WERQppBYqmDX6SRTxc2psbDWpFgjnIJxMKifYQwRqZhvM8aZVXCASU_2aztFISkVaTbkIVGI5FRmcTZiwSa7PwbyPzFS2TkSC0I9bxGPSfUc496k3UI6p8PSd26foE2z1c2z_-y-eF_THLENgWVMoRRINQxayzmr3CCAcbCnNZrCZ_Dj94XDxPSdw |
| link.rule.ids | 315,786,790,870,2115,27955,27956 |
| linkProvider | Directory of Open Access Journals |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Investigation+of+Parameter+Control+for+Electrocatalytic+Semihydrogenation+in+a+Proton-Exchange+Membrane+Reactor+Utilizing+Bayesian+Optimization&rft.jtitle=Frontiers+in+chemical+engineering&rft.au=Ashikari%2C+Yosuke&rft.au=Tamaki%2C+Takashi&rft.au=Takahashi%2C+Yusuke&rft.au=Yao%2C+Yiyue&rft.date=2022-01-26&rft.issn=2673-2718&rft.eissn=2673-2718&rft.volume=3&rft_id=info:doi/10.3389%2Ffceng.2021.819752&rft.externalDBID=n%2Fa&rft.externalDocID=10_3389_fceng_2021_819752 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2673-2718&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2673-2718&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2673-2718&client=summon |