Alcohol and Alkane Organic Extraction Using Pervaporation Process
In this work, different feed mixtures are investigated for the separation of alcohol‐water, toluene‐water, alcohol‐toluene, and alkane‐toluene mixtures by pervaporation using a poly (dimethylsiloxane) membrane (PDMS). The polymeric membrane is characterized by Fourier transform infrared spectrometry...
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Published in | Macromolecular symposia. Vol. 386; no. 1 |
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Main Authors | , , , , |
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01.08.2019
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Abstract | In this work, different feed mixtures are investigated for the separation of alcohol‐water, toluene‐water, alcohol‐toluene, and alkane‐toluene mixtures by pervaporation using a poly (dimethylsiloxane) membrane (PDMS). The polymeric membrane is characterized by Fourier transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The total flux and membrane selectivity for hexane‐toluene mixtures are found to be greater than those obtained for heptane‐toluene, alcohol‐toluene, toluene‐water, and alcohol‐water mixtures. Moreover, the total flux and selectivity for the alkane‐toluene mixtures are found to be higher than those obtained for the alcohol‐toluene mixtures. The feed concentration and the temperature for hexane‐toluene mixture have the same effect on the membrane total flux. Overall, the pervaporation separation index (PSI) decreases with increasing feed concentration. The highest PSI value of 20 359 g m−2 h−1 is found at a hexane feed concentration of 10 wt%, a temperature of 40 °C, a permeation flux equal to 717 g m−2 h and a selectivity of 29. |
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AbstractList | In this work, different feed mixtures are investigated for the separation of alcohol‐water, toluene‐water, alcohol‐toluene, and alkane‐toluene mixtures by pervaporation using a poly (dimethylsiloxane) membrane (PDMS). The polymeric membrane is characterized by Fourier transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The total flux and membrane selectivity for hexane‐toluene mixtures are found to be greater than those obtained for heptane‐toluene, alcohol‐toluene, toluene‐water, and alcohol‐water mixtures. Moreover, the total flux and selectivity for the alkane‐toluene mixtures are found to be higher than those obtained for the alcohol‐toluene mixtures. The feed concentration and the temperature for hexane‐toluene mixture have the same effect on the membrane total flux. Overall, the pervaporation separation index (PSI) decreases with increasing feed concentration. The highest PSI value of 20 359 g m−2 h−1 is found at a hexane feed concentration of 10 wt%, a temperature of 40 °C, a permeation flux equal to 717 g m−2 h and a selectivity of 29. |
Author | Van der Bruggen, Bart Arous, Omar Abdessemed, Djamel Nezzal, Ghania Hamouni, Samia |
Author_xml | – sequence: 1 givenname: Samia surname: Hamouni fullname: Hamouni, Samia organization: Department of the Environment Engineering – sequence: 2 givenname: Omar surname: Arous fullname: Arous, Omar email: omararous@yahoo.fr organization: Faculty of Chemistry – sequence: 3 givenname: Djamel surname: Abdessemed fullname: Abdessemed, Djamel organization: Department of the Environment Engineering – sequence: 4 givenname: Ghania surname: Nezzal fullname: Nezzal, Ghania organization: Department of the Environment Engineering – sequence: 5 givenname: Bart surname: Van der Bruggen fullname: Van der Bruggen, Bart organization: KU Leuven |
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SubjectTerms | Alcohol Alkanes Flux Fourier transforms Heptanes Infrared analysis organic extraction PDMS Pervaporation Polydimethylsiloxane polymeric membrane Scanning electron microscopy Selectivity Separation Silicone resins Thermogravimetric analysis Toluene |
Title | Alcohol and Alkane Organic Extraction Using Pervaporation Process |
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