Studies on the Mechanism of the Excitation Step in Peroxyoxalate Chemiluminescence

• Published in: European journal of organic chemistry Vol. 2000; no. 24; pp. 4037 - 4046
• Main Authors: Stevani, Cassius V., Silva, Sandra M., Baader, Wilhelm J.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag GmbH 01.12.2000; WILEY‐VCH Verlag GmbH
• Subjects: Electron transfer; Kinetics; Linear free energy relationships; Luminescence; Peroxyoxalate chemiluminescence

Studies on the mechanism of excited state formation in the peroxyoxalate system have been performed, to corroborate the involvement of the well‐known Chemically Initiated Electron Exchange Luminescence (CIEEL) mechanism in the chemi‐excitation step of this complex sequence. The singlet quantum yield...