Rhodium complexes containing chiral P-donor ligands as catalysts for asymmetric hydrogenation in non conventional media

• Published in: Catalysis letters Vol. 141; no. 6; pp. 808 - 816
• Main Authors: Escárcega-Bobadilla, Martha V., Rodríguez-Pérez, Laura, Teuma, Emmanuelle, Serp, Philippe, Masdeu-Bultó, Anna M., Gómez, Montserrat
• Format: Journal Article
• Language: English
• Published: Boston Springer US 01.06.2011; Springer; Springer Nature B.V
• Subjects: Asymmetry; Carbon; Carbon dioxide; Catalysis; Catalysts; Chemistry; Chemistry and Materials Science; Coordination compounds; Dichloromethane; Enantiomers; Exact sciences and technology; Fluorination; General and physical chemistry; Hydrogenation; Industrial Chemistry/Chemical Engineering; Ionic liquids; Ions; Leaching; Ligands; Liquid phases; Multi wall carbon nanotubes; Nanotubes; Organometallic Chemistry; Physical Chemistry; Recycling; Rhodium; Solvents; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Asymmetric hydrogenation; Chiral monodentate P-donor ligands; Ionic liquids; Rhodium; Supercritical CO; Enantioselectivity; Support; Octane derivatives; Carbon dioxide; Immobilization; Liquid phase; Asymmetric induction; Hydrogenation; Ionic liquid; Molecular species; Recycling; Platinoid; Rhodium complex; Catalytic reaction; Transition metal; Fluorine compound; Supercritical state; Carbon; Organic solvent; Multiwalled nanotube; Catalyst; Monodentate ligand

Rhodium-catalysed asymmetric hydrogenation using P-donor ligands, such as new fluorinated ( R )-BINOL and azadioxaphosphabicyclo[3.3.0]octane derivatives was carried out in different reaction media such as organic solvent (CH 2 Cl 2 ), ionic liquid ([BMI][PF 6 ]), supercritical carbon dioxide (scCO...