Polymer-bound osmium oxide catalysts
Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of physical techniques (Raman, IR, XPS, 13C and 15N solid-state NMR spectroscopy). Model compounds of type Os 2O 6L 4 (L = pyridine, 4- iso-propyl p...
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Published in | Journal of molecular catalysis. A, Chemical Vol. 120; no. 1; pp. 197 - 205 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Amsterdam
Elsevier B.V
13.06.1997
Elsevier |
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Abstract | Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of physical techniques (Raman, IR, XPS,
13C and
15N solid-state NMR spectroscopy). Model compounds of type Os
2O
6L
4 (L = pyridine, 4-
iso-propyl pyridine, and 4-
tert-butyl pyridine) were obtained under the conditions of the catalyst synthesis. The catalytic systems were successful in the dihydroxylation of alkenes. |
---|---|
AbstractList | Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of physical techniques (Raman, IR, XPS,
13C and
15N solid-state NMR spectroscopy). Model compounds of type Os
2O
6L
4 (L = pyridine, 4-
iso-propyl pyridine, and 4-
tert-butyl pyridine) were obtained under the conditions of the catalyst synthesis. The catalytic systems were successful in the dihydroxylation of alkenes. |
Author | Mink, Janos Kratzer, Roland M. Fischer, Richard W. Berkesi, Otto Herrmann, Wolfgang A. Blümel, Janet Apperley, David C. Friedrich, Holger B. |
Author_xml | – sequence: 1 givenname: Wolfgang A. surname: Herrmann fullname: Herrmann, Wolfgang A. organization: Anorganisch-chemisches Institut, Technische Universität München, D-85747 Garching bei München, Germany – sequence: 2 givenname: Roland M. surname: Kratzer fullname: Kratzer, Roland M. organization: Anorganisch-chemisches Institut, Technische Universität München, D-85747 Garching bei München, Germany – sequence: 3 givenname: Janet surname: Blümel fullname: Blümel, Janet organization: Anorganisch-chemisches Institut, Technische Universität München, D-85747 Garching bei München, Germany – sequence: 4 givenname: Holger B. surname: Friedrich fullname: Friedrich, Holger B. organization: Department of Chemistry, University of Natal, Durban 4041 South Africa – sequence: 5 givenname: Richard W. surname: Fischer fullname: Fischer, Richard W. organization: Hoechst AG, Central Research, C 487, D-65926 Frankfurt Germany – sequence: 6 givenname: David C. surname: Apperley fullname: Apperley, David C. organization: University of Durham, Industrial Research Laboratories, South Road, Durham, DH1 3LE UK – sequence: 7 givenname: Janos surname: Mink fullname: Mink, Janos organization: Department of Analytical Chemistry, University of Veszprem, Egyetem u. 10, P.O. Box 158, H-8201 Veszprem Hungary – sequence: 8 givenname: Otto surname: Berkesi fullname: Berkesi, Otto organization: Department of Analytical Chemistry, University of Veszprem, Egyetem u. 10, P.O. Box 158, H-8201 Veszprem Hungary |
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Keywords | Dihydroxylation Alkenes Supported catalyst Osmium Platinoid Compounds Heterogeneous catalysis Alkene Hydroxylation Transition metal Compounds Crosslinked polymer Experimental study Pyridine(4-vinyl) polymer Osmium Oxides |
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Snippet | Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of... |
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SubjectTerms | Alkenes Catalysis Catalysts: preparations and properties Chemistry Dihydroxylation Exact sciences and technology General and physical chemistry Osmium Supported catalyst Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
Title | Polymer-bound osmium oxide catalysts |
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