Semiconductor photocatalysts: A critical review highlighting the various strategies to boost the photocatalytic performances for diverse applications

The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-h...

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Published inAdvances in colloid and interface science Vol. 311; p. 102830
Main Authors Ahmad, Irshad, Zou, Yanhong, Yan, Jiaying, Liu, Yuyu, Shukrullah, Shazia, Naz, Muhammad Yasin, Hussain, Humaira, Khan, Waheed Qamar, Khalid, N.R.
Format Journal Article
LanguageEnglish
Published Netherlands Elsevier B.V 01.01.2023
Subjects
CO2 reduction
H2 evolution
N2 fixation
Photocatalysts
Pollutants degradation
Semiconductors
Strategies
N2 fixation
Pollutants degradation
CO2 reduction
H2 evolution
Photocatalysts
Strategies
CO reduction
H evolution
N fixation
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Abstract The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-hole recombination rate. Sincemost of intrinsic semiconductor photocatalysts cannot meet all these requirements, they are often modified to boost their photocatalytic properties. Many strategies have been adopted to design novel and efficient photocatalysts for diverse applications. Herein, we review the most efficient of these strategies and methods focused on effectively overcoming the efficiency limitations of photocatalysts to promote their large-scale application. Subsequently, a particular aim is put on the most current studies for photocatalytic applications, including CO2 reduction, N2 fixation, H2 evolution, and pollutants degradation. Finally, key challenges and future perspectives in designing and implementing semiconductor photocatalysts for large-scale applications are discussed. Therefore, it is foreseen that this review will work as a guide for future research and provides a variety of strategies to develop novel and high-performance photocatalysts for various applications. [Display omitted] •Recent advances in strategies to design semiconductor catalysts are discussed.•The mechanism of various strategies for photocatalytic performance are highlighted.•The effect of diverse strategies on the photocatalytic performance is summarized.•Combination of different strategies leads to further increased performance.•Challenges pertaining the use of semiconductor catalysts are reviewed.
AbstractList The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-hole recombination rate. Sincemost of intrinsic semiconductor photocatalysts cannot meet all these requirements, they are often modified to boost their photocatalytic properties. Many strategies have been adopted to design novel and efficient photocatalysts for diverse applications. Herein, we review the most efficient of these strategies and methods focused on effectively overcoming the efficiency limitations of photocatalysts to promote their large-scale application. Subsequently, a particular aim is put on the most current studies for photocatalytic applications, including CO reduction, N fixation, H evolution, and pollutants degradation. Finally, key challenges and future perspectives in designing and implementing semiconductor photocatalysts for large-scale applications are discussed. Therefore, it is foreseen that this review will work as a guide for future research and provides a variety of strategies to develop novel and high-performance photocatalysts for various applications.
The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-hole recombination rate. Sincemost of intrinsic semiconductor photocatalysts cannot meet all these requirements, they are often modified to boost their photocatalytic properties. Many strategies have been adopted to design novel and efficient photocatalysts for diverse applications. Herein, we review the most efficient of these strategies and methods focused on effectively overcoming the efficiency limitations of photocatalysts to promote their large-scale application. Subsequently, a particular aim is put on the most current studies for photocatalytic applications, including CO2 reduction, N2 fixation, H2 evolution, and pollutants degradation. Finally, key challenges and future perspectives in designing and implementing semiconductor photocatalysts for large-scale applications are discussed. Therefore, it is foreseen that this review will work as a guide for future research and provides a variety of strategies to develop novel and high-performance photocatalysts for various applications.The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-hole recombination rate. Sincemost of intrinsic semiconductor photocatalysts cannot meet all these requirements, they are often modified to boost their photocatalytic properties. Many strategies have been adopted to design novel and efficient photocatalysts for diverse applications. Herein, we review the most efficient of these strategies and methods focused on effectively overcoming the efficiency limitations of photocatalysts to promote their large-scale application. Subsequently, a particular aim is put on the most current studies for photocatalytic applications, including CO2 reduction, N2 fixation, H2 evolution, and pollutants degradation. Finally, key challenges and future perspectives in designing and implementing semiconductor photocatalysts for large-scale applications are discussed. Therefore, it is foreseen that this review will work as a guide for future research and provides a variety of strategies to develop novel and high-performance photocatalysts for various applications.
The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a photocatalyst depends on four key elements: light absorption ability, the density of active sites, redox capacity, and photoinduced electron-hole recombination rate. Sincemost of intrinsic semiconductor photocatalysts cannot meet all these requirements, they are often modified to boost their photocatalytic properties. Many strategies have been adopted to design novel and efficient photocatalysts for diverse applications. Herein, we review the most efficient of these strategies and methods focused on effectively overcoming the efficiency limitations of photocatalysts to promote their large-scale application. Subsequently, a particular aim is put on the most current studies for photocatalytic applications, including CO2 reduction, N2 fixation, H2 evolution, and pollutants degradation. Finally, key challenges and future perspectives in designing and implementing semiconductor photocatalysts for large-scale applications are discussed. Therefore, it is foreseen that this review will work as a guide for future research and provides a variety of strategies to develop novel and high-performance photocatalysts for various applications. [Display omitted] •Recent advances in strategies to design semiconductor catalysts are discussed.•The mechanism of various strategies for photocatalytic performance are highlighted.•The effect of diverse strategies on the photocatalytic performance is summarized.•Combination of different strategies leads to further increased performance.•Challenges pertaining the use of semiconductor catalysts are reviewed.
ArticleNumber 102830
Author Liu, Yuyu
Zou, Yanhong
Ahmad, Irshad
Shukrullah, Shazia
Naz, Muhammad Yasin
Yan, Jiaying
Khan, Waheed Qamar
Khalid, N.R.
Hussain, Humaira
Author_xml – sequence: 1
  givenname: Irshad
  surname: Ahmad
  fullname: Ahmad, Irshad
  email: irshadmahar55@yahoo.com
  organization: Department of Physics, University of Agriculture, Faisalabad 38040, Pakistan
– sequence: 2
  givenname: Yanhong
  surname: Zou
  fullname: Zou, Yanhong
  organization: Institute for Sustainable Energy, College of Sciences, Shanghai University, Shangda Road 99, Baoshan, Shanghai 20044, China
– sequence: 3
  givenname: Jiaying
  surname: Yan
  fullname: Yan, Jiaying
  organization: Institute for Sustainable Energy, College of Sciences, Shanghai University, Shangda Road 99, Baoshan, Shanghai 20044, China
– sequence: 4
  givenname: Yuyu
  surname: Liu
  fullname: Liu, Yuyu
  email: liuyuyu2014@126.com
  organization: Institute for Sustainable Energy, College of Sciences, Shanghai University, Shangda Road 99, Baoshan, Shanghai 20044, China
– sequence: 5
  givenname: Shazia
  surname: Shukrullah
  fullname: Shukrullah, Shazia
  organization: Department of Physics, University of Agriculture, Faisalabad 38040, Pakistan
– sequence: 6
  givenname: Muhammad Yasin
  surname: Naz
  fullname: Naz, Muhammad Yasin
  organization: Department of Physics, University of Agriculture, Faisalabad 38040, Pakistan
– sequence: 7
  givenname: Humaira
  surname: Hussain
  fullname: Hussain, Humaira
  organization: Department of Chemistry, University of Okara, Okara 56300, Pakistan
– sequence: 8
  givenname: Waheed Qamar
  surname: Khan
  fullname: Khan, Waheed Qamar
  organization: Institute of Advanced Materials, Bahauddin Zakariya University, Multan 6800, Pakistan
– sequence: 9
  givenname: N.R.
  surname: Khalid
  fullname: Khalid, N.R.
  organization: Department of Physics, University of Okara, Okara 56300, Pakistan
BackLink https://www.ncbi.nlm.nih.gov/pubmed/36592501$$D View this record in MEDLINE/PubMed
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Keywords N2 fixation
Pollutants degradation
CO2 reduction
H2 evolution
Photocatalysts
Strategies
CO reduction
H evolution
N fixation
Language English
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Snippet The photocatalytic technology illustrates an eco-friendly and sustainable route to overcome environmental and energy issues. The successful construction of a...
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SubjectTerms CO2 reduction
H2 evolution
N2 fixation
Photocatalysts
Pollutants degradation
Semiconductors
Strategies
Title Semiconductor photocatalysts: A critical review highlighting the various strategies to boost the photocatalytic performances for diverse applications
URI https://dx.doi.org/10.1016/j.cis.2022.102830
https://www.ncbi.nlm.nih.gov/pubmed/36592501
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